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Journal of Polymer Research

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01-01-2016 | Original Paper

The preparation and properties study of polydimethylsiloxane-based coatings modified by epoxy resin

Authors: Cheng Zhou, Rui Li, Wei Luo, Yang Chen, Huawei Zou, Mei Liang, Yi Li

Published in: Journal of Polymer Research | Issue 1/2016

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Abstract

In this research, a hydroxyl-terminated polydimethylsiloxane (HTPDMS) was modified by the incorporation of siliconized epoxy resin (SER) containing a segment of siloxane on the side chain of epoxy resin. The chemical structure of the SER was studied by FT-IR, GPC and NMR techniques. Adhesion test showed that the adhesion strength of silicone rubber systems improved markedly after modification. Contact angle (CA) measurements showed the presence of the epoxy block at the surface, which improved adhesion properties of the modified HTPDMS. Morphology studies (SEM) displayed that enhancement in the mechanical properties of the silicone rubber systems due to good compatibility between SER and silicone rubber matrix. Thermogravimetric analysis (TGA) indicated that the residual yield at 800 °C of modified HTPDMS increased compared with that of the neat HTPDMS, but the onset decomposition temperature was reduced with the increase in SER content. These observations highlight the significant role of SER in the modification of HTPDMS.

previous article Synergistic effects of zinc-mannitol alkoxide with calcium/zinc stearates and with β-diketone on thermal stability of rigid poly(vinyl chloride)

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Huang JC (2012) Fabrication of a gecko seta-like structure using polydimethylsiloxane. Int J Adhes Adhes 36:25–31CrossRef

Tsai MF, Lee YD, Long YC (2000) Synthesis of a polydimethylsiloxane-block-hydroxyl grafted acrylate prepolymer copolymer to improve the adhesion between silicone rubber and polyurethane by induced surface reconstruction. J Polym Res 7(2):73–79CrossRef

Xiang K, Huang G, Zheng J, Wang X, Li GX, Huang J (2012) Accelerated thermal ageing studies of polydimethylsiloxane (PDMS) rubber. J Polym Res 19(5):1–7CrossRef

Zhang M, Wu Y, Wu H, Zhang Q (2011) Study on reactive polydimethylsiloxane-modified waterborne polyurethanes. J Polym Res 19(1):1–10

Liao SK, Jang SC, Lin MF (2005) Phase behavior and mechanical properties of siloxane-urethane copolymer. J Polym Res 12(2):103–112CrossRef

Shi Y, Huang G, Liu Y, Qu Y, Zhang D, Dang Y (2013) Synthesis and thermal properties of novel room temperature vulcanized (rtv) silicone rubber containing poss units in polysioxane main chains. J Polym Res 20(9):1–11CrossRef

Lv P, Wang Z, Hu Y, Yu M (2009) Study on effect of polydimethylsiloxane in intumescent flame retardant polypropylene. J Polym Res 16(2):81–89CrossRef

Chen WH, Chen PC, Wang SC, Yeh JT, Huang CY, Chen KN (2009) Uv-curable pdms-containing pu system for hydrophobic textile surface treatment. J Polym Res 16(5):601–610CrossRef

Lauter U, Kantor SW, Schmidt-Rohr K, MacKnight WJ (1999) Vinyl-substituted silphenylene siloxane copolymers: novel high-temperature elastomers. Macromolecules 32(10):3426–3431CrossRef

10.

Chojnowski J, Cypryk M, Fortuniak W, Scibiorek M, Rozga-Wijas K (2003) Synthesis of branched polysiloxanes with controlled branching and functionalization by anionic ring-opening polymerization. Macromolecules 36(11):3890–3897CrossRef

11.

Roth J, Albrecht V, Nitschke M, Bellmann C, Simon F, Zschoche S, Michel S, Luhmann C, Grundke K, Voit B (2008) Surface functionalization of silicone rubber for permanent adhesion improvement. Langmuir 24(21):12603–12611CrossRef

12.

Eddington DT, Puccinelli JP, Beebe DJ (2006) Thermal aging and reduced hydrophobic recovery of polydimethylsiloxane. Sensors Actuators B Chem 114(1):170–172CrossRef

13.

Pinto S, Alves P, Matos CM, Santos AC, Rodrigues LR, Teixeira JA, Gil MH (2010) Poly (dimethyl siloxane) surface modification by low pressure plasma to improve its characteristics towards biomedical applications. Colloids Surf B: Biointerfaces 81(1):20–26CrossRef

14.

Abbasi F, Mirzadeh H, Katbab AA (2001) Modification of polysiloxane polymers for biomedical applications: a review. Polym Int 50(12):1279–1287CrossRef

15.

Sia SK, Whitesides GM (2003) Microfluidic devices fabricated in poly (dimethylsiloxane) for biological studies. Electrophoresis 24(21):3563–3576CrossRef

16.

Mikhail AS, Jones KS, Sheardown H (2008) Dendrimer-grafted cell adhesion peptide–modified PDMS. Biotechnol Prog 24(4):938–944CrossRef

17.

Boxshall K, Wu MH, Cui Z, Cui Z, Watts JF, Baker MA (2006) Simple surface treatments to modify protein adsorption and cell attachment properties within a poly (dimethylsiloxane) micro-bioreactor. Surf Interface Anal 38(4):198–201CrossRef

18.

Sugiura S, Edahiro JI, Sumaru K, Kanamori T (2008) Surface modification of polydimethylsiloxane with photo-grafted poly (ethylene glycol) for micropatterned protein adsorption and cell adhesion. Colloids Surf B: Biointerfaces 63(2):301–305CrossRef

19.

Iwasaki Y, Takamiya M, Iwata R, Yusa SI, Akiyoshi K (2007) Surface modification with well-defined biocompatible triblock copolymers: improvement of biointerfacial phenomena on a poly (dimethylsiloxane) surface. Colloids Surf B: Biointerfaces 57(2):226–236CrossRef

20.

Lee S, Vörös J (2005) An aqueous-based surface modification of poly (dimethylsiloxane) with poly (ethylene glycol) to prevent biofouling. Langmuir 21(25):11957–11962CrossRef

21.

Bodas D, Khan-Malek C (2006) Formation of more stable hydrophilic surfaces of PDMS by plasma and chemical treatments. Microelectron Eng 83(4):1277–1279CrossRef

22.

Cordeiro AL, Nitschke M, Janke A, Helbig R, D’Souza F, Donnelly GT, Willemsen PR, Werner C (2009) Fluorination of poly (dimethylsiloxane) surfaces by low pressure CF4 plasma–physicochemical and antifouling properties. eXPRESS Polym Lett 3:70–83CrossRef

23.

Karkhaneh A, Mirzadeh H, Ghaffariyeh AR (2007) Simultaneous graft copolymerization of 2-hydroxyethyl methacrylate and acrylic acid onto polydimethylsiloxane surfaces using a two-step plasma treatment. J Appl Polym Sci 105(4):2208–2217CrossRef

24.

Lippens E, Smet ND, Schauvliege S, Martens A, Gasthuys F, Schacht E et al (2013) Biocompatibility properties of surface-modified poly(dimethylsiloxane) for urinary applications. J Biomater Appl 27(6):651–660CrossRef

25.

Jalili K, Abbasi F, Milchev A (2013) Surface microdynamics phase transition and internal structure of high-density, ultrathin PHEMA-b-PNIPAM diblock copolymer brushes on silicone rubber. Macromolecules 46(13):5260–5278CrossRef

26.

Ercole F, Davis TP, Evans RA (2010) Photo-responsive systems and biomaterials: photochromic polymers, light-triggered self-assembly, surface modification, fluorescence modulation and beyond. Polym Chem 1(1):37–54CrossRef

27.

Böhmer MR, Klibanov AL, Tiemann K, Hall CS, Gruell H, Steinbach OC (2009) Ultrasound triggered image-guided drug delivery. Eur J Radiol 70(2):242–253CrossRef

28.

Ochi M, Shimaoka S (1999) Phase structure and toughness of silicone-modified epoxy resin with added silicone graft copolymer. Polymer 40(5):1305–1312CrossRef

29.

Lee SS, Kim SC (1997) Morphology and properties of polydimethylsiloxane-modified epoxy resin. J Appl Polym Sci 64(5):941–955CrossRef

30.

Ahmad S, Gupta AP, Sharmin E, Alam M, Pandey SK (2005) Synthesis, characterization and development of high performance siloxane-modified epoxy paints. Prog Org Coat 54(3):248–255CrossRef

31.

Rath SK, Chavan JG, Sasane S, Patri M, Samui AB, Chakraborty BC (2010) Two component silicone modified epoxy foul release coatings: effect of modulus, surface energy and surface restructuring on pseudobarnacle and macrofouling behavior. Appl Surf Sci 256(8):2440–2446CrossRef

32.

Takahashi T, Nakajima N, Saito N (1989) In: Riew CK (ed) Rubber-toughened plastics, Adv. Chem. Ser. 222. American Chemical Society, Washington, D. C., p 243CrossRef

33.

Marabotti I, Morelli A, Orsini ML, Martinelli E, Galli G, Chiellini E, Lien ME, Pettitt EM, Callow EM, Callow AJ, Conlan LS, Mutton JR, Clare SA, Kocijan A, Donik C, Jenko M (2009) Fluorinated/siloxane copolymer blends for fouling release: chemical characterisation and biological evaluation with algae and barnacles. Biofouling 25(6):481–493CrossRef

34.

Martinelli E, Savothaman KM, Galli G, Pettitt EM, Callow EM, Callow AJ, Conlan LS, Clare SA, Sugiharto BA, Davies C, Williams D (2012) Poly(dimethyl siloxane) (PDMS) network blends of amphiphilic acrylic copolymers with poly(ethylene glycol)-fluoroalkyl side chains for fouling-release coatings. II. Laboratory assays and field immersion trials. Biofouling 28(6):571–582CrossRef

35.

Ngo TC, Kalinova R, Cossement D, Hennebert E, Mincheva R, Snyders R, Flammang P, Dubois P, Lazzaroni R, Leclère P (2013) Modification of the adhesive properties of silicone-based coatings by block copolymers. Langmuir 30(1):358–368CrossRef

36.

Lin ST, Huang SK (1994) Synthesis and characterization of siloxane-modified epoxy resin. J Polym Res 1(2):151–162CrossRef

37.

Lin ST, Huang SK (1997) Thermal degradation study of siloxane-DGEBA epoxy copolymers. Eur Polym J 33(3):365–373CrossRef

38.

Li J, Fan L, Wong C (2010) Insulator coating and method for forming same. U.S. Patent 7,722,951 B2

39.

Zhang Y, Jing X, Jing K, Chang L, Bao W (2015) Study on the pore structure and oxygen-containing functional groups devoting to the hydrophilic force of dewatered lignite. Appl Surf Sci 324:90–98CrossRef

40.

Abbasi N (2014) The effects of plasma treated electrospun nanofibrous poly (ε-caprolactone) scaffolds with different orientations on mouse embryonic stem cell proliferation. Cell J 16(3)

41.

Chen J, Chen Q, Ma Q (2012) Influence of surface functionalization via chemical oxidation on the properties of carbon nanotubes. J Colloid Interface Sci 370(11):32–38CrossRef

42.

Amouroux N, Petit J, Léger L (2001) Role of interfacial resistance to shear stress on adhesive peel strength. Langmuir 17(21):6510–6517CrossRef

43.

Abbasian A, Ghaffarian SR, Mohammadi N, Fallahi D (2004) The contact angle of thin-uncured epoxy films: thickness effect. Colloids Surf A Physicochem Eng Asp 236(1):133–140CrossRef

44.

Grassie N, Macfarlane IG (1978) The thermal degradation of polysiloxanes—I. Poly (dimethylsiloxane). Eur Polym J 14(11):875–884CrossRef

45.

Rode VV, Verkhoti MA, Rafikov SR (1969) The thermal degradation and stabilization of polydimethysiloxane. Vysoke Soedin Sect A 11(7):1529

46.

Thomas TH, Kendrick TC (1969) Thermal analysis of polydimethylsiloxanes. I. Thermal degradation in controlled atmospheres. J Polym Sci Part A‐2: Polym Phys 7(3):537–549

47.

Radhakrishnan TS (1999) New method for evaluation of kinetic parameters and mechanism of degradation from pyrolysis–GC studies: thermal degradation of polydimethylsiloxanes. J Appl Polym Sci 73(3):441–450CrossRef

48.

Woo EM, Barlow JW, Paul DR (1985) Thermodynamics of the phase behaviour of poly (vinyl chloride)/aliphatic polyester blends. Polymer 26(5):763–773CrossRef

49.

Chiu HT, Chiu SH, Wu JH (2003) Study on mechanical properties and intermolecular interaction of silicone rubber/polyurethane/epoxy blends. J Appl Polym Sci 89(4):959–970CrossRef

Title: The preparation and properties study of polydimethylsiloxane-based coatings modified by epoxy resin
Authors: Cheng Zhou
Rui Li
Wei Luo
Yang Chen
Huawei Zou
Mei Liang
Yi Li
Publication date: 01-01-2016
Publisher: Springer Netherlands
Published in: Journal of Polymer Research / Issue 1/2016
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-015-0903-3

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