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2021 | OriginalPaper | Buchkapitel

15. π-Conjugated Polymers Incorporating Naphthalene-Based Nitrogen-Containing Heteroaromatics for Organic Photovoltaics

verfasst von : Itaru Osaka

Erschienen in: Progress in the Science of Functional Dyes

Verlag: Springer Singapore

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Abstract

Recently, a wide variety of π-conjugated polymers have been developed for the use as the active layer in organic photovoltaics (OPVs). This chapter will summarize the recent development of π-conjugated polymers with donor–acceptor motifs, specifically, based on naphthalene-based nitrogen-containing heteroaromatics as the acceptor unit. With the strong electron-deficient nature as well as the large π-conjugation system, incorporation of these heteroaromatics in the backbone allows us to create π-conjugated polymers having wide absorption range, i.e., narrow bandgap, deep HOMO energy levels, and high crystallinity, all of which are important for improving the efficiency of OPV cells. We describe the syntheses, properties, structural order in the thin films, and OPV performances of the π-conjugated polymers based on naphthobisthiadiazole and its analogues.

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Titel: π-Conjugated Polymers Incorporating Naphthalene-Based Nitrogen-Containing Heteroaromatics for Organic Photovoltaics
verfasst von: Itaru Osaka
Verlag: Springer Singapore
Buch: Progress in the Science of Functional Dyes
Print ISBN: 978-981-334-391-7

Electronic ISBN: 978-981-334-392-4

Copyright-Jahr: 2021
DOI: https://doi.org/10.1007/978-981-33-4392-4_15