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Erschienen in: Journal of Materials Engineering and Performance 9/2019

04.09.2019

A Biomedical Ti-35Nb-5Ta-7Zr Alloy Fabricated by Powder Metallurgy

verfasst von: B. Q. Li, X. Lu

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 9/2019

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Abstract

Ti-35Nb-5Ta-7Zr alloy for biomedical applications with a reduced Young’s modulus of less than 10 GPa, being comparable to that of human bones, was successfully fabricated by powder metallurgy method. The microstructure, compressive and tensile behavior were studied. Results indicate that Ti-rich and Ta-rich phases co-exist in β-matrix. Ti-35Nb-5Ta-7Zr alloys yield at about 10% in compression, with increasing in the content of process control agent, the resultant compressive yield strength and Young’s modulus increase from 650 ± 46 to 1055 ± 90 MPa and from 6.3 ± 0.03 to 8.24 ± 0.04 GPa, respectively. The tensile fractography of alloy with 9.7 GPa tensile Young’s modulus, 433 MPa UTS at the 5.5% elongation consists of cleavage fracture and ductile fracture with dimples. The failure mechanism has been discussed taking the intrinsic microstructural features into consideration.

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Literatur
1.
Zurück zum Zitat P. Heinl, L. Müller, C. Körner, R.F. Singer, and F.A. Müller, Cellular Ti-6Al-4V Structures with Interconnected Macro Porosity for Bone Implants Fabricated by Selective Electron Beam Melting, Acta Biomater., 2008, 4, p 1536–1544CrossRef P. Heinl, L. Müller, C. Körner, R.F. Singer, and F.A. Müller, Cellular Ti-6Al-4V Structures with Interconnected Macro Porosity for Bone Implants Fabricated by Selective Electron Beam Melting, Acta Biomater., 2008, 4, p 1536–1544CrossRef
2.
Zurück zum Zitat N. Resnina, S. Belyaev, A. Voronkov, and R. Badun, Shape Memory Effects in Porous Ti-45.0 at.% Ni Alloy Produced by Self-Propagating High-Temperature Synthesis, Materials Today Proceedings, 2017, 4, p 4690–4695CrossRef N. Resnina, S. Belyaev, A. Voronkov, and R. Badun, Shape Memory Effects in Porous Ti-45.0 at.% Ni Alloy Produced by Self-Propagating High-Temperature Synthesis, Materials Today Proceedings, 2017, 4, p 4690–4695CrossRef
3.
Zurück zum Zitat X.Y. Li and S. Taniguchi, Correlation of High Temperature Oxidation with Tensile Properties for Ti-48Al-2Cr-2Nb and Ti-48Al-2Cr-2Fe Alloys, Intermetallics, 2005, 13, p 683–693CrossRef X.Y. Li and S. Taniguchi, Correlation of High Temperature Oxidation with Tensile Properties for Ti-48Al-2Cr-2Nb and Ti-48Al-2Cr-2Fe Alloys, Intermetallics, 2005, 13, p 683–693CrossRef
4.
Zurück zum Zitat M.J. Long and H.J. Rack, Titanium Alloys in Total Joint Replacement—A Materials Science Perspective, Biomaterial, 1998, 19, p 1621–1639CrossRef M.J. Long and H.J. Rack, Titanium Alloys in Total Joint Replacement—A Materials Science Perspective, Biomaterial, 1998, 19, p 1621–1639CrossRef
5.
Zurück zum Zitat L.Q. Wang, W.J. Lu, J.N. Qin, F. Zhang, and D. Zhang, Texture and Superelastic Behavior of Cold-Rolled TiNbTaZr Alloy, Mater. Sci. Eng., A, 2008, 491, p 372–377CrossRef L.Q. Wang, W.J. Lu, J.N. Qin, F. Zhang, and D. Zhang, Texture and Superelastic Behavior of Cold-Rolled TiNbTaZr Alloy, Mater. Sci. Eng., A, 2008, 491, p 372–377CrossRef
6.
Zurück zum Zitat S. Acharya, A.G. Panicker, D.V. Laxmi, S. Suwas, and K. Chatterjee, Study of the Influence of Zr on the Mechanical Properties and Functional Response of Ti-Nb-Ta-Zr-O Alloy for Orthopedic Applications, Mater. Des., 2019, 164, p 107555CrossRef S. Acharya, A.G. Panicker, D.V. Laxmi, S. Suwas, and K. Chatterjee, Study of the Influence of Zr on the Mechanical Properties and Functional Response of Ti-Nb-Ta-Zr-O Alloy for Orthopedic Applications, Mater. Des., 2019, 164, p 107555CrossRef
7.
Zurück zum Zitat A. Maghsoudlou, A. Zarei-Hanzaki, H.R. Abedi, A. Barabi, F. Pilehva, D. Dietrich, and T. Lampke, The Room Temperature Tensile Deformation Behavior of Thermomechanically Processed β-Metastable Ti-Nb-Ta-Zr Bio-alloy: The Role of Deformation-Induced Martensite, Materials Science and Engineering: A, 2018, 738, p 15–23CrossRef A. Maghsoudlou, A. Zarei-Hanzaki, H.R. Abedi, A. Barabi, F. Pilehva, D. Dietrich, and T. Lampke, The Room Temperature Tensile Deformation Behavior of Thermomechanically Processed β-Metastable Ti-Nb-Ta-Zr Bio-alloy: The Role of Deformation-Induced Martensite, Materials Science and Engineering: A, 2018, 738, p 15–23CrossRef
8.
Zurück zum Zitat R. Karre, M.K. Niranjan, and S.R. Dey, First Principles Theoretical Investigations of Low Young’s Modulus Beta Ti-Nb and Ti-Nb-Zr Alloys Compositions for Biomedical Applications, Mater. Sci. Eng., C, 2015, 50, p 52–58CrossRef R. Karre, M.K. Niranjan, and S.R. Dey, First Principles Theoretical Investigations of Low Young’s Modulus Beta Ti-Nb and Ti-Nb-Zr Alloys Compositions for Biomedical Applications, Mater. Sci. Eng., C, 2015, 50, p 52–58CrossRef
9.
Zurück zum Zitat C. Marker, S.L. Shang, J.C. Zhao, and Z.K. Liu, Thermodynamic Description of the Ti-Mo-Nb-Ta-Zr System and Its Implications for Phase Stability of Ti Bio-implant Materials, Calphad, 2018, 61, p 72–84CrossRef C. Marker, S.L. Shang, J.C. Zhao, and Z.K. Liu, Thermodynamic Description of the Ti-Mo-Nb-Ta-Zr System and Its Implications for Phase Stability of Ti Bio-implant Materials, Calphad, 2018, 61, p 72–84CrossRef
10.
Zurück zum Zitat A. Fukuda, M. Takemoto, T. Saito, S. Fujibayashi, M. Neo, S. Yamaguchi, T. Kizuki, T. Matsushita, M. Niinomi, T. Kokubo, and T. Nakamura, Bone Bonding Bioactivity of Ti Metal and Ti-Zr-Nb-Ta Alloys with Ca Ions Incorporated on Their Surfaces by Simple Chemical and Heat Treatments, Acta Biomater., 2011, 7, p 1379–1386CrossRef A. Fukuda, M. Takemoto, T. Saito, S. Fujibayashi, M. Neo, S. Yamaguchi, T. Kizuki, T. Matsushita, M. Niinomi, T. Kokubo, and T. Nakamura, Bone Bonding Bioactivity of Ti Metal and Ti-Zr-Nb-Ta Alloys with Ca Ions Incorporated on Their Surfaces by Simple Chemical and Heat Treatments, Acta Biomater., 2011, 7, p 1379–1386CrossRef
11.
Zurück zum Zitat A. Biesiekierski, D. Ping, Y.C. Li, J.X. Lin, K.S. Munir, Y. Yamabe-Mitarai, and C. Wen., Extraordinary High Strength Ti-Zr-Ta Alloys Through Nanoscaled, Dual-Cubic Spinodal Reinforcement, Acta Biomaterialia, 2017, 53, p 549–558CrossRef A. Biesiekierski, D. Ping, Y.C. Li, J.X. Lin, K.S. Munir, Y. Yamabe-Mitarai, and C. Wen., Extraordinary High Strength Ti-Zr-Ta Alloys Through Nanoscaled, Dual-Cubic Spinodal Reinforcement, Acta Biomaterialia, 2017, 53, p 549–558CrossRef
12.
Zurück zum Zitat J.M. Cordeiro, B.E. Nagay, A.L.R. Ribeiro, N.C. da Cruz, and V.A.R. Barão, Functionalization of an Experimental Ti-Nb-Zr-Ta Alloy with a Biomimetic Coating Produced by Plasma Electrolytic Oxidation, J. Alloy. Compd., 2019, 770, p 1038–1048CrossRef J.M. Cordeiro, B.E. Nagay, A.L.R. Ribeiro, N.C. da Cruz, and V.A.R. Barão, Functionalization of an Experimental Ti-Nb-Zr-Ta Alloy with a Biomimetic Coating Produced by Plasma Electrolytic Oxidation, J. Alloy. Compd., 2019, 770, p 1038–1048CrossRef
13.
Zurück zum Zitat M.F. Ijaz, Y. Zhukova, A. Konopatsky, S. Dubinskiy, and S. Prokoshkin, Effect of Ta Addition on the Electrochemical Behavior and Functional Fatigue Life of Metastable Ti-Zr-Nb Based Alloy for Indwelling Implant Applications, J. Alloy. Compd., 2018, 748, p 51–56CrossRef M.F. Ijaz, Y. Zhukova, A. Konopatsky, S. Dubinskiy, and S. Prokoshkin, Effect of Ta Addition on the Electrochemical Behavior and Functional Fatigue Life of Metastable Ti-Zr-Nb Based Alloy for Indwelling Implant Applications, J. Alloy. Compd., 2018, 748, p 51–56CrossRef
14.
Zurück zum Zitat P. Stenlund, O. Omar, U. Brohede, S. Norgren, B. Norlindh, A. Johansson, J. Lausmaa, P. Thomsen, and A. Palmquist, Bone Response to a Novel Ti-Ta-Nb-Zr Alloy, Acta Biomater., 2015, 20, p 165–175CrossRef P. Stenlund, O. Omar, U. Brohede, S. Norgren, B. Norlindh, A. Johansson, J. Lausmaa, P. Thomsen, and A. Palmquist, Bone Response to a Novel Ti-Ta-Nb-Zr Alloy, Acta Biomater., 2015, 20, p 165–175CrossRef
15.
Zurück zum Zitat J. Málek, F. Hnilica, J. Veselý, B. Smola, S. Bartáková, and J. Vaněk, The Influence of Chemical Composition and Thermo-mechanical Treatment on Ti-Nb-Ta-Zr Alloys, Mater. Des., 2012, 35, p 731–740CrossRef J. Málek, F. Hnilica, J. Veselý, B. Smola, S. Bartáková, and J. Vaněk, The Influence of Chemical Composition and Thermo-mechanical Treatment on Ti-Nb-Ta-Zr Alloys, Mater. Des., 2012, 35, p 731–740CrossRef
16.
Zurück zum Zitat S.J. Li, R. Yang, S. Li, Y.L. Hao, Y.Y. Cui, M. Niinomi, and Z.X. Guo, Wear Characteristics of Ti-Nb-Ta-Zr and Ti-6Al-4V Alloys for Biomedical Applications, Wear, 2004, 257, p 869–876CrossRef S.J. Li, R. Yang, S. Li, Y.L. Hao, Y.Y. Cui, M. Niinomi, and Z.X. Guo, Wear Characteristics of Ti-Nb-Ta-Zr and Ti-6Al-4V Alloys for Biomedical Applications, Wear, 2004, 257, p 869–876CrossRef
17.
Zurück zum Zitat S. Ozan, J.X. Lin, Y.C. Li, and C. Wen, New Ti-Ta-Zr-Nb Alloys with Ultrahigh Strength for Potential Orthopedic Implant Applications, J. Mech. Behav. Biomed. Mater., 2017, 75, p 119–127CrossRef S. Ozan, J.X. Lin, Y.C. Li, and C. Wen, New Ti-Ta-Zr-Nb Alloys with Ultrahigh Strength for Potential Orthopedic Implant Applications, J. Mech. Behav. Biomed. Mater., 2017, 75, p 119–127CrossRef
18.
Zurück zum Zitat L.Y. Han, C.S. Wang, and J.B. Qiang, Microstructure and Properties of Ti-Fe-Zr-Y Alloys Prepared by Laser Rapid Prototyping, Journal of Alloys and Compounds, 2017, 700, p 159–168CrossRef L.Y. Han, C.S. Wang, and J.B. Qiang, Microstructure and Properties of Ti-Fe-Zr-Y Alloys Prepared by Laser Rapid Prototyping, Journal of Alloys and Compounds, 2017, 700, p 159–168CrossRef
19.
Zurück zum Zitat C. Wang, Q.Z. Gao, Y. Yuan, H.L. Zhang, J. Zhang, Q.Y. Wang, and F. Qu, Microstructure Evolutions of Ni-Ti-Nb-Al Alloys with Different Al Addition, J. Alloy. Compd., 2017, 695, p 2293–2929 C. Wang, Q.Z. Gao, Y. Yuan, H.L. Zhang, J. Zhang, Q.Y. Wang, and F. Qu, Microstructure Evolutions of Ni-Ti-Nb-Al Alloys with Different Al Addition, J. Alloy. Compd., 2017, 695, p 2293–2929
20.
Zurück zum Zitat L.M. Elias, S.G. Schneider, S. Schneider, H.M. Silva, and F. Malvisi, Microstructural and Mechanical Characterization of Biomedical Ti-Nb-Zr(-Ta) Alloys, Mater. Sci. Eng., A, 2006, 432, p 108–112CrossRef L.M. Elias, S.G. Schneider, S. Schneider, H.M. Silva, and F. Malvisi, Microstructural and Mechanical Characterization of Biomedical Ti-Nb-Zr(-Ta) Alloys, Mater. Sci. Eng., A, 2006, 432, p 108–112CrossRef
21.
Zurück zum Zitat V.T. Nguyen, M. Qian, Z. Shi, T. Song, and J. Zou, Compositional Design of Strong and Ductile (Tensile) Ti-Zr-Nb-Ta Medium Entropy Alloys (MEAs) Using the Atomic Mismatch Approach, Mater. Sci. Eng., A, 2019, 742, p 762–772CrossRef V.T. Nguyen, M. Qian, Z. Shi, T. Song, and J. Zou, Compositional Design of Strong and Ductile (Tensile) Ti-Zr-Nb-Ta Medium Entropy Alloys (MEAs) Using the Atomic Mismatch Approach, Mater. Sci. Eng., A, 2019, 742, p 762–772CrossRef
22.
Zurück zum Zitat A. Nouri, P.D. Hodgson, and C. Wen, Effect of Process Control Agent on the Porous Structure and Mechanical Properties of a Biomedical Ti-Sn-Nb Alloy Produced by Powder Metallurgy, Acta Biomater., 2010, 6, p 1630–1639CrossRef A. Nouri, P.D. Hodgson, and C. Wen, Effect of Process Control Agent on the Porous Structure and Mechanical Properties of a Biomedical Ti-Sn-Nb Alloy Produced by Powder Metallurgy, Acta Biomater., 2010, 6, p 1630–1639CrossRef
23.
Zurück zum Zitat V. Sheremetyev, S. Prokoshkin, V. Brailovski, S. Dubinskiy, M. Filonova, and M. Petrzhik, Long-Term Stability of Superelastic Behavior of Nanosubgrained Ti-Nb-Zr and Ti-Nb-Ta Shape Memory Alloys, Materials Today: Proceedings, 2015, 2, p s26–s31 V. Sheremetyev, S. Prokoshkin, V. Brailovski, S. Dubinskiy, M. Filonova, and M. Petrzhik, Long-Term Stability of Superelastic Behavior of Nanosubgrained Ti-Nb-Zr and Ti-Nb-Ta Shape Memory Alloys, Materials Today: Proceedings, 2015, 2, p s26–s31
24.
Zurück zum Zitat A. Nouri, P.D. Hodgson, and C. Wen, Effect of Ball-Milling Time on the Structural Characteristic of Biomedical Porous Ti-Sn-Nb Alloy, Mater. Sci. Eng., C, 2011, 31, p 921–928CrossRef A. Nouri, P.D. Hodgson, and C. Wen, Effect of Ball-Milling Time on the Structural Characteristic of Biomedical Porous Ti-Sn-Nb Alloy, Mater. Sci. Eng., C, 2011, 31, p 921–928CrossRef
25.
Zurück zum Zitat E. Gordo, B. Gómez, E.M. Ruiz-Navas, and J.M. Torralba, Influence of Milling Parameters on the Manufacturing of Fe-TiCN Composite Powders, J. Mater. Process. Technol., 2005, 162–163, p 59–64CrossRef E. Gordo, B. Gómez, E.M. Ruiz-Navas, and J.M. Torralba, Influence of Milling Parameters on the Manufacturing of Fe-TiCN Composite Powders, J. Mater. Process. Technol., 2005, 162–163, p 59–64CrossRef
26.
Zurück zum Zitat C. Yang, M.D. Zhu, X. Luo, L.H. Liu, W.W. Zhang, Y. Long, Z.Y. Xiao, Z.Q. Fu, L.C. Zhang, and E.J. Lavernia, Influence of Powder Properties on Densification Mechanism During Spark Plasma Sintering, Scripta Mater., 2017, 139, p 96–99CrossRef C. Yang, M.D. Zhu, X. Luo, L.H. Liu, W.W. Zhang, Y. Long, Z.Y. Xiao, Z.Q. Fu, L.C. Zhang, and E.J. Lavernia, Influence of Powder Properties on Densification Mechanism During Spark Plasma Sintering, Scripta Mater., 2017, 139, p 96–99CrossRef
27.
Zurück zum Zitat D.L. Zhang, Processing of Advanced Materials Using High-Energy Mechanical Milling, Prog. Mater Sci., 2004, 49, p 537–560CrossRef D.L. Zhang, Processing of Advanced Materials Using High-Energy Mechanical Milling, Prog. Mater Sci., 2004, 49, p 537–560CrossRef
28.
Zurück zum Zitat W.M. Wang, Z.Y. Fu, H. Wang, and R.Z. Yuan, Influence of Hot Pressing Sintering Temperature and Time on Microstructure and Mechanical Properties of TiB2 Ceramics, J. Eur. Ceram. Soc., 2002, 22, p 1045–1049CrossRef W.M. Wang, Z.Y. Fu, H. Wang, and R.Z. Yuan, Influence of Hot Pressing Sintering Temperature and Time on Microstructure and Mechanical Properties of TiB2 Ceramics, J. Eur. Ceram. Soc., 2002, 22, p 1045–1049CrossRef
29.
Zurück zum Zitat M. Kheradmandfard, S. Kashani-Bozorg, K. Kang, O.V. Penkov, A. Hanzaki, Y. Pyoun, A. Amanov, and D. Kim, Simultaneous Grain Refinement and Nanoscale Spinodal Decomposition of β Phase in Ti-Nb-Ta-Zr Alloy Induced by Ultrasonic Mechanical Impacts, J. Alloy. Compd., 2018, 738, p 540–549CrossRef M. Kheradmandfard, S. Kashani-Bozorg, K. Kang, O.V. Penkov, A. Hanzaki, Y. Pyoun, A. Amanov, and D. Kim, Simultaneous Grain Refinement and Nanoscale Spinodal Decomposition of β Phase in Ti-Nb-Ta-Zr Alloy Induced by Ultrasonic Mechanical Impacts, J. Alloy. Compd., 2018, 738, p 540–549CrossRef
30.
Zurück zum Zitat Wu. Hejun and Jianqiu. Zhou, The Quantitative Understanding on the Influence of α″ Phase on Mechanical Behavior of Ti-Nb-Ta-Zr-O Alloy, J. Alloy. Compd., 2018, 768, p 914–923CrossRef Wu. Hejun and Jianqiu. Zhou, The Quantitative Understanding on the Influence of α″ Phase on Mechanical Behavior of Ti-Nb-Ta-Zr-O Alloy, J. Alloy. Compd., 2018, 768, p 914–923CrossRef
31.
Zurück zum Zitat Y.H. Li, C. Yang, F. Wang, H.D. Zhao, S.G. Qu, X.Q. Li, W.W. Zhang, and Y.Y. Li, Biomedical TiNbZrTaSi Alloys Designed by d-Electron Alloy Design Theory, Mater. Des., 2015, 85, p 7–13CrossRef Y.H. Li, C. Yang, F. Wang, H.D. Zhao, S.G. Qu, X.Q. Li, W.W. Zhang, and Y.Y. Li, Biomedical TiNbZrTaSi Alloys Designed by d-Electron Alloy Design Theory, Mater. Des., 2015, 85, p 7–13CrossRef
32.
Zurück zum Zitat B.Q. Li, F. Yan, and X. Lu, Effect of Microstructure on the Tensile Property of Porous Ti Produced by Powder Metallurgy Technique, Mater. Sci. Eng., C, 2012, 534, p 43–52CrossRef B.Q. Li, F. Yan, and X. Lu, Effect of Microstructure on the Tensile Property of Porous Ti Produced by Powder Metallurgy Technique, Mater. Sci. Eng., C, 2012, 534, p 43–52CrossRef
33.
Zurück zum Zitat Q.Q. Wei, L.Q. Wang, Y.F. Fu, J.N. Qin, W.J. Lu, and D. Zhang, Influence of Oxygen Content on Microstructure and Mechanical Properties of Ti-Nb-Ta-Zr Alloy, Mater. Des., 2011, 32, p 2934–2939CrossRef Q.Q. Wei, L.Q. Wang, Y.F. Fu, J.N. Qin, W.J. Lu, and D. Zhang, Influence of Oxygen Content on Microstructure and Mechanical Properties of Ti-Nb-Ta-Zr Alloy, Mater. Des., 2011, 32, p 2934–2939CrossRef
34.
Zurück zum Zitat M. Takemoto, S. Fujibayashi, M. Neo, J. Suzuki, T. Kokubo, and T. Nakamura, Mechanical Properties and Osteoconductivity of Porous Bioactive Titanium, Biomaterials, 2005, 26, p 6014–6023CrossRef M. Takemoto, S. Fujibayashi, M. Neo, J. Suzuki, T. Kokubo, and T. Nakamura, Mechanical Properties and Osteoconductivity of Porous Bioactive Titanium, Biomaterials, 2005, 26, p 6014–6023CrossRef
Metadaten
Titel
A Biomedical Ti-35Nb-5Ta-7Zr Alloy Fabricated by Powder Metallurgy
verfasst von
B. Q. Li
X. Lu
Publikationsdatum
04.09.2019
Verlag
Springer US
Erschienen in
Journal of Materials Engineering and Performance / Ausgabe 9/2019
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-019-04294-7

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