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Journal of Coatings Technology and Research

Erschienen in:

03.05.2018

A fluorine–silicone acrylic resin modified with UV-absorbing monomers and a free radical scavenger

verfasst von: Huibin Lei, Deliang He, Jun Hu, Ping Li, Haihong Huang

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 4/2018

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Abstract

A novel UV-absorbing and free-radical-catching fluorine–silicone acrylic resin with 2-(4-benzoyl-3-hydroxyphenoxy) ethyl acrylate (BHEA), 2,2,6,6-tetramethyl-4-piperidyl methacrylate (TMPM), dodecafluoroheptyl methacrylate (DFMA) and 3-methacryloxypropyltrimethoxysilane (MPS) as functional monomers was successfully synthesized by solution copolymerization. Based on various investigations, our characterization results for the resin and its coating indicated that the resin exhibits high UV-absorbing and free-radical-catching performances, and the hydrophobicity of the varnish coating was promoted by the actions of fluorine and silicone. In addition, the weatherability improved because of the enduring triple protection of the UV absorbent (BHEA), free-radical-catching agent (TMPM), fluorine (DFMA) and silicone (MPS). After a 1000-h aging test, the color difference (∆E) and rate of loss of gloss (∆G) of varnish coatings were 2.96% and 62%, respectively, and the impact strength and flexibility of color paint coatings were 420 N cm and 2 mm, respectively. Moreover, the chemically bonded free-radical-catching agent (TMPM) showed a more enduring performance for producing nitroxides than the simple blend.

Vorheriger Artikel Recent developments in the volatile corrosion inhibitor (VCI) coatings for metal: a review

Nächster Artikel Preparation in presence of urushiol and properties of acrylate latex with interparticle bridges

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Titel: A fluorine–silicone acrylic resin modified with UV-absorbing monomers and a free radical scavenger
verfasst von: Huibin Lei
Deliang He
Jun Hu
Ping Li
Haihong Huang
Publikationsdatum: 03.05.2018
Verlag: Springer US
Erschienen in: Journal of Coatings Technology and Research / Ausgabe 4/2018
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI: https://doi.org/10.1007/s11998-018-0078-z

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