Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 18/2020

10.08.2020

A high energy density flexible symmetric supercapacitor based on Al-doped MnO2 nanosheets @ carbon cloth electrode materials

verfasst von: Mengyao Xu, Ning Fu, Xiaodong Wang, Zhenglong Yang

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 18/2020

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The drawback of traditional capacitors with low energy density forces people to develop high-performance supercapacitor materials. Herein, the Al-doped MnO2 @ carbon cloth is selected as the ideal electrode material. A typical hydrothermal reaction can be used to synthesize Al-doped MnO2 @ carbon cloth at 150 °C for 4 h. Its operating window can be successfully expanded from 0–0.8 to 0–1.2 V, and the areal-specific capacitance reaches 1043 mF cm−2, keeping 91.1% of the original after cycling 5000 times at a current density of 20 mA cm−2. Using the electrode materials designed above, the flexible symmetrical supercapacitor is successfully assembled. This device shows a greater operating window of 0–2.3 V, a superior large areal-specific capacitance of 521.91 mF cm−2, and the energy density remarkably reaches 4.72 mWh cm−3. After 100 bending cycles, there is also basically no loss in performance. This study highlights the promising prospects of the improvement of MnO2 @ CC materials.
Vorheriger Artikel Synthesis and electrochemical properties of calcium cobaltate as novel anode material
Nächster Artikel Nitrogen-doped carbon/SiOx composites from rice husks as a high-performance anode for lithium-ion batteries

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Jetzt informieren
Anhänge
Nur mit Berechtigung zugänglich
Literatur
1.
X. He, X. Mao, C. Zhang, W. Yang, Y. Zhou, Y. Yang, J. Xu, Flexible binder-free hierarchical copper sulfide/carbon cloth hybrid supercapacitor electrodes and the application as negative electrodes in asymmetric supercapacitor. J. Mater. Sci. Mater. Electron. 31, 2145–2152 (2019)
2.
Y. Lv, A. Liu, Z. Shi, J. Mu, Z. Guo, X. Zhang, H. Che, Hierarchical MnCo2O4/NiMn layered double hydroxide composite nanosheet arrays on nickel foam for enhanced electrochemical storage in supercapacitors. ChemElectroChem 5, 3968–3979 (2018)
3.
H. Wang, C. Xu, Y. Chen, Y. Wang, MnO2 nanograsses on porous carbon cloth for flexible solid-state asymmetric supercapacitors with high energy density. Energy Storage Mater. 8, 127–133 (2017)
4.
A. Muzaffar, M. Basheer Ahamed, K. Deshmukh, Hydrothermal synthesis of ZnWO4–MnO2 nanopowder doped with carbon black nanoparticles for high-performance supercapacitor applications. J. Mater. Sci. Mater. Electron. 30, 21250–21258 (2019)
5.
A.G. Pandolfo, A.F. Hollenkamp, Carbon properties and their role in supercapacitors. J. Power Sources 157, 11–27 (2006)
6.
G. Moreno-Fernandez, M. Kunowsky, M.Á. Lillo-Ródenas, J. Ibañez, J.M. Rojo, New carbon monoliths for supercapacitor electrodes. Looking at the double layer. ChemElectroChem 4, 1016–1025 (2017)
7.
Z. Song, H. Duan, D. Zhu, Y. Lv, W. Xiong, T. Cao, L. Li, M. Liu, L. Gan, Ternary-doped carbon electrodes for advanced aqueous solid-state supercapacitors based on a “water-in-salt” gel electrolyte. J. Mater. Chem. A 7, 15801–15811 (2019)
8.
J. Chen, H. Wei, H. Chen, W. Yao, H. Lin, S. Han, N/P co-doped hierarchical porous carbon materials for superior performance supercapacitors. Electrochim. Acta 271, 49–57 (2018)
9.
J. Zhang, Y. Wang, C. Yu, T. Zhu, Y. Li, J. Cui, J. Wu, X. Shu, Y. Qin, J. Sun, J. Yan, Y. Zhang, Y. Wu, Hierarchical NiCo2O4/MnO2 core–shell nanosheets arrays for flexible asymmetric supercapacitor. J. Mater. Sci. 55, 688–700 (2019)
10.
H. Chen, J. Li, C. Long, T. Wei, G. Ning, J. Yan, Z. Fan, Nickel sulfide/graphene/carbon nanotube composites as electrode material for the supercapacitor application in the sea flashing signal system. J. Mar. Sci. Appl. 13, 462–466 (2014)
11.
A. Bello, K. Makgopa, M. Fabiane, D. Dodoo-Ahrin, K.I. Ozoemena, N. Manyala, Chemical adsorption of NiO nanostructures on nickel foam-graphene for supercapacitor applications. J. Mater. Sci. 48, 6707–6712 (2013)
12.
H. Jiang, T. Zhao, C. Yan, J. Ma, C. Li, Hydrothermal synthesis of novel Mn3O4 nano-octahedrons with enhanced supercapacitors performances. Nanoscale 2, 2195–2198 (2010)
13.
R. Wang, X. Yan, J. Lang, Z. Zheng, P. Zhang, A hybrid supercapacitor based on flower-like Co(OH)2 and urchin-like VN electrode materials. J. Mater. Chem. A 2, 12724–12732 (2014)
14.
J. Li, W. Zhao, F. Huang, A. Manivannan, N. Wu, Single-crystalline Ni(OH)2 and NiO nanoplatelet arrays as supercapacitor electrodes. Nanoscale 3, 5103–5109 (2011)
15.
V. Subramanian, Mesoporous anhydrous RuO2 as a supercapacitor electrode material. Solid State Ion. 175, 511–515 (2004)
16.
T. Zhu, J.S. Chen, X.W. Lou, Shape-controlled synthesis of porous Co3O4 nanostructures for application in supercapacitors. J. Mater. Chem. 20, 7015–7020 (2010)
17.
Z. Tang, C.-H. Tang, H. Gong, A high energy density asymmetric supercapacitor from nano-architectured Ni(OH)2/carbon nanotube electrodes. Adv. Funct. Mater. 22, 1272–1278 (2012)
18.
S. He, W. Chen, Application of biomass-derived flexible carbon cloth coated with MnO2 nanosheets in supercapacitors. J. Power Sources 294, 150–158 (2015)
19.
P.A. Shinde, V.C. Lokhande, T. Ji, C.D. Lokhande, Facile synthesis of hierarchical mesoporous weirds-like morphological MnO2 thin films on carbon cloth for high performance supercapacitor application. J. Colloid Interface Sci. 498, 202–209 (2017)
20.
D. Guo, X. Yu, W. Shi, Y. Luo, Q. Li, T. Wang, Facile synthesis of well-ordered manganese oxide nanosheet arrays on carbon cloth for high-performance supercapacitors. J. Mater. Chem. A 2, 8833–8838 (2014)
21.
Z. Xu, S. Sun, W. Cui, J. Lv, Y. Geng, H. Li, J. Deng, Interconnected network of ultrafine MnO2 nanowires on carbon cloth with weed-like morphology for high-performance supercapacitor electrodes. Electrochim. Acta 268, 340–346 (2018)
22.
Q. Zong, Q. Zhang, X. Mei, Q. Li, Z. Zhou, D. Li, M. Chen, F. Shi, J. Sun, Y. Yao, Z. Zhang, Facile synthesis of Na-doped MnO2 nanosheets on carbon nanotube fibers for ultrahigh-energy-density all-solid-state wearable asymmetric supercapacitors. ACS Appl. Mater. Interfaces 10, 37233–37241 (2018)
23.
R. Poonguzhali, N. Shanmugam, R. Gobi, A. Senthilkumar, G. Viruthagiri, N. Kannadasan, Effect of Fe doping on the electrochemical capacitor behavior of MnO2 nanocrystals. J. Power Sources 293, 790–798 (2015)
24.
A.M. Hashem, H.M. Abuzeid, N. Narayanan, H. Ehrenberg, C.M. Julien, Synthesis, structure, magnetic, electrical and electrochemical properties of Al, Cu and Mg doped MnO2. Mater. Chem. Phys. 130, 33–38 (2011)
25.
Z. Hu, X. Xiao, L. Huang, C. Chen, T. Li, T. Su, X. Cheng, L. Miao, Y. Zhang, J. Zhou, 2D vanadium doped manganese dioxides nanosheets for pseudocapacitive energy storage. Nanoscale 7, 16094–160949 (2015)
26.
J. Li, Y. Ren, S. Wang, Z. Ren, J. Yu, Transition metal doped MnO2 nanosheets grown on internal surface of macroporous carbon for supercapacitors and oxygen reduction reaction electrocatalysts. Appl. Mater. Today 3, 63–72 (2016)
27.
C. Tang, X. Wei, Y. Jiang, X. Wu, L. Han, K. Wang, J. Chen, Cobalt-doped MnO2 hierarchical yolk-shell spheres with improved supercapacitive performance. J. Phys. Chem. C 119, 8465–8471 (2015)
28.
Z. Yang, X. Wang, Y. Huang, First-principles study on the doping effects of Al in α-MnO2. Curr. Appl. Phys. 15, 1556–1561 (2015)
29.
C. Yuan, J. Li, L. Hou, X. Zhang, L. Shen, X.W.D. Lou, Ultrathin mesoporous NiCo2O4 nanosheets supported on Ni foam as advanced electrodes for supercapacitors. Adv. Funct. Mater. 2, 4592–4597 (2012)
30.
J. Yang, L. Lian, H. Ruan, F. Xie, M. Wei, Nanostructured porous MnO2 on Ni foam substrate with a high mass loading via a CV electrodeposition route for supercapacitor application. Electrochim. Acta 136, 189–194 (2014)
31.
L. Yu, G. Zhang, C. Yuan, X.W. Lou, Hierarchical NiCo2O4@MnO2 core–shell heterostructured nanowire arrays on Ni foam as high-performance supercapacitor electrodes. Chem. Commun. 49, 137–139 (2013)
32.
J. Yan, Z. Fan, T. Wei, W. Qian, M. Zhang, F. Wei, Fast and reversible surface redox reaction of graphene–MnO2 composites as supercapacitor electrodes. Carbon 48, 3825–3833 (2010)
33.
Y. Liu, L. Guo, X. Teng, J. Wang, T. Hao, X. He, Z. Chen, High-performance 2.5 V flexible aqueous asymmetric supercapacitors based on K+/Na+-inserted MnO2 nanosheets. Electrochim. Acta 300, 9–17 (2019)
34.
H. Wei, J. Wang, S. Yang, W. Wang, D. Hou, T. Li, Synthesis of 3D mesoporous wall-like MnO2 with improved electrochemical performance. J. Electron. Mater. 46, 1539–1545 (2016)
35.
N. Fu, J. Yu, J. Zhao, R. Liu, F. Li, Y. Du, Z. Yang, In-situ preparation of nitrogen-doped unimodal ultramicropore carbon nanosheets with ultrahigh gas selectivity. Carbon 149, 538–545 (2019)
36.
N.C. Maile, S.K. Shinde, R.T. Patil, A.V. Fulari, R.R. Koli, D.Y. Kim, D.S. Lee, V.J. Fulari, Structural and morphological changes in binder-free MnCo2O4 electrodes for supercapacitor applications: effect of deposition parameters. J. Mater. Sci. Mater. Electron. 30, 3729–3743 (2019)
37.
J. Wang, Y. Yang, Z. Huang, F. Kang, Synthesis and electrochemical performance of MnO2/CNTs-embedded carbon nanofibers nanocomposites for supercapacitors. Electrochim. Acta 75, 213–219 (2012)
38.
W. Yao, J. Wang, H. Li, Y. Lu, Flexible α-MnO2 paper formed by millimeter-long nanowires for supercapacitor electrodes. J. Power Sources 247, 824–830 (2014)
39.
L. Yin, I. Adler, T. Tsang, L.J. Matienzo, S.O. Grim, Paramagnetism and shake-up satellites in X-ray photoelectron spectra. Chem. Phys. Lett. 24, 81–84 (1974)
40.
J.P. Holgado, G. Munuera, J.P. Espinós, A.R. González-Elipe, XPS study of oxidation processes of CeOx defective layers. Appl. Surf. Sci. 158, 164–171 (2000)
41.
Z. Song, H. Duan, L. Li, D. Zhu, T. Cao, Y. Lv, W. Xiong, Z. Wang, M. Liu, L. Gan, High-energy flexible solid-state supercapacitors based on O, N, S-tridoped carbon electrodes and a 3.5 V gel-type electrolyte. Chem. Eng. J. 372, 1216–1225 (2019)
42.
J. Yu, N. Fu, J. Zhao, R. Liu, F. Li, Y. Du, Z. Yang, High specific capacitance electrode material for supercapacitors based on resin-derived nitrogen-doped porous carbons. ACS Omega 4, 15904–15911 (2019)
43.
K.M. Nam, D.H. Shin, N. Jung, M.G. Joo, S. Jeon, S.M. Park, B.Y. Chang, Development of galvanostatic Fourier transform electrochemical impedance spectroscopy. Anal. Chem. 85, 2246–2252 (2013)
44.
L.-D. Chen, Y.-Q. Zheng, H.-L. Zhu, Manganese oxides derived from Mn(II)-based metal–organic framework as supercapacitor electrode materials. J. Mater. Sci. 53, 1346–1355 (2017)
45.
D. Xue, D. Zhu, H. Duan, Z. Wang, Y. Lv, W. Xiong, L. Li, M. Liu, L. Gan, Deep-eutectic-solvent synthesis of N/O self-doped hollow carbon nanorods for efficient energy storage. Chem. Commun. 55, 11219–11222 (2019)
46.
S. Chen, J. Zhu, Q. Han, Z. Zheng, Y. Yang, X. Wang, Shape-controlled synthesis of one-dimensional MnO2 via a facile quick-precipitation procedure and its electrochemical properties. Cryst. Growth Des. 9, 4356–4361 (2009)
47.
J.P. Alper, M.S. Kim, M. Vincent, B. Hsia, V. Radmilovic, C. Carraro, R. Maboudian, Silicon carbide nanowires as highly robust electrodes for micro-supercapacitors. J. Power Sources 230, 298–302 (2013)
48.
T. Qin, H. Chen, Y. Zhang, X. Chen, L. Liu, D. Yan, S. Ma, J. Hou, F. Yu, S. Peng, Modulating surface chemistry of heteroatom-rich micropore carbon cloth electrode for aqueous 2.1 V high-voltage window all-carbon supercapacitor. J. Power Sources 431, 232–238 (2019)
49.
L. Wang, H. Yang, X. Liu, R. Zeng, M. Li, Y. Huang, X. Hu, Constructing hierarchical tectorum-like α-Fe2O3/PPy nanoarrays on carbon cloth for solid-state asymmetric supercapacitors. Angew. Chem. Int. Ed. 56, 1125–1130 (2017)
50.
W. Zilong, Z. Zhu, J. Qiu, S. Yang, High performance flexible solid-state asymmetric supercapacitors from MnO2/ZnO core–shell nanorods//specially reduced graphene oxide. J. Mater. Chem. C 2, 1331–1336 (2014)
51.
S. Zhai, H.E. Karahan, L. Wei, X. Chen, Z. Zhou, X. Wang, Y. Chen, Hydrothermal assembly of micro-nano-integrated core-sheath carbon fibers for high-performance all-carbon micro-supercapacitors. Energy Storage Mater. 9, 221–228 (2017)
52.
C. Choi, H.J. Sim, G.M. Spinks, X. Lepró, R.H. Baughman, S.J. Kim, Elastomeric and dynamic MnO2/CNT core–shell structure coiled yarn supercapacitor. Adv. Energy Mater. 6, 1502119 (2016)
53.
X. Li, X. Deng, Q. Li, S. Huang, K. Xiao, Z. Liu, Y. Tong, Hierarchical double-shelled poly(3,4-ethylenedioxythiophene) and MnO2 decorated Ni nanotube arrays for durable and enhanced energy storage in supercapacitors. Electrochim. Acta 264, 46–52 (2018)
54.
P. Yang, Y. Ding, Z. Lin, Z. Chen, Y. Li, P. Qiang, M. Ebrahimi, W. Mai, C.P. Wong, Z.L. Wang, Low-cost high-performance solid-state asymmetric supercapacitors based on MnO2 nanowires and Fe2O3 nanotubes. Nano Lett. 14, 731–736 (2014)
55.
H. Zhang, D. Xiao, Q. Li, Y. Ma, S. Yuan, L. Xie, C. Chen, C. Lu, Porous NiCo2O4 nanowires supported on carbon cloth for flexible asymmetric supercapacitor with high energy density. J. Energy Chem. 27, 195–202 (2018)
56.
W. Liu, K. Feng, Y. Zhang, T. Yu, L. Han, G. Lui, M. Li, G. Chiu, P. Fung, A. Yu, Hair-based flexible knittable supercapacitor with wide operating voltage and ultra-high rate capability. Nano Energy 34, 491–499 (2017)
57.
Y. Liu, X. Miao, J. Fang, X. Zhang, S. Chen, W. Li, W. Feng, Y. Chen, W. Wang, Y. Zhang, Layered-MnO2 nanosheet grown on nitrogen-doped graphene template as a composite cathode for flexible solid-state asymmetric supercapacitor. ACS Appl. Mater. Interfaces 8, 5251–5260 (2016)
Metadaten
Titel
A high energy density flexible symmetric supercapacitor based on Al-doped MnO2 nanosheets @ carbon cloth electrode materials
verfasst von
Mengyao Xu
Ning Fu
Xiaodong Wang
Zhenglong Yang
Publikationsdatum
10.08.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 18/2020
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-020-04165-1

Weitere Artikel der Ausgabe 18/2020

Journal of Materials Science: Materials in Electronics 18/2020 Zur Ausgabe

Publisher Correction

Correction to: A novel impedimetric sensor for trace level detection of dimethyl sulfide (DMS)

OriginalPaper

Graphene/polyaniline nanocomposites: effect of in-situ polymerization and solvent blending methods with dodecylbenzene sulfonic acid surfactant

OriginalPaper

Study the magnetic and dielectric properties of Sn substituted nickel–cobalt ferrite synthesized by auto combustion method

OriginalPaper

The role of a nonconductive film (NCF) on Cu/Ni/Sn-Ag microbump interconnect reliability

OriginalPaper

Vertically aligned ZnO/In2S3 core/shell heterostructures with enhanced photoelectrochemical properties

OriginalPaper

Synthesis and electrochemical properties of calcium cobaltate as novel anode material

Neuer Inhalt

    Bildnachweise