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Adsorption

Erschienen in:

28.04.2020

A novel blended amine functionalized porous silica adsorbent for carbon dioxide capture

verfasst von: Peiyu Zhao, Guojie Zhang, Lanxia Hao

Erschienen in: Adsorption | Ausgabe 5/2020

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Abstract

In order to accomplish efficient CO₂ capture, poly(ethyleneimine) (PEI) and tetraethylenepentamine (TEPA), with commonly used and inexpensive, was codispersed into the as-prepared SBA-15 (SBA-15(p)) to prepared blended amine functionalized adsorbent. The influence of the mass ratio of PEI to TEPA on the adsorption property was investigated. The promoting effects of TEPA on CO₂ capture property were investigated. The adsorbents were characterized using N₂ adsorption/desorption, Fourier transform infrared spectroscopy (FTIR), Transmission electron microscope (TEM) and in situ diffuse reflectance infrared fourier transform spectroscopy (in situ DRIFTS). Among the prepared adsorbents, the SBA-15(p) with 30 wt% PEI and 40 wt% TEPA has the CO₂ capture capacity of 4.64 mmol/g and the optimal amine efficiency (0.359 molCO₂/molN) at 75 °C with 20 vol% CO₂ in N₂. The addition of TEPA species could improve the CO₂ adsorption amount with high amine utilization. The P123 with wheel-like distribution in SBA-15(p) promotes the CO₂ capture by optimizing the accessibility of amine to the CO₂. After 15 adsorption cycles, the SBA-15(p) with 40 wt% PEI and 30 wt% TEPA has better reusability and cyclic performance, the adsorption capacity can keep around 4.13 mmol/g. The result indicated that more PEI in the adsorbent would improve the adsorbent cyclic stability. Meanwhile, the in-situ DRIFTS results suggested that the reaction of CO₂ molecule with the amine active sites in the adsorbent, agrees with anionic and cationic mechanisms.

Vorheriger Artikel Ionic liquid loaded polyether sulfone microspheres for CO2 separation

Nächster Artikel Measurement of competitive and adsorption on zeolite 13X for post-combustion capture

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Titel: A novel blended amine functionalized porous silica adsorbent for carbon dioxide capture
verfasst von: Peiyu Zhao
Guojie Zhang
Lanxia Hao
Publikationsdatum: 28.04.2020
Verlag: Springer US
Erschienen in: Adsorption / Ausgabe 5/2020
Print ISSN: 0929-5607
Elektronische ISSN: 1572-8757
DOI: https://doi.org/10.1007/s10450-020-00238-z

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