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01.01.2019 | Original Research

A novel deep eutectic solvent from lignin-derived acids for improving the enzymatic digestibility of herbal residues from cellulose

verfasst von: Long Chen, Qiang Yu, Qiong Wang, Wen Wang, Wei Qi, Xinshu Zhuang, Zhongming Wang, Zhenhong Yuan

Erschienen in: Cellulose | Ausgabe 3/2019

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Abstract

A novel lignin-derived deep eutectic solvent (DES) was synthesized from choline chloride (ChCl) and p-coumaric acid (PCA). The results showed that after pretreatment with lignin-derived DES, the dense cellulose–hemicellulose–lignin structure of herb residues of Cortex albiziae (HRCA) was effectively broken down and this facilitated subsequent enzymatic hydrolysis. The optimum pretreatment conditions were ChCl/PCA molar ratio of 1:1, 160 °C-5 h, and a solid–liquid ratio of 1:10. Compared with untreated HRCA, 72-h enzymatic digestibility increased from 48.08 to 84.62%. When a ChCl–PCA–water pretreatment was used, the 72-h digestibility level of the residue reached 99.36%. Moreover, the recycling and reusability of this novel DES were evaluated. The results showed that synthesis and utilization of green, environment-friendly and recyclable lignin-derived DES can offer a new way of utilizing lignin which has considerable potential in the refining of biomass.

Graphical abstract

A novel lignin-derived deep eutectic solvent was synthesized, this DES pretreatment can improve the enzymatic digestibility of HCRA cellulose efficiently.

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Titel: A novel deep eutectic solvent from lignin-derived acids for improving the enzymatic digestibility of herbal residues from cellulose
verfasst von: Long Chen
Qiang Yu
Qiong Wang
Wen Wang
Wei Qi
Xinshu Zhuang
Zhongming Wang
Zhenhong Yuan
Publikationsdatum: 01.01.2019
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 3/2019
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-018-2190-8

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