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Journal of Materials Science
Erschienen in: Journal of Materials Science 22/2016

22.07.2016 | Original Paper

A novel PAN/NaX/ZnO nanocomposite absorbent: synthesis, characterization, removal of uranium anionic species from contaminated water

verfasst von: H. R. Shakur, Kh. Rezaee Ebrahim Saraee, M. R. Abdi, G. Azimi

Erschienen in: Journal of Materials Science | Ausgabe 22/2016

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Abstract

In this study, a novel PAN/NaX/ZnO nanocomposite absorbent was introduced and its ability to remove of uranium anionic species, which are the most dominant species of uranium in water at natural pH, from contaminated waters was studied. In this regards, micro and nano sized NaX zeolite and PAN/NaX/ZnO nanocomposite were successfully synthesized and characterized using various methods, including X-ray powder diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), Fourier transforms infrared spectroscopy (FT-IR), atomic absorption spectroscopy (AAS), and Brunauer–Emmett–Teller (BET) specific surface area analysis. Batch technique was used to study the adsorption behavior of uranium ions from contaminated water as a function of solid–liquid ratio, initial uranium concentration, contact time, and temperature. Results showed that although NaX nanozeolite due to its negative framework charge, showed low sorption capacity for adsorption of uranium anionic species but the composite of it with ZnO nanoparticles and polyacrylonitrile (PAN) effectively improved its uranium adsorption capacity. The novel PAN/NaX/ZnO nanocomposite could selectively remove uranium ions from contaminated water with removal efficiency of more than 98.65 % in the presence of all anions and cations which are available in waters.
Vorheriger Artikel Local deformation in a hydrogel induced by an external magnetic field
Nächster Artikel Aligned carbon nanotube–epoxy composites: the effect of nanotube organization on strength, stiffness, and toughness

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Literatur
1.
Stalder E, Blanc A, Haldimann M, Dudler V (2012) Occurrence of uranium in Swiss drinking water. Chemosphere 86:672–679CrossRef
2.
Birke M, Rauch U, Lorenz H, Kringel R (2010) Distribution of uranium in German bottled and tap water. J Geochem Explor 107:272–282CrossRef
3.
Nriagu J, Nam DH, Ayanwola TA, Dinh H, Erdenechimeg E, Ochir C, Bolorma TA (2012) High levels of uranium in groundwater of Ulaanbaatar, Mongolia. Sci Total Environ 414:722–726CrossRef
4.
Katsoyiannis IA, Zouboulis AI (2013) Removal of uranium from contaminated drinking water: a mini review of available treatment methods. Desalination Water Treat 51:2915–2925CrossRef
5.
Sarri S, Misaelides P, Zamboulis D, Papadopoulou L, Warcho J (2013) Removal of uranium anionic species from aqueous solutions by polyethylenimine–epichlorohydrin resins. J Radioanal Nucl Chem 295:1731–1736CrossRef
6.
Barczyk K, Mozgawa W, Krol M (2014) Studies of anions sorption on natural zeolites. Spectrochim Acta Part A Mol Biomol Spectrosc 133:876–882CrossRef
7.
Onyango MS, Kojima Y, Aoyi O, Bernardo EC, Matsuda H (2004) Adsorption equilibrium modeling and solution chemistry dependence of fluoride removal from water by trivalent-cation-exchanged zeolite F-9. J Colloid Interface Sci 279:341–350CrossRef
8.
Verbinnen B, Block C, Hannes D, Lievens P, Vaclavikova M, Stefusova K, Gallios G, Vandecasteele C (2012) Removal of molybdate anions from water by adsorption on zeolite-supported magnetite. Water Environ Res 84(9):753–760CrossRef
9.
Sharafzadeh S, Nezamzadeh-Ejhieh A (2015) Using of anionic adsorption property of a surfactant modified clinoptilolite nano-particles in modification of carbon paste electrode as effective ingredient for determination of anionic ascorbic acid species in presence of cationic dopamine species. Electrochim Acta 184:371–380CrossRef
10.
Nezamzadeh-Ejhieh A, Tavakoli-Ghinani S (2014) Effect of a nano-sized natural clinoptilolite modified by the hexadecyltrimethyl ammonium surfactant on cephalexin drug delivery. C R Chim 17:49–61CrossRef
11.
Nezamzadeh-Ejhieh A, Shahanshahi M (2013) Modification of clinoptilolite nano-particles with hexadecylpyridynium bromide surfactant as an active component of Cr(VI) selective electrode. J Ind Eng 19:2026–2033CrossRef
12.
Nezamzadeh-Ejhieh A, Esmaeilian A (2012) Application of surfactant modified zeolite carbon paste electrode (SMZ-CPE) towards potentiometric determination of sulfate. Microporous Mesoporous Mater 147:302–309CrossRef
13.
Nezamzadeh-Ejhieh A, Afshari A (2012) Modification of a PVC-membrane electrode by surfactant modified clinoptilolite zeolite towards potentiometric determination of sulfide. Microporous Mesoporous Mater 153:267–274CrossRef
14.
Naghash A, Nezamzadeh-Ejhieh A (2015) Comparison of the efficiency of modified clinoptilolite with HDTMA and HDP surfactants for the removal of phosphate in aqueous solutions. J Ind Eng Chem 31:185–191CrossRef
15.
Hasheminejad M, Nezamzadeh-Ejhieh A (2015) A novel citrate selective electrode based on surfactant modified nano-clinoptilolite. Food Chem 172:794–801CrossRef
16.
Camacho LM, Parra RR, Deng S (2011) Arsenic removal from groundwater by MnO2-modified natural clinoptilolite zeolite: Effects of pH and initial feed concentration. J Hazard Mater 189:286–293CrossRef
17.
Taffarel SR, Rubio J (2010) Removal of Mn2+ from aqueous solution by manganese oxide coated zeolite. Miner Eng 23:1131–1138CrossRef
18.
Brazlauskas M, Kitrys S (2008) Synthesis and properties of CuO/zeolite sandwich type adsorbent-catalysts. Chin J Catal 29(1):25–30CrossRef
19.
Xu R, Pang W, Yu J, Huo Q, Chen J (2007) Chemistry of Zeolites and Related Porous Materials: Synthesis and Structure. John Wiley & Sons (Asia) Pte Ltd
20.
Qian L, Yan ZF (2001) Micropore modification of zeolites with transition-metal oxides. Colloids Surf A 180:311–316CrossRef
21.
Fan FL, Qin Z, Bai J, Rong WD, Fan FY, Tian W, Lei WX, Wang Y, Zhao L (2012) Rapid removal of uranium from aqueous solutions using magnetic Fe3O4@SiO2 composite particles. J Environ Radioact 106:40–46CrossRef
22.
Wei J, Zhang X, Liu Q, Li Z, Liu L, Wang J (2014) Magnetic separation of uranium by CoFe2O4 hollow spheres. Chem Eng J 241:228–234CrossRef
23.
Zong P, Wang H, Pan H, Zhao Y, He C (2013) Application of NKF-6 zeolite for the removal of U(VI) from aqueous solution. J Radioanal Nucl Chem 295:1969–1979CrossRef
24.
Wang G, Wang X, Chai X, Liu J, Deng N (2010) Adsorption of uranium (VI) from aqueous solution on calcined and acid-activated kaolin. Appl Clay Sci 47:448–451CrossRef
25.
Chen S, Hong J, Yang H, Yang J (2013) Adsorption of uranium (VI) from aqueous solution using a novel graphene oxide-activated carbon felt composite. Journal of Environmental Radioactivity 126:253e258
26.
Abdi MR, Shakur HR, Rezaee Ebrahim Saraee K, Sadeghi M (2014) Effective removal of uranium ions from drinking water using CuO/X zeolite based nanocomposites: effects of nano concentration and cation exchange. J Radioanal Nucl Chem 300:1217–1225CrossRef
27.
Singh BK, Tomar R, Tomar R, Tomar SS (2011) Sorption of homologues of radionuclides by synthetic ion exchanger. Microporous Mesoporous Mater 142:629–640CrossRef
28.
Shakur HR (2011) A detailed study of physical properties of ZnS quantum dots synthesized by reverse micelle method. Physica E 44:641–646CrossRef
29.
Nezamzadeh-Ejhieh A, Karimi-Shamsabadi M (2014) Comparison of photocatalytic efficiency of supported CuO onto micro and nano particles of zeolite X in photodecolorization of Methylene blue and Methyl orange aqueous mixture. Appl Catal A 477:83–92CrossRef
30.
Bouvy C, Marine W, Sporken R, Su BL (2007) Nanosized ZnO confined inside a Faujasite X zeolite matrix: characterization and optical properties. Colloids Surf A 300:145–149CrossRef
31.
Sudha G, Subramanian E (2015) Synthesis, characterization and photocatalytic study of cerium oxide/zeolite-NaX catalyst with brilliant green dye degradation. J Adv Chem Sci 1(3):117–120
32.
Huang M, Xu C, Wu Z, Huang Y, Lin J, Wu J (2008) Photocatalytic discolorization of methyl orange solution by Pt modified TiO2 loaded on natural zeolite. Dyes Pigm 77:327–334CrossRef
33.
Nezamzadeh-Ejhieh A, Karimi-Shamsabadi M (2013) Decolorization of a binary azo dyes mixture using CuO incorporated nanozeolite-X as a heterogeneous catalyst and solar irradiation. Chem Eng J 228:631–641CrossRef
34.
Nilchi A, Saberi R, Moradi M, Azizpour H, Zarghami R (2011) Adsorption of cesium on copper hexacyanoferrate–PAN composite ion exchanger from aqueous solution. Chem Eng J 172:572–580CrossRef
35.
Miao P, Wu D, Zeng K, Xu G, Zhao C, Yang G (2010) Influence of electron beam pre-irradiation on the thermal behaviors of polyacrylonitrile. Polym Degrad Stab 95:1665–1671CrossRef
36.
Kiani GR, Sheikhloie H, Arsalani N (2011) Heavy metal ion removal from aqueous solutions by functionalized polyacrylonitrile. Desalination 269:266–270CrossRef
37.
Nezamzadeh-Ejhieh A, Hushmandrad S (2010) Solar photodecolorization of methylene blue by CuO/X zeolite as a heterogeneous catalyst. Appl Catal A 388:149–159CrossRef
38.
Zeng Zhan B, Anne White M, Lumsden M, Mueller-Neuhaus J, Robertson KN, Stanley Cameron T, Gharghouri M (2002) Control of particle size and surface properties of Crystals of NaX Zeolite. Chem Mater 14:3636–3642CrossRef
39.
Faghihian H, Riazi L (2013) Dearomatization of normal paraffin by adsorption process using synthesized NaX zeolite. Pet Sci 10:408–414CrossRef
40.
Fathizadeh M, Aroujaliana A, Raisi A (2011) Effect of added NaX nano-zeolite into polyamide as a top thin layer of membrane on water flux and salt rejection in a reverse osmosis process. J Membr Sci 375:88–95CrossRef
41.
Camacho LM, Denga S, Parra RR (2010) Uranium removal from groundwater by natural clinoptilolite zeolite: Effects of pH and initial feed concentration. J Hazard Mater 175:393–398CrossRef
42.
Chao HP, Chen SH (2012) Adsorption characteristics of both cationic and oxyanionic metal ions on hexadecyltrimethylammonium bromide-modified NaY zeolite. Chem Eng J 193–194:283–289CrossRef
43.
Kazansky VB, Borovkov VY, Serykh AI, Santen RAV, Stobbelaar PJ (1999) On the role of zinc oxide nanometric clusters in preparation of ZnNaY zeolite by ion exchange. Phys Chem Chem Phys 1:2881–2886CrossRef
44.
Kaynar UH, Ayvacıklı M, Kaynar SC, Hicsonmez U (2014) Removal of uranium(VI) from aqueous solutions using nanoporous ZnO prepared with microwave-assisted combustion synthesis. J Radioanal Nucl Chem 299:1469–1477CrossRef
45.
Ho YS, McKay G (1999) Pseudo-second order model for sorption processes. Process Biochem 34:451–465CrossRef
46.
Anari-Anaraki M, Nezamzadeh-Ejhieh A (2015) Modification of an Iranian clinoptilolite nano-particles by hexadecyltrimethyl ammonium cationic surfactant and dithizone for removal of Pb(II) from aqueous solution. J Colloid Interface Sci 440:272–281CrossRef
47.
Borandegi M, Nezamzadeh-Ejhieh A (2015) Enhanced removal efficiency of clinoptilolite nano-particles toward Co(II) from aqueous solution by modification with glutamic acid. Colloids Surf A Physicochem Eng Asp 479:35–45CrossRef
48.
Huang H, Xiao H, Yan B, Yang L (2010) Ammonium removal from aqueous solutions by using natural Chinese (Chende) zeolite as adsorbent. J Hazard Mater 175:247–252CrossRef
49.
Song X, Wang S, Chen L, Zhang M, Dong Y (2009) Effect of pH, ionic strength and temperature on the sorption of radionickel on Na-montmorillonite. Appl Radiat Isot 67:1007–1012CrossRef
50.
Perez-Marın AB, Meseguer Zapata V, Ortuno JF, Aguilar M, Saez J, Llorens M (2007) Removal of cadmium from aqueous solutions by adsorption onto orange waste. J Hazard Mater B 139:122–131CrossRef
51.
Limousin G, Gaudet JP, Charlet L, Szenknect S, Barthes V, Krimissa M (2007) Sorption isotherms: a review on physical bases, modeling and measurement. Appl Geochem 22:249–275CrossRef
52.
Heidari-Chaleshtori M, Nezamzadeh-Ejhieh A (2015) Clinoptilolite nano-particles modified with aspartic acid for removal of Cu(II) from aqueous solutions: isotherms and kinetic aspects. New J Chem 39:9396–9406CrossRef
Metadaten
Titel
A novel PAN/NaX/ZnO nanocomposite absorbent: synthesis, characterization, removal of uranium anionic species from contaminated water
verfasst von
H. R. Shakur
Kh. Rezaee Ebrahim Saraee
M. R. Abdi
G. Azimi
Publikationsdatum
22.07.2016
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 22/2016
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-016-0227-7

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