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Journal of Nanoparticle Research
Erschienen in: Journal of Nanoparticle Research 4/2019

01.04.2019 | Research Paper

A PEG-grafted carbon hybrid as sulfur host for high-performance lithium-sulfur batteries

verfasst von: Jin Guo, Mingang Zhang, Xiaoyan Yan, Shushan Yao, Xiangyu Cao, Jiansheng Liu

Erschienen in: Journal of Nanoparticle Research | Ausgabe 4/2019

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Abstract

Sulfur, as a cathode material for lithium-sulfur batteries, has a highly theoretical capacity of 1672 mAh g−1. However, the diffusion and dissolution of intermediate polysulfides and volume changes result in a rapid decay of capacity. In this work, an acidifying acetylene black/carbon nanotubes@sulfur (H-AB/CNTs@S) hybrid electrode material with a 3D interlinked network structure has been synthesized by grafting polyethylene glycol (PEG) and then depositing elemental sulfur on the commercial H-AB/CNTs hybrid surface. The H-AB/CNTs@S hybrids are characterized by Fourier transform infrared (FTIR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and electrochemical methods. The H-AB/CNTs hybrid substrate provides electrons and Li ion transfer pathway for the sulfur electrode. The PEG chains with abundant hydrophilic functional groups can help alleviate the diffusion of hydrophilic polysulfides. As a result, the H-AB/CNTs@S hybrid electrode with PEG delivers a high initial discharge capacity of 1380 mAh g−1 at a current density of 0.1 C and remains at 923 mAh g−1 after 100 cycles.
Vorheriger Artikel Correlation between the rate of silver nanoparticle oxidation and their biological activity: the role of the capping agent
Nächster Artikel Improved small-angle x-ray scattering of nanoparticle self-assembly using a cell with a flat liquid surface

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Metadaten
Titel
A PEG-grafted carbon hybrid as sulfur host for high-performance lithium-sulfur batteries
verfasst von
Jin Guo
Mingang Zhang
Xiaoyan Yan
Shushan Yao
Xiangyu Cao
Jiansheng Liu
Publikationsdatum
01.04.2019
Verlag
Springer Netherlands
Erschienen in
Journal of Nanoparticle Research / Ausgabe 4/2019
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-019-4507-4

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