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Journal of Materials Science
Erschienen in: Journal of Materials Science 29/2020

10.07.2020 | Review

A review of the electrocatalysts on hydrogen evolution reaction with an emphasis on Fe, Co and Ni-based phosphides

verfasst von: Zhenhua Ge, Bin Fu, Jinping Zhao, Xing Li, Bo Ma, Yantao Chen

Erschienen in: Journal of Materials Science | Ausgabe 29/2020

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Abstract

Hydrogen fuel receives worldwide attention for the zero emission and high energy density. Production of hydrogen by electrochemical water splitting requires efficient electrocatalysts to boost the hydrogen evolution reaction (HER). Transition metal phosphides are regarded as promising substitutes for precious metals as HER electrocatalysts. This review focuses on the recent progress with respect to the advantages, common synthetic approaches and enhancement strategies of Fe, Co and Ni-based phosphides, with important works in each section elaborately introduced for researchers in the relevant area. After the rational design and fabrication, Fe, Co and Ni-based phosphides can become highly efficient, durable and cost-effective electrocatalysts, and thereby exhibit a great potential for the scale-up production of hydrogen fuel.
Vorheriger Artikel 1000 at 1000: transforming titania take two
Nächster Artikel Formation of single-crystal Cu2O strips in non-single-crystal CuO thin films by continuous-wave laser diode with micro-chevron laser beam (-CLB)

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Literatur
1.
Dincer I, Acar C (2015) Review and evaluation of hydrogen production methods for better sustainability. Int J Hydrogen Energy 40(34):11094–11111
2.
Turner JA (2004) Sustainable hydrogen production. Science 305(5686):972–974
3.
Balderas-Xicohténcatl R, Schmieder P, Denysenko D, Volkmer D, Hirscher M (2018) High volumetric hydrogen storage capacity using interpenetrated metal-organic frameworks. Energy Technol 6(3):510–512
4.
Abánades A, Rubbia C, Salmieri D (2013) Thermal cracking of methane into Hydrogen for a CO2-free utilization of natural gas. Int J Hydrogen Energy 38(20):8491–8496
5.
Wang M, Wang Z, Gong X, Guo Z (2014) The intensification technologies to water electrolysis for hydrogen production—a review. Renew Sust Energ Rev 29:573–588
6.
Zhao G, Rui K, Dou SX, Sun W (2018) Heterostructures for electrochemical hydrogen evolution reaction: a review. Adv Funct Mater 28(43):1803291
7.
Zou X, Zhang Y (2015) Noble metal-free hydrogen evolution catalysts for water splitting. Chem Soc Rev 44(15):5148–5180
8.
Fang M, Dong G, Wei R, Ho JC (2017) Hierarchical nanostructures: design for sustainable water splitting. Adv Energy Mater 7(23):1700559
9.
Conway BE, Tilak BV (2002) Interfacial processes involving electrocatalytic evolution and oxidation of H2, and the role of chemisorbed H. Electrochim Acta 47(22–23):3571–3594
10.
Wang Y, Kong B, Zhao D, Wang H, Selomulya C (2017) Strategies for developing transition metal phosphides as heterogeneous electrocatalysts for water splitting. Nano Today 15:26–55
11.
Morales-Guio CG, Stern LA, Hu X (2014) Nanostructured hydrotreating catalysts for electrochemical hydrogen evolution. Chem Soc Rev 43(18):6555–6569
12.
Wei J, Zhou M, Long A et al (2018) Heterostructured electrocatalysts for hydrogen evolution reaction under alkaline conditions. Nano-Micro Lett 10:75
13.
Chen Y, Ren R, Wen Z et al (2018) Superior electrocatalysis for hydrogen evolution with crumpled graphene/tungsten disulfide/tungsten trioxide ternary nanohybrids. Nano Energy 47:66–73
14.
Ma B, Yang Z, Yuan Z, Chen Y (2019) Effective surface roughening of three-dimensional copper foam via sulfurization treatment as a bifunctional electrocatalyst for water splitting. Int J Hydrogen Energy 44(3):1620–1626
15.
Oyama ST (2003) Novel catalysts for advanced hydroprocessing: transition metal phosphides. J Catal 216(1–2):343–352
16.
Sawhill SJ, Phillips DC, Bussell ME (2003) Thiophene hydrodesulfurization over supported nickel phosphide catalysts. J Catal 215(2):208–219
17.
Zuzaniuk V, Prins R (2003) Synthesis and characterization of silica-supported transition-metal phosphides as HDN catalysts. J Catal 219(1):85–96
18.
Yi S-S, Yan J-M, Wulan B-R, Li S-J, Liu K-H, Jiang Q (2017) Noble-metal-free cobalt phosphide modified carbon nitride: an efficient photocatalyst for hydrogen generation. Appl Catal B-Environ 200:477–483
19.
Ma B, Zhao J, Ge Z, Chen Y, Yuan Z (2020) 5 nm NiCoP nanoparticles coupled with g-C3N4 as high-performance photocatalyst for hydrogen evolution. Sci China Mater 63(2):258–266
20.
Parra-Puerto A, Ng KL, Fahy K, Goode AE, Ryan MP, Kucernak A (2019) Supported transition metal phosphides: activity survey for HER, ORR, OER, and corrosion resistance in acid and alkaline electrolytes. ACS Catal 9(12):11515–11529
21.
Hu K, Xiao Z, Cheng Y et al (2017) Iron phosphide/N, P-doped carbon nanosheets as highly efficient electrocatalysts for oxygen reduction reaction over the whole pH range. Electrochim Acta 254:280–286
22.
Lei H, Chen M, Liang Z, Liu C, Zhang W, Cao R (2018) Ni2P hollow microspheres for electrocatalytic oxygen evolution and reduction reactions. Catal Sci Technol 8(9):2289–2293
23.
Lv Y, Wang X (2017) Nonprecious metal phosphides as catalysts for hydrogen evolution, oxygen reduction and evolution reactions. Catal Sci Technol 7(17):3676–3691
24.
Jin S (2017) Are metal chalcogenides, nitrides, and phosphides oxygen evolution catalysts or bifunctional catalysts? ACS Energy Lett 2(8):1937–1938
25.
Liu P, Rodriguez JA (2005) Catalysts for hydrogen evolution from the [NiFe] hydrogenase to the Ni2P(001) surface: the importance of ensemble effect. J Am Chem Soc 127(42):14871–14878
26.
Popczun EJ, McKone JR, Read CG et al (2013) Nanostructured nickel phosphide as an electrocatalyst for the hydrogen evolution reaction. J Am Chem Soc 135(25):9267–9270
27.
Xu Y, Wu R, Zhang J, Shi Y, Zhang B (2013) Anion-exchange synthesis of nanoporous FeP nanosheets as electrocatalysts for hydrogen evolution reaction. Chem Commun 49(59):6656–6658
28.
Du H, Liu Q, Cheng N, Asiri AM, Sun X, Li C (2014) Template-assisted synthesis of CoP nanotubes to efficiently catalyze hydrogen-evolving reaction. J Mater Chem A 2(36):14812–14816
29.
McEnaney JM, Crompton JC, Callejas JF et al (2014) Amorphous molybdenum phosphide nanoparticles for electrocatalytic hydrogen evolution. Chem Mater 26(16):4826–4831
30.
Xiao P, Sk MA, Thia L et al (2014) Molybdenum phosphide as an efficient electrocatalyst for the hydrogen evolution reaction. Energy Environ Sci 7(8):2624–2629
31.
Cui W, Liu Q, Xing Z, Asiri AM, Alamry KA, Sun X (2015) MoP nanosheets supported on biomass-derived carbon flake: one-step facile preparation and application as a novel high-active electrocatalyst toward hydrogen evolution reaction. Appl Catal B-Environ 164:140–150
32.
McEnaney JM, Chance Crompton J, Callejas JF et al (2014) Electrocatalytic hydrogen evolution using amorphous tungsten phosphide nanoparticles. Chem Commun 50(75):11026–11028
33.
Pu Z, Liu Q, Asiri AM, Sun X (2014) Tungsten phosphide nanorod arrays directly grown on carbon cloth: a highly efficient and stable hydrogen evolution cathode at all pH values. ACS Appl Mater Interfaces 6(24):21874–21879
34.
Pu Z, Ya X, Amiinu IS et al (2016) Ultrasmall tungsten phosphide nanoparticles embedded in nitrogen-doped carbon as a highly active and stable hydrogen-evolution electrocatalyst. J Mater Chem A 4(40):15327–15332
35.
Tian J, Liu Q, Cheng N, Asiri AM, Sun X (2014) Self-supported Cu3P nanowire arrays as an integrated high-performance three-dimensional cathode for generating hydrogen from water. Angew Chem Int Ed 53(36):9577–9581
36.
Han A, Zhang H, Yuan R, Ji H, Du P (2017) Crystalline copper phosphide nanosheets as an efficient janus catalyst for overall water splitting. ACS Appl Mater Interfaces 9(3):2240–2248
37.
Hou C-C, Chen Q-Q, Wang C-J et al (2016) Self-supported cedarlike semimetallic Cu3P nanoarrays as a 3D high-performance janus electrode for both oxygen and hydrogen evolution under basic conditions. ACS Appl Mater Interfaces 8(35):23037–23048
38.
Koper MTM (2011) Thermodynamic theory of multi-electron transfer reactions: implications for electrocatalysis. J Electroanal Chem 660(2):254–260
39.
Shi Y, Zhang B (2016) Recent advances in transition metal phosphide nanomaterials: synthesis and applications in hydrogen evolution reaction. Chem Soc Rev 45(6):1529–1541
40.
Hou J, Wu Y, Zhang B, Cao S, Li Z, Sun L (2019) Rational design of nanoarray architectures for electrocatalytic water splitting. Adv Funct Mater 29(20):1808367
41.
Sheng W, Gasteiger HA, Shao-Horn Y (2010) Hydrogen oxidation and evolution reaction kinetics on platinum: acid vs alkaline electrolytes. J Electrochem Soc 157(11):B1529–B1536
42.
Li W, Xiong D, Gao X, Song W-G, Xia F, Liu L (2017) Self-supported Co–Ni–P ternary nanowire electrodes for highly efficient and stable electrocatalytic hydrogen evolution in acidic solution. Catal Today 287:122–129
43.
Wu T, Pi M, Zhang D, Chen S (2016) 3D structured porous CoP3 nanoneedle arrays as an efficient bifunctional electrocatalyst for the evolution reaction of hydrogen and oxygen. J Mater Chem A 4(38):14539–14544
44.
Wang X-D, Chen H-Y, Xu Y-F et al (2017) Self-supported NiMoP2 nanowires on carbon cloth as an efficient and durable electrocatalyst for overall water splitting. J Mater Chem A 5(15):7191–7199
45.
Nikolic VM, Maslovara SL, Tasic GS et al (2015) Kinetics of hydrogen evolution reaction in alkaline electrolysis on a Ni cathode in the presence of Ni–Co–Mo based ionic activators. Appl Catal B-Environ 179:88–94
46.
Barber JH, Conway BE (1999) Structural specificity of the kinetics of the hydrogen evolution reaction on the low-index surfaces of Pt single-crystal electrodes in 0.5 M dm−3 NaOH. J Electroanal Chem 461(1–2):80–89
47.
Huang J, Li Z, Liaw BY, Zhang J (2016) Graphical analysis of electrochemical impedance spectroscopy data in Bode and Nyquist representations. J Power Sources 309:82–98
48.
Xiao P, Chen W, Wang X (2015) A review of phosphide-based materials for electrocatalytic hydrogen evolution. Adv Energy Mater 5(24):1500985
49.
Laursen AB, Patraju KR, Whitaker MJ et al (2015) Nanocrystalline Ni5P4: a hydrogen evolution electrocatalyst of exceptional efficiency in both alkaline and acidic media. Energy Environ Sci 8(3):1027–1034
50.
Shirotani I, Tachi K, Todo S et al (1996) Electrical conductivity and superconductivity of metal phosphides with skutterudite-type structure prepared at high pressure. J Phys Chem Solids 57(2):211–216
51.
Westerstrandh B, Lundgren L, Gäfvert U, Carlsson B (1977) Magnetic susceptibility resistivity and thermal expansion measurements on FeP. Phys Scripta 15(4):276
52.
Takai M, Mera F, Kaseda M, Osaka T (1998) Increasing the resistivity of NiFeP films by means of electrodeposition. J Magn Soc JPN 22:629–632
53.
Dean JA (1999) Lange’s handbook of chemistry, 15th edn. McGRAW-HILL, New York
54.
Haynes WM, Lide DR, Bruno TJ (2017) CRC handbook of chemistry and physics, 97th edn. CRC Press, Boca Raton
55.
Huang X, Xu X, Luan X, Cheng D (2020) CoP nanowires coupled with CoMoP nanosheets as a highly efficient cooperative catalyst for hydrogen evolution reaction. Nano Energy 68:104332
56.
Wang X, Zhou H, Zhang D, Pi M, Feng J, Chen S (2018) Mn-doped NiP2 nanosheets as an efficient electrocatalyst for enhanced hydrogen evolution reaction at all pH values. J Power Sources 387:1–8
57.
Jin Z, Li P, Xiao D (2016) Metallic Co2P ultrathin nanowires distinguished from CoP as robust electrocatalysts for overall water-splitting. Green Chem 18(6):1459–1464
58.
Liang H, Gandi AN, Anjum DH, Wang X, Schwingenschlogl U, Alshareef HN (2016) Plasma-assisted synthesis of NiCoP for efficient overall water splitting. Nano Lett 16(12):7718–7725
59.
Zhang C, Huang Y, Yu Y, Zhang J, Zhuo S, Zhang B (2017) ) Sub-1.1 nm ultrathin porous CoP nanosheets with dominant reactive 200 facets: a high mass activity and efficient electrocatalyst for the hydrogen evolution reaction. Chem Sci 8(4):2769–2775
60.
Yang L, Liu D, Hao S et al (2017) Topotactic conversion of alpha-Fe2O3 nanowires into FeP as a superior fluorosensor for nucleic acid detection: insights from experiment and theory. Anal Chem 89(4):2191–2195
61.
Nørskov JK, Bligaard T, Logadottir A, Kitchin JR, Chen JG, Pandelov S, Stimming U (2005) Trends in the exchange current for hydrogen evolution. J Electrochem Soc 152(3):J23–J26
62.
Hinnemann B, Moses PG, Bonde J et al (2005) Biomimetic hydrogen evolution: MoS2 nanoparticles as catalyst for hydrogen evolution. J Am Chem Soc 127(15):5308–5309
63.
Cao H, Xie Y, Wang H et al (2018) Flower-like CoP microballs assembled with (002) facet nanowires via precursor route: efficient electrocatalysts for hydrogen and oxygen evolution. Electrochim Acta 259:830–840
64.
Pan Y, Sun K, Lin Y et al (2019) Electronic structure and d-band center control engineering over M-doped CoP (M=Ni, Mn, Fe) hollow polyhedron frames for boosting hydrogen production. Nano Energy 56:411–419
65.
Li H, Zhao X, Liu H et al (2018) Sub-1.5 nm ultrathin CoP nanosheet aerogel: efficient electrocatalyst for hydrogen evolution reaction at All pH values. Small 14(41):1802824
66.
Byrappa K, Adschiri T (2007) Hydrothermal technology for nanotechnology. Prog Cryst Growth Charact Mater 53(2):117–166
67.
Tam KH, Cheung CK, Leung YH et al (2006) Defects in ZnO nanorods prepared by a hydrothermal method. J Phys Chem B 110(42):20865–20871
68.
Sun H, Xu X, Yan Z et al (2017) Porous multishelled Ni2P hollow microspheres as an active electrocatalyst for hydrogen and oxygen evolution. Chem Mater 29(19):8539–8547
69.
Yang H, Zhang Y, Hu F, Wang Q (2015) Urchin-like CoP nanocrystals as hydrogen evolution reaction and oxygen reduction reaction dual-electrocatalyst with superior stability. Nano Lett 15(11):7616–7620
70.
Jiang P, Liu Q, Ge C et al (2014) CoP nanostructures with different morphologies: synthesis, characterization and a study of their electrocatalytic performance toward the hydrogen evolution reaction. J Mater Chem A 2(35):14634–14640
71.
Zhang R, Wang X, Yu S et al (2017) Ternary NiCo2Px nanowires as pH-universal electrocatalysts for highly efficient hydrogen evolution reaction. Adv Mater 29(9):1605502
72.
Liang Y, Liu Q, Asiri AM, Sun X, Luo Y (2014) Self-Supported FeP nanorod arrays: a cost-effective 3D hydrogen evolution cathode with high catalytic activity. ACS Catal 4(11):4065–4069
73.
Niu Z, Qiu C, Jiang J, Ai L (2018) Hierarchical CoP–FeP branched heterostructures for highly efficient electrocatalytic water splitting. ACS Sustain Chem Eng 7(2):2335–2342
74.
Zhang W, Wu Y, Qi J, Chen M, Cao R (2017) A thin NiFe hydroxide film formed by stepwise electrodeposition strategy with significantly improved catalytic water oxidation efficiency. Adv Energy Mater 7(9):1602547
75.
Sakita AMP, Noce RD, Valles E, Benedetti AV (2017) Pulse electrodeposition of CoFe thin films covered with layered double hydroxides as a fast route to prepare enhanced catalysts for oxygen evolution reaction. Appl Surf Sci 434:1153–1160
76.
Pei Y, Ge Y, Chu H et al (2018) Controlled synthesis of 3D porous structured cobalt-iron based nanosheets by electrodeposition as asymmetric electrodes for ultra-efficient water splitting. Appl Catal B-Environ 244:583–593
77.
Pu Z, Liu Q, Jiang P, Asiri AM, Obaid AY, Sun X (2014) CoP nanosheet arrays supported on a Ti Plate: an efficient cathode for electrochemical hydrogen evolution. Chem Mater 26(15):4326–4329
78.
Zhao X, Zhang Z, Cao X et al (2020) Elucidating the sources of activity and stability of FeP electrocatalyst for hydrogen evolution reactions in acidic and alkaline media. Appl Catal B-Environ 260:118156
79.
Zhou L, Shao M, Li J, Jiang S, Wei M, Duan X (2017) Two-dimensional ultrathin arrays of CoP: electronic modulation toward high performance overall water splitting. Nano Energy 41:583–590
80.
Wang A-L, Lin J, Xu H, Tong Y-X, Li G-R (2016) Ni2P–CoP hybrid nanosheet arrays supported on carbon cloth as an efficient flexible cathode for hydrogen evolution. J Mater Chem A 4(43):16992–16999
81.
Yan Y, Xia BY, Ge X, Liu Z, Fisher A, Wang X (2015) A flexible electrode based on iron phosphide nanotubes for overall water splitting. Chem-Eur J 21(50):18062–18067
82.
Xuan C, Wang J, Xia W et al (2017) Porous structured Ni–Fe–P nanocubes derived from a prussian blue analogue as an electrocatalyst for efficient overall water splitting. ACS Appl Mater Interfaces 9(31):26134–26142
83.
Popczun EJ, Read CG, Roske CW, Lewis NS, Schaak RE (2014) Highly active electrocatalysis of the hydrogen evolution reaction by cobalt phosphide nanoparticles. Angew Chem Int Ed 53(21):5427–5430
84.
Tian J, Liu Q, Liang Y, Xing Z, Asiri AM, Sun X (2014) FeP nanoparticles film grown on carbon cloth: an ultrahighly active 3D hydrogen evolution cathode in both acidic and neutral solutions. ACS Appl Mater Interfaces 6(23):20579–20584
85.
Tian J, Liu Q, Asiri AM, Sun X (2014) Self-supported nanoporous cobalt phosphide nanowire arrays: an efficient 3D hydrogen-evolving cathode over the wide range of pH 0-14. J Am Chem Soc 136(21):7587–7590
86.
Yang X, Lu A-Y, Zhu Y et al (2015) CoP nanosheet assembly grown on carbon cloth: a highly efficient electrocatalyst for hydrogen generation. Nano Energy 15:634–641
87.
Ma B, Yang Z, Chen Y, Yuan Z (2019) Nickel cobalt phosphide with three-dimensional nanostructure as a highly efficient electrocatalyst for hydrogen evolution reaction in both acidic and alkaline electrolytes. Nano Res 12(2):375–380
88.
Wang X, Kolen’ko YV, Bao XQ, Kovnir K, Liu L (2015) One-step synthesis of self-supported nickel phosphide nanosheet array cathodes for efficient electrocatalytic hydrogen generation. Angew Chem Int Ed 54(28):8188–8192
89.
Han A, Jin S, Chen H, Ji H, Sun Z, Du P (2015) A robust hydrogen evolution catalyst based on crystalline nickel phosphide nanoflakes on three-dimensional graphene/nickel foam: high performance for electrocatalytic hydrogen production from pH 0–14. J Mater Chem A 3(5):1941–1946
90.
Zhou D, He L, Zhu W et al (2016) Interconnected urchin-like cobalt phosphide microspheres film for highly efficient electrochemical hydrogen evolution in both acidic and basic media. J Mater Chem A 4(26):10114–10117
91.
Jiang P, Liu Q, Liang Y, Tian J, Asiri AM, Sun X (2014) A cost-effective 3D hydrogen evolution cathode with high catalytic activity: feP nanowire array as the active phase. Angew Chem Int Ed 53(47):12555–12559
92.
Ma L, Shen X, Zhou H, Zhu G, Ji Z, Chen K (2015) CoP nanoparticles deposited on reduced graphene oxide sheets as an active electrocatalyst for hydrogen evolution reaction. J Mater Chem A 3(10):5337–5343
93.
Pu Z, Tang C, Luo Y (2015) Ferric phosphide nanoparticles film supported on titanium plate: a high-performance hydrogen evolution cathode in both acidic and neutral solutions. Int J Hydrogen Energy 40(15):5092–5098
94.
Liu M, Li J (2016) Cobalt phosphide hollow polyhedron as efficient bifunctional electrocatalysts for the evolution reaction of hydrogen and oxygen. ACS Appl Mater Interfaces 8(3):2158–2165
95.
Feng Y, Yu X-Y, Paik U (2016) Nickel cobalt phosphides quasi-hollow nanocubes as an efficient electrocatalyst for hydrogen evolution in alkaline solution. Chem Commun 52(8):1633–1636
96.
Chen J, Liu J, Xie J-Q et al (2019) Co–Fe–P nanotubes electrocatalysts derived from metal-organic frameworks for efficient hydrogen evolution reaction under wide pH range. Nano Energy 56:225–233
97.
Ledendecker M, Krick Calderon S, Papp C, Steinruck HP, Antonietti M, Shalom M (2015) The synthesis of nanostructured Ni5P4 films and their use as a non-noble bifunctional electrocatalyst for full water splitting. Angew Chem Int Ed 127(42):12538–12542
98.
99.
Shi Y, Xu Y, Zhuo S, Zhang J, Zhang B (2015) Ni2P nanosheets/Ni foam composite electrode for long-lived and pH-tolerable electrochemical hydrogen generation. ACS Appl Mater Interfaces 7(4):2376–2384
100.
Popczun EJ, Roske CW, Read CG et al (2015) Highly branched cobalt phosphide nanostructures for hydrogen-evolution electrocatalysis. J Mater Chem A 10:5420–5425
101.
Huang Z, Chen Z, Chen Z, Lv C, Meng H, Zhang C (2014) Ni12P5 nanoparticles as an efficient catalyst for hydrogen generation via electrolysis and photoelectrolysis. ACS Nano 8(8):8121–8129
102.
Huang Z, Chen Z, Chen Z, Lv C, Humphrey MG, Zhang C (2014) Cobalt phosphide nanorods as an efficient electrocatalyst for the hydrogen evolution reaction. Nano Energy 9:373–382
103.
Shi J, Qiu F, Yuan W, Guo M, Yuan C, Lu Z-H (2020) Novel electrocatalyst of nanoporous FeP cubes prepared by fast electrodeposition coupling with acid-etching for efficient hydrogen evolution. Electrochim Acta 329:135185
104.
Zhu Y-P, Liu Y-P, Ren T-Z, Yuan Z-Y (2015) Self-supported cobalt phosphide mesoporous nanorod arrays: a flexible and bifunctional electrode for highly active electrocatalytic water reduction and oxidation. Adv Funct Mater 25(47):7337–7347
105.
Cao X, Jia D, Li D, Cui L, Liu J (2018) One-step co-electrodeposition of hierarchical radial NixP nanospheres on Ni foam as highly active flexible electrodes for hydrogen evolution reaction and supercapacitor. Chem Eng J 348:310–318
106.
Kim H, Oh S, Cho E, Kwon H (2018) 3D porous cobalt–iron–phosphorus bifunctional electrocatalyst for the oxygen and hydrogen evolution reactions. ACS Sustain Chem Eng 6(5):6305–6311
107.
Zhou M, Sun Q, Shen Y, Ma Y, Wang Z, Zhao C (2019) Fabrication of 3D microporous amorphous metallic phosphides for high-efficiency hydrogen evolution reaction. Electrochim Acta 306:651–659
108.
Wang P, Song F, Amal R, Ng YH, Hu X (2016) Efficient water splitting catalyzed by cobalt phosphide-based nanoneedle arrays supported on carbon cloth. Chemsuschem 9(5):472–477
109.
Zhou Q, Shen Z, Zhu C et al (2018) Nitrogen-doped CoP electrocatalysts for coupled hydrogen evolution and sulfur generation with low energy consumption. Adv Mater 30(27):1800140
110.
Xiao X, Tao L, Li M et al (2018) Electronic modulation of transition metal phosphide via doping as efficient and pH-universal electrocatalysts for hydrogen evolution reaction. Chem Sci 9(7):1970–1975
111.
Jiang P, Liu Q, Sun X (2014) NiP2 nanosheet arrays supported on carbon cloth: an efficient 3D hydrogen evolution cathode in both acidic and alkaline solutions. Nanoscale 6(22):13440–13445
112.
Li J, Li J, Zhou X et al (2016) Highly efficient and robust nickel phosphides as bifunctional electrocatalysts for overall water-splitting. ACS Appl Mater Interfaces 8(17):10826–10834
113.
Sun Y, Hang L, Shen Q et al (2017) Mo doped Ni2P nanowire arrays: an efficient electrocatalyst for the hydrogen evolution reaction with enhanced activity at all pH values. Nanoscale 9(43):16674–16679
114.
Yan Y, Shi XR, Miao M et al (2018) Bio-inspired design of hierarchical FeP nanostructure arrays for the hydrogen evolution reaction. Nano Res 11(7):3537–3547
115.
Li Y, Zhang H, Jiang M, Kuang Y, Sun X, Duan X (2016) Ternary NiCoP nanosheet arrays: an excellent bifunctional catalyst for alkaline overall water splitting. Nano Res 9(8):2251–2259
116.
Du Y, Qu H, Liu Y, Han Y, Wang L, Dong B (2019) Bimetallic CoFeP hollow microspheres as highly efficient bifunctional electrocatalysts for overall water splitting in alkaline media. Appl Surf Sci 465:816–823
117.
Feng JX, Tong SY, Tong YX, Li GR (2018) Pt-like hydrogen evolution electrocatalysis on PANI/CoP Hybrid nanowires by weakening the shackles of hydrogen ions on the surfaces of catalysts. J Am Chem Soc 140(15):5118–5126
118.
Liu T, Ma X, Liu D et al (2017) Mn doping of CoP nanosheets array: an efficient electrocatalyst for hydrogen evolution reaction with enhanced activity at all pH values. ACS Catal 7(1):98–102
119.
Hansen MH, Stern L-A, Feng L, Rossmeisl J, Hu X (2015) Widely available active sites on Ni2P for electrochemical hydrogen evolution—insights from first principles calculations. Phys Chem Chem Phys 17(16):10823–10829
120.
Miao Y-E, Li F, Zhou Y, Lai F, Lu H, Liu T (2017) Engineering a nanotubular mesoporous cobalt phosphide electrocatalyst by the Kirkendall effect towards highly efficient hydrogen evolution reactions. Nanoscale 9(42):16313–16320
121.
Lv C, Peng Z, Zhao Y, Huang Z, Zhang C (2016) The hierarchical nanowires array of iron phosphide integrated on a carbon fiber paper as an effective electrocatalyst for hydrogen generation. J Mater Chem A 4(4):1454–1460
122.
Yu X, Yu Z-Y, Zhang X-L et al (2019) “Superaerophobic” nickel phosphide nanoarray catalyst for efficient hydrogen evolution at ultrahigh current densities. J Am Chem Soc 141(18):7537–7543
123.
Tian Y, Yu J, Zhang H et al (2019) 3D porous Ni-Co-P nanosheets on carbon fiber cloth for efficient hydrogen evolution reaction. Electrochim Acta 300:217–224
124.
Xu K, Cheng H, Lv H et al (2018) Controllable surface reorganization engineering on cobalt phosphide nanowire arrays for efficient alkaline hydrogen evolution reaction. Adv Mater 30(1):1703322
125.
Son CY, Kwak IH, Lim YR, Park J (2016) FeP and FeP2 nanowires for efficient electrocatalytic hydrogen evolution reaction. Chem Commun 52(13):2819–2822
126.
Zeng Y, Wang Y, Huang G et al (2018) Porous CoP nanosheets converted from layered double hydroxides with superior electrochemical activity for hydrogen evolution reactions at wide pH ranges. Chem Commun 54(12):1465–1468
127.
Zhang J, Liang X, Wang X, Zhuang Z (2017) CoP nanotubes formed by Kirkendall effect as efficient hydrogen evolution reaction electrocatalysts. Mater Lett 202:146–149
128.
Ma S, Wang L, Zhang S et al (2019) Facile fabrication of a binary NiCo phosphide with hierarchical architecture for efficient hydrogen evolution reactions. Int J Hydrogen Energy 44(8):4188–4196
129.
Hu E, Feng Y, Nai J, Zhao D, Hu Y, Lou XW (2018) Construction of hierarchical Ni–Co–P hollow nanobricks with oriented nanosheets for efficient overall water splitting. Energy Environ Sci 11(4):872–880
130.
Chung DY, Jun SW, Yoon G et al (2017) Large-scale synthesis of carbon-shell-coated fep nanoparticles for robust hydrogen evolution reaction electrocatalyst. J Am Chem Soc 139(19):6669–6674
131.
Wang MQ, Ye C, Liu H, Xu M, Bao SJ (2018) Nanosized metal phosphides embedded in nitrogen-doped porous carbon nanofibers for enhanced hydrogen evolution at all pH values. Angew Chem Int Ed 57(7):1963–1967
132.
Zhang C, Pu Z, Amiinu IS et al (2018) Co2P quantum dot embedded N, P dual-doped carbon self-supported electrodes with flexible and binder-free properties for efficient hydrogen evolution reactions. Nanoscale 10(6):2902–2907
133.
Ma J, Wang M, Lei G et al (2018) Polyaniline derived N-doped carbon-coated cobalt phosphide nanoparticles deposited on N-doped graphene as an efficient electrocatalyst for hydrogen evolution reaction. Small 14(2):1702895
134.
Tabassum H, Guo W, Meng W et al (2017) Metal-organic frameworks derived cobalt phosphide architecture encapsulated into B/N Co-doped graphene nanotubes for all pH Value electrochemical hydrogen evolution. Adv Energy Mater 7(9):1601671
135.
Zhang X-Y, Guo B-Y, Chen Q-W et al (2019) Ultrafine and highly-dispersed bimetal Ni2P/Co2P encapsulated by hollow N-doped carbon nanospheres for efficient hydrogen evolution. Int J Hydrogen Energy 44(29):14908–14917
136.
Yan L, Jiang H, Wang Y et al (2019) One-step and scalable synthesis of Ni2P nanocrystals encapsulated in N,P-codoped hierarchically porous carbon matrix using a bipyridine and phosphonate linked nickel metal–organic framework as highly efficient electrocatalysts for overall water splitting. Electrochim Acta 297:755–766
137.
Yang S, Chen L, Wei W, Lv X, Xie J (2019) CoP nanoparticles encapsulated in three-dimensional N-doped porous carbon for efficient hydrogen evolution reaction in a broad pH range. Appl Surf Sci 476:749–756
138.
Yang F, Chen Y, Cheng G, Chen S, Luo W (2017) Ultrathin nitrogen-doped carbon coated with CoP for efficient hydrogen evolution. ACS Catal 7(6):3824–3831
139.
Tang C, Gan L, Zhang R et al (2016) Ternary FexCo1–xP nanowire array as a robust hydrogen evolution reaction electrocatalyst with Pt-like activity: experimental and theoretical insight. Nano Lett 16(10):6617–6621
140.
Zhang R, Tang C, Kong R et al (2017) Al-Doped CoP nanoarray: a durable water-splitting electrocatalyst with superhigh activity. Nanoscale 9(14):4793–4800
141.
Wen L, Sun Y, Zhang C et al (2018) Cu-doped CoP nanorod arrays: efficient and durable hydrogen evolution reaction electrocatalysts at all pH values. ACS Appl Mater Interfaces 1(8):3835–3842
142.
Gao W, Yan M, Cheung H-Y et al (2017) Modulating electronic structure of CoP electrocatalysts towards enhanced hydrogen evolution by Ce chemical doping in both acidic and basic media. Nano Energy 38:290–296
143.
Wang M, Tuo Y, Li X, Hua Q, Du F, Jiang L (2019) Mesoporous Mn-doped FeP: facile synthesis and enhanced electrocatalytic activity for hydrogen evolution in a wide pH range. ACS Sustain Chem Eng 7(14):12419–12427
144.
Zhuo J, Cabán-Acevedo M, Liang H et al (2015) High-performance electrocatalysis for hydrogen evolution reaction using Se-doped pyrite-phase nickel diphosphide nanostructures. ACS Catal 5(11):6355–6361
145.
Anjum MAR, Okyay MS, Kim M, Lee MH, Park N, Lee JS (2018) Bifunctional sulfur-doped cobalt phosphide electrocatalyst outperforms all-noble-metal electrocatalysts in alkaline electrolyzer for overall water splitting. Nano Energy 53:286–295
146.
Men Y, Li P, Yang F, Cheng G, Chen S, Luo W (2019) Nitrogen-doped CoP as robust electrocatalyst for high-efficiency pH-universal hydrogen evolution reaction. Appl Catal B-Environ 253:21–27
147.
Wang L, Wu H, Xi S et al (2019) Nitrogen-doped cobalt phosphide for enhanced hydrogen evolution activity. ACS Appl Mater Interfaces 11(19):17359–17367
148.
Yan L, Zhang B, Zhu J, Liu Z, Zhang H, Li Y (2019) Callistemon-like Zn and S codoped CoP nanorod clusters as highly efficient electrocatalysts for neutral-pH overall water splitting. J Mater Chem A 7(39):22453–22462
149.
Xu K, Sun Y, Sun Y et al (2018) Yin-Yang harmony: metal and nonmetal dual-doping boosts electrocatalytic activity for alkaline hydrogen evolution. ACS Energy Lett 3(11):2750–2756
150.
Zhang W, Sun Y, Liu Q, Guo J, Zhang X (2019) Vanadium and nitrogen co-doped CoP nanoleaf array as pH-universal electrocatalyst for efficient hydrogen evolution. J Alloy Compd 791:1070–1078
151.
Liu H, Ma X, Hu H et al (2019) Robust NiCoP/CoP heterostructures for highly efficient hydrogen evolution electrocatalysis in alkaline solution. ACS Appl Mater Interfaces 11(17):15528–15536
152.
Lin Y, Sun K, Liu S et al (2019) Construction of CoP/NiCoP nanotadpoles heterojunction interface for wide pH hydrogen evolution electrocatalysis and supercapacitor. Adv Energy Mater 9(36):1901213
153.
Wang H, Wang X, Zheng B, Yang D, Zhang W, Chen Y (2019) Self-assembled Ni2P/FeP heterostructural nanoparticles embedded in N-doped graphene nanosheets as highly efficient and stable multifunctional electrocatalyst for water splitting. Electrochim Acta 318:449–459
154.
Jiao L, Zhou YX, Jiang HL (2016) Metal-organic framework-based CoP/reduced graphene oxide: high-performance bifunctional electrocatalyst for overall water splitting. Chem Sci 7(3):1690–1695
155.
Guan C, Xiao W, Wu H et al (2018) Hollow Mo-doped CoP nanoarrays for efficient overall water splitting. Nano Energy 48:73–80
156.
Pan Y, Lin Y, Chen Y, Liu Y, Liu C (2016) Cobalt phosphide-based electrocatalysts: synthesis and phase catalytic activity comparison for hydrogen evolution. J Mater Chem A 4(13):4745–4754
157.
Wu C, Yang Y, Dong D, Zhang Y, Li J (2017) In situ coupling of cop polyhedrons and carbon nanotubes as highly efficient hydrogen evolution reaction electrocatalyst. Small 13(15):1602873
158.
Zhuang M, Ou X, Dou Y et al (2016) Polymer-embedded fabrication of Co2P nanoparticles encapsulated in N,P-doped graphene for hydrogen generation. Nano Lett 16(7):4691–4698
159.
Callejas JF, Read CG, Popczun EJ, McEnaney JM, Schaak RE (2015) Nanostructured Co2P electrocatalyst for the hydrogen evolution reaction and direct comparison with morphologically equivalent CoP. Chem Mater 27(10):3769–3774
160.
Xu K, Ding H, Zhang M et al (2017) Regulating water-reduction kinetics in cobalt phosphide for enhancing HER catalytic activity in alkaline solution. Adv Mater 29(28):1606980
161.
Wang J, Yang W, Liu J (2016) CoP2 nanoparticles on reduced graphene oxide sheets as a super-efficient bifunctional electrocatalyst for full water splitting. J Mater Chem A 4(13):4686–4690
162.
Zhou Y, Yang Y, Wang R et al (2018) Rhombic porous CoP2 nanowire arrays synthesized by alkaline etching as highly active hydrogen-evolution-reaction electrocatalysts. J Mater Chem A 6(39):19038–19046
163.
Pu Z, Liu Q, Tang C, Asiri AM, Sun X (2014) Ni2P nanoparticle films supported on a Ti plate as an efficient hydrogen evolution cathode. Nanoscale 6(19):11031–11034
164.
Pan Y, Hu W, Liu D, Liu Y, Liu C (2015) Carbon nanotubes decorated with nickel phosphide nanoparticles as efficient nanohybrid electrocatalysts for the hydrogen evolution reaction. J Mater Chem A 3(24):13087–13094
165.
Pan Y, Liu Y, Zhao J et al (2015) Monodispersed nickel phosphide nanocrystals with different phases: synthesis, characterization and electrocatalytic properties for hydrogen evolution. J Mater Chem A 3(4):1656–1665
166.
Pu Z, Amiinu IS, Zhang C, Wang M, Kou Z, Mu S (2017) Phytic acid-derivative transition metal phosphides encapsulated in N, P-codoped carbon: an efficient and durable hydrogen evolution electrocatalyst in a wide pH range. Nanoscale 9(10):3555–3560
167.
Callejas JF, McEnaney JM, Read CG et al (2014) Electrocatalytic and photocatalytic hydrogen production from acidic and neutral-pH aqueous solutions using iron phosphide nanoparticles. ACS Nano 8(11):11101–11107
168.
Yan L, Cao L, Dai P et al (2017) Metal-organic frameworks derived nanotube of nickel–cobalt bimetal phosphides as highly efficient electrocatalysts for overall water splitting. Adv Funct Mater 27(40):1703455
169.
Fang Z, Peng L, Qian Y et al (2018) Dual Tuning of Ni–Co–A (A=P, Se, O) nanosheets by anion substitution and holey engineering for efficient hydrogen evolution. J Am Chem Soc 140(15):5241–5247
170.
Li J, Yan M, Zhou X et al (2016) Mechanistic insights on ternary Ni2−xCoxP for hydrogen evolution and their hybrids with graphene as highly efficient and robust catalysts for overall water splitting. Adv Funct Mater 26(37):6785–6796
171.
Li Y, Liu J, Chen C, Zhang X, Chen J (2017) Preparation of NiCoP hollow quasi-polyhedra and their electrocatalytic properties for hydrogen evolution in alkaline solution. ACS Appl Mater Interfaces 9(7):5982–5991
172.
Du C, Yang L, Yang F, Cheng G, Luo W (2017) Nest-like NiCoP for highly efficient overall water splitting. ACS Catal 7(6):4131–4137
173.
Kang Q, Li M, Shi J, Lu Q, Gao F (2020) A universal strategy for carbon-supported transition metal phosphides as high-performance bi-functional electrocatalysts towards efficient overall water splitting. ACS Appl Mater Interfaces 12(17):19447–19456
174.
Mo Q, Zhang W, He L, Yu X, Gao Q (2019) Bimetallic Ni2-xCoxP/N-doped carbon nanofibers: solid-solution-alloy engineering toward efficient hydrogen evolution. Appl Catal B-Environ 244:620–627
175.
Huang C, Ouyang T, Zou Y, Li N, Liu Z-Q (2018) Ultrathin NiCo2Px nanosheets strongly coupled with CNTs as efficient and robust electrocatalysts for overall water splitting. J Mater Chem A 6(17):7420–7427
176.
Lu X, Yu L, Lou X (2019) Highly crystalline Ni-doped FeP/carbon hollow nanorods as all-pH efficient and durable hydrogen evolving electrocatalysts. Sci Adv 5(2):eaav6009
177.
Guo Y, Tang J, Wang Z, Sugahara Y, Yamauchi Y (2018) Hollow porous heterometallic phosphide nanocubes for enhanced electrochemical water splitting. Small 14(44):1802442
178.
Boppella R, Tan J, Yang W, Moon J (2018) Homologous CoP/NiCoP heterostructure on N-doped carbon for highly efficient and pH-universal hydrogen evolution electrocatalysis. Adv Funct Mater 29(6):1807976
179.
Mishra IK, Zhou H, Sun J et al (2018) Hierarchical CoP/Ni5P4/CoP microsheet arrays as a robust pH-universal electrocatalyst for efficient hydrogen generation. Energy Environ Sci 11(8):2246–2252
Metadaten
Titel
A review of the electrocatalysts on hydrogen evolution reaction with an emphasis on Fe, Co and Ni-based phosphides
verfasst von
Zhenhua Ge
Bin Fu
Jinping Zhao
Xing Li
Bo Ma
Yantao Chen
Publikationsdatum
10.07.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 29/2020
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-020-05010-w

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