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Erschienen in: Journal of Materials Science 7/2017

07.12.2016 | Original Paper

A robust pendant-type cross-linked anion exchange membrane (AEM) with high hydroxide conductivity at a moderate IEC value

verfasst von: Yunfeng Zhang, Cuicui Li, Zehui Yang, Xupo Liu, Jiaming Dong, Yuan Liu, Weiwei Cai, Hansong Cheng

Erschienen in: Journal of Materials Science | Ausgabe 7/2017

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Abstract

A novel pendant-type cross-linked anion exchange membrane (pc-AEM) was successfully synthesized using a pre-synthesis approach to precisely control the IEC value and the degree of cross-linking. The physical properties of the pc-AEMs and the non-cross-linked pc-AEMs as well as Nafion 117 were determined, and the results were systematically compared. It was found that the synthesized pc-AEMs show much better dimensional retention capacity than the non-cross-linked pc-AEM and Nafion 117. In addition, the mechanical strength of the pc-AEMs was also remarkably enhanced. By increasing the IEC value of the pc-AEMs to the same level of Nafion 117, the highest ionic conductivity of 0.036 S/cm at 80 °C was reached. The remarkable enhancement of conductivity is chiefly attributed to the construction of highly efficient ionic transport channels resulting from the combined pendant-type and cross-linked architectures of the pc-AEMs.

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Metadaten
Titel
A robust pendant-type cross-linked anion exchange membrane (AEM) with high hydroxide conductivity at a moderate IEC value
verfasst von
Yunfeng Zhang
Cuicui Li
Zehui Yang
Xupo Liu
Jiaming Dong
Yuan Liu
Weiwei Cai
Hansong Cheng
Publikationsdatum
07.12.2016
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 7/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-016-0656-3

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