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Rare Metals
Erschienen in: Rare Metals 1/2022

15.05.2021 | Original Article

A sensitive acetaminophen sensor based on Co metal–organic framework (ZIF-67) and macroporous carbon composite

verfasst von: Jing Tang, Zhen-Zhen Hui, Tao Hu, Xin Cheng, Jia-Hao Guo, Zi-Rong Li, Hao Yu

Erschienen in: Rare Metals | Ausgabe 1/2022

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Abstract

The composite of zeolitic imidazolate frameworks (ZIF-67) and ordered macroporous carbon (OMC) was successfully synthesized via in situ growth from the OMC matrix. The ZIF67–OMC composite was verified by scanning electron microscopy (SEM) and transmission electron microscopy (TEM), powder X-ray diffraction (XRD) and electrochemical impedance spectroscopy (EIS) and then evaluated as a modified material for electrochemical sensor. Benefitting from the large surface area and enhanced conductivity of the ZIF67–OMC composite, ZIF67–OMC nanocomposite showed superior electrocatalytic performance toward acetaminophen (AP) oxidation. The redox reaction of AP underwent a quasi-reversible redox reaction with higher anodic current at ZIF67–OMC modified electrode compared with the bare glassy carbon electrode (GCE). In optimal condition, the ZIF67–OMC/GCE was stable, reproducible and had a linear range of 0.05–100 μmol·L−1 AP concentration, with the detection limit of 20 nmol·L−1 (signal-to-noise of S/N = 3). In addition, the prepared sensing platform for the detection of AP was evaluated for the compound paracetamol tablets and urine samples.

Graphic abstract

Vorheriger Artikel Increasing ionic conductivity in Li0.33La0.56TiO3 thin-films via optimization of processing atmosphere and temperature
Nächster Artikel Ablation-resistant Ir/Re coating on C/C composites at ultra-high temperatures

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Metadaten
Titel
A sensitive acetaminophen sensor based on Co metal–organic framework (ZIF-67) and macroporous carbon composite
verfasst von
Jing Tang
Zhen-Zhen Hui
Tao Hu
Xin Cheng
Jia-Hao Guo
Zi-Rong Li
Hao Yu
Publikationsdatum
15.05.2021
Verlag
Nonferrous Metals Society of China
Erschienen in
Rare Metals / Ausgabe 1/2022
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI
https://doi.org/10.1007/s12598-021-01709-0

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