Skip to main content
Erschienen in: Cellulose 8/2017

25.05.2017 | Original Paper

A simple and efficient protocol to develop durable multifunctional property to cellulosic materials using in situ generated nano-ZnO

verfasst von: A. Arputharaj, Vigneshwaran Nadanathangam, Sanjeev R. Shukla

Erschienen in: Cellulose | Ausgabe 8/2017

Einloggen

Aktivieren Sie unsere intelligente Suche um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

This article focuses on the development of a durable multi-functional finish for cotton fabric by direct synthesis of nano zinc oxide (nano-ZnO) particles in the pores of the fibres. Anions and cations of zinc nitrate interacted with cellulose molecules and opened up the internal pore structure of cellulosic fibrils that in turn acted as nucleating sites for the formation of nano-ZnO on reaction with sodium hydroxide. The finished fabric was characterized using XRD, FTIR, SEM, TEM, AAS, DSC and AFM. The finished fabric displayed excellent antibacterial activities (>99%) against two pathogens, Staphylococcus aureus (Gram-positive) and Klebsiella pneumoniae (Gram-negative) with 40 UPF even after 30 washes confirming the utility of this method. Inherent physical and mechanical properties of the fabric were found to be unaffected. Low stress mechanical properties evaluated by Kawabata Evaluation System for Fabrics indicated that the total hand value of the finished fabric changed from 3.54 to 3.40. A plausible mechanism for in situ formation of nano-ZnO and its durability on cotton fabric has been proposed.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Arputharaj A, Prasad V, Saxena S, Vigneshwaran N, Shukla SR (2016) Ionic liquid mediated application of nano zinc oxide on cotton fabric for multi-functional properties. J Text Inst. doi:10.1080/00405000.2016.1222984 Arputharaj A, Prasad V, Saxena S, Vigneshwaran N, Shukla SR (2016) Ionic liquid mediated application of nano zinc oxide on cotton fabric for multi-functional properties. J Text Inst. doi:10.​1080/​00405000.​2016.​1222984
Zurück zum Zitat Atmaca S, Kadri GÜL, Ciçek R (1998) The effect of zinc on microbial growth. Turk J Med Sci 28:595–598 Atmaca S, Kadri GÜL, Ciçek R (1998) The effect of zinc on microbial growth. Turk J Med Sci 28:595–598
Zurück zum Zitat Baldwin S, Odio MR, Haines SL, O’Connor RJ, Englehart JS, Lane AT (2001) Skin benefits from continuous topical administration of a zinc oxide/petrolatum formulation by a novel disposable diaper. JEADV 15:5–11 Baldwin S, Odio MR, Haines SL, O’Connor RJ, Englehart JS, Lane AT (2001) Skin benefits from continuous topical administration of a zinc oxide/petrolatum formulation by a novel disposable diaper. JEADV 15:5–11
Zurück zum Zitat Basak S, Samanta KK, Chattopadhyay SK (2015) Fire retardant property of cotton fabric treated with herbal extract. J Text Inst 106:1338–1347CrossRef Basak S, Samanta KK, Chattopadhyay SK (2015) Fire retardant property of cotton fabric treated with herbal extract. J Text Inst 106:1338–1347CrossRef
Zurück zum Zitat Bertoniere NR, King WD (1989) Effect of scouring/bleaching, caustic mercerization, and liquid ammonia treatment on the pore structure of cotton textile fibers. Text Res J 59:114–121CrossRef Bertoniere NR, King WD (1989) Effect of scouring/bleaching, caustic mercerization, and liquid ammonia treatment on the pore structure of cotton textile fibers. Text Res J 59:114–121CrossRef
Zurück zum Zitat Dhandapani P, Siddarth AS, Kamalasekaran S, Maruthamuthu S, Rajagopal G (2014) Bio-approach: ureolytic bacteria mediated synthesis of ZnO nanocrystals on cotton fabric and evaluation of their antibacterial properties. Carbohydr Polym 103:448–455CrossRef Dhandapani P, Siddarth AS, Kamalasekaran S, Maruthamuthu S, Rajagopal G (2014) Bio-approach: ureolytic bacteria mediated synthesis of ZnO nanocrystals on cotton fabric and evaluation of their antibacterial properties. Carbohydr Polym 103:448–455CrossRef
Zurück zum Zitat El-Hady MA, Farouk A, Sharaf S (2013) Flame retardancy and UV protection of cotton based fabrics using nano ZnO and polycarboxylic acids. Carbohydr Polym 92:400–406CrossRef El-Hady MA, Farouk A, Sharaf S (2013) Flame retardancy and UV protection of cotton based fabrics using nano ZnO and polycarboxylic acids. Carbohydr Polym 92:400–406CrossRef
Zurück zum Zitat Gokarneshan N, Rachel DA, Rajendran V, Lavanya B, Ghoshal A (2015) Emerging research trends in medical textiles. Springer, SingaporeCrossRef Gokarneshan N, Rachel DA, Rajendran V, Lavanya B, Ghoshal A (2015) Emerging research trends in medical textiles. Springer, SingaporeCrossRef
Zurück zum Zitat Kan CW, Lam YL (2013) Low stress mechanical properties of plasma-treated cotton fabric subjected to zinc oxide-anti-microbial treatment. Materials 6:314–333CrossRef Kan CW, Lam YL (2013) Low stress mechanical properties of plasma-treated cotton fabric subjected to zinc oxide-anti-microbial treatment. Materials 6:314–333CrossRef
Zurück zum Zitat Kathirvelu S, D’souza L, Dhurai B (2009) UV protection finishing of textiles using ZnO nanoparticles. Indian J Fibre Text 34:267–273 Kathirvelu S, D’souza L, Dhurai B (2009) UV protection finishing of textiles using ZnO nanoparticles. Indian J Fibre Text 34:267–273
Zurück zum Zitat Khosravian S, Montazer M, Malek RM, Harifi T (2015) In situ synthesis of nano ZnO on starch sized cotton introducing nano photo active fabric optimized with response surface methodology. Carbohydr Polym 132:126–133CrossRef Khosravian S, Montazer M, Malek RM, Harifi T (2015) In situ synthesis of nano ZnO on starch sized cotton introducing nano photo active fabric optimized with response surface methodology. Carbohydr Polym 132:126–133CrossRef
Zurück zum Zitat Owens DK, Wendt RC (1969) Estimation of the surface free energy of polymers. J Appl Polym Sci 13:1741–1747CrossRef Owens DK, Wendt RC (1969) Estimation of the surface free energy of polymers. J Appl Polym Sci 13:1741–1747CrossRef
Zurück zum Zitat Perelshtein I, Applerot G, Perkas N, Wehrschetz-Sigl E, Hasmann A, Guebitz GM, Gedanken A (2009) Antibacterial properties of an in situ generated and simultaneously deposited nanocrystalline ZnO on fabrics. ACS Appl Mater Interfaces 1:361–366CrossRef Perelshtein I, Applerot G, Perkas N, Wehrschetz-Sigl E, Hasmann A, Guebitz GM, Gedanken A (2009) Antibacterial properties of an in situ generated and simultaneously deposited nanocrystalline ZnO on fabrics. ACS Appl Mater Interfaces 1:361–366CrossRef
Zurück zum Zitat Race E, Speakman JB, Rowe FM (1945) The dyeing of cotton with mineral khaki part vii-the fungicidal and bactericidal efficiencies of cotton yarn treated by various mineral khaki processes. J Soc Dyers Colour 61:310–321CrossRef Race E, Speakman JB, Rowe FM (1945) The dyeing of cotton with mineral khaki part vii-the fungicidal and bactericidal efficiencies of cotton yarn treated by various mineral khaki processes. J Soc Dyers Colour 61:310–321CrossRef
Zurück zum Zitat Saif MJ, Zia KM, Rehman FU, Ahmad MN (2015) An eco-friendly, permanent, and non-leaching antimicrobial coating on cotton fabrics. J Text Inst 106:907–911CrossRef Saif MJ, Zia KM, Rehman FU, Ahmad MN (2015) An eco-friendly, permanent, and non-leaching antimicrobial coating on cotton fabrics. J Text Inst 106:907–911CrossRef
Zurück zum Zitat Shaheen TI, El-Naggar ME, Abdelgawad AM, Hebeish A (2016) Durable antibacterial and UV protections of in situ synthesized Zinc oxide nanoparticles onto cotton fabrics. Int J Biol Macromol 83:426–432CrossRef Shaheen TI, El-Naggar ME, Abdelgawad AM, Hebeish A (2016) Durable antibacterial and UV protections of in situ synthesized Zinc oxide nanoparticles onto cotton fabrics. Int J Biol Macromol 83:426–432CrossRef
Zurück zum Zitat Sirelkhatim A, Mahmud S, Seeni A, Kiran S, Gulzar T (2015) Review on zinc oxide nanoparticles: antibacterial activity and toxicity mechanism. Nano-Micro Lett 7:219–242CrossRef Sirelkhatim A, Mahmud S, Seeni A, Kiran S, Gulzar T (2015) Review on zinc oxide nanoparticles: antibacterial activity and toxicity mechanism. Nano-Micro Lett 7:219–242CrossRef
Zurück zum Zitat Subash AA, Chandramouli KV, Ramachandran T, Rajendran R, Muthusamy M (2012) Preparation, characterization, and functional analysis of zinc oxide nanoparticle-coated cotton fabric for antibacterial efficacy. J Text Inst 103:298–303 Subash AA, Chandramouli KV, Ramachandran T, Rajendran R, Muthusamy M (2012) Preparation, characterization, and functional analysis of zinc oxide nanoparticle-coated cotton fabric for antibacterial efficacy. J Text Inst 103:298–303
Zurück zum Zitat Uysala I, Severcana F, Evis Z (2013) Characterization by Fourier transform infrared spectroscopy of hydroxyapatite co-doped with zinc and fluoride. Ceram Int 39:7727–7733CrossRef Uysala I, Severcana F, Evis Z (2013) Characterization by Fourier transform infrared spectroscopy of hydroxyapatite co-doped with zinc and fluoride. Ceram Int 39:7727–7733CrossRef
Zurück zum Zitat Vigneshwaran N, Sampath K, Kathe AA, Varadarajan PV, Prasad V (2006) Functional finishing of cotton fabric using zinc oxide—soluble starch nano composites. Nanotechnology 17:5087–5095CrossRef Vigneshwaran N, Sampath K, Kathe AA, Varadarajan PV, Prasad V (2006) Functional finishing of cotton fabric using zinc oxide—soluble starch nano composites. Nanotechnology 17:5087–5095CrossRef
Metadaten
Titel
A simple and efficient protocol to develop durable multifunctional property to cellulosic materials using in situ generated nano-ZnO
verfasst von
A. Arputharaj
Vigneshwaran Nadanathangam
Sanjeev R. Shukla
Publikationsdatum
25.05.2017
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 8/2017
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-017-1335-5

Weitere Artikel der Ausgabe 8/2017

Cellulose 8/2017 Zur Ausgabe