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Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 1/2019

31.10.2018

A study on graphene/tin oxide performance as negative electrode compound for lithium battery application

verfasst von: Atef Y. Shenouda, Anton A. Momchilov

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 1/2019

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Abstract

A novel negative (anode) material for lithium-ion batteries, tin oxide particles covered with graphene (SnO/graphene) prepared from graphite was fabricated by hydrothermal synthesis. The structure and morphology of the composite were characterized by Raman spectra, FTIR spectra, XRD, XPS and FESEM. It is observed that the G and 2D bands (1581 and 2831 cm−1, respectively) have more intensity in graphene rather than graphite. EIS was carried out. It is observed that the lowest Warburg impedance coefficient, σw, is 24.39 Ω s0.5 for Li/SnO–graphene (3:1) cell. The reversible specific capacity of Li/SnO–graphene (3:1) cell was about 0.950 Ah g−1 after 100 cycles at current density current 10−2 A g−1. These results indicate that 3 SnO:1 graphene possesses superior cycle performance and high rate capability. The enhanced electrochemical performances can be ascribed to the characteristic structure of tin oxide with graphene shells, which buffer the volume change of the metallic tin and prevent the detachment and agglomeration of pulverized tin.
Vorheriger Artikel Facile synthesis of SiO2/C anode using PVC as carbon source for lithium-ion batteries
Nächster Artikel Thermal decomposition followed by acid etching to synthesize Fe3O4@C for lithium storage

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Literatur
1.
M.H. Liang, L.J. Zhi, Graphene-based electrode materials for rechargeable lithium batteries. J. Mater. Chem. 19, 5871–5878 (2009)CrossRef
2.
S.M. Paek, E.J. Yoo, I. Honma, Enhanced cyclic performance and lithium storage capacity of SnO2/graphene nanoporous electrodes with three-dimensionally delaminated flexible structure. Nano Lett. 9, 72–75 (2009)CrossRef
3.
A.Y. Shenouda, H.K. Liu, Electrochemical behaviour of tin borophosphate negative electrodes for energy storage systems. J. Power Sources 185, 1386–1391 (2008)CrossRef
4.
A.Y. Shenouda, H.K. Liu, Studies on electrochemical behaviour of zinc-doped LiFePO4 for lithium battery positive electrode. J. Alloys Compd. 477, 498–503 (2009)CrossRef
5.
M. Reddy, G. Subba Rao, B. Chowdari, Metal oxides and oxysalts as anode materials for Li ion. Batteries Chem. Rev. 113, 5364–5457 (2013)
6.
J.S. Chen, Y.L. Cheah, Y.T. Chen, N. Jayaprakash, S. Madhavi, Y.H. Yang, SnO2 nanoparticles with controlled carbon nanocoating as high-capacity anode materials for lithium-ion batteries. J. Phys. Chem. C 113, 20504–20508 (2009)CrossRef
7.
W. Yue, S. Yang, Y. Ren, X. Yang, In situ growth of Sn, SnO on graphene nanosheets and their application as anode materials for lithium-ion batteries. Electrochim. Acta 92, 412–420 (2013)CrossRef
8.
Y. Wang, M. Wu, Z. Jiao, J.Y. Lee, Sn@CNT and Sn@C@CNT nanostructures for superior reversible lithium ion storage. Chem. Mater. 21, 3210–3215 (2009)CrossRef
9.
X.W. Lou, Y. Wang, C.L. Yuan, J.Y. Lee, L.A. Archer, Template-free synthesis of SnO2 hollow nanostructures with high lithium storage capacity. Adv. Mater. 18, 2325–2329 (2006)CrossRef
10.
S.J. Han, B.C. Jang, T. Kim, S.M. Oh, T. Hyeon, Simple synthesis of hollow tin dioxide microspheres and their application to lithium-ion battery anodes. Adv. Funct. Mater. 15, 1845–1850 (2005)CrossRef
11.
G. Wu, M. Wu, D. Wang, L. Yin, J. Ye, S. Deng, Z. Zhu, W. Ye Guiliang, Z. Li, A facile method for in-situ synthesis of SnO2/graphene as a high performance anode material for lithium-ion batteries. Appl. Surf. Sci. 315, 400–406 (2014)CrossRef
12.
L.Y. Jiang, X.L. Wu, Y.G. Guo, L.J. Wan, SnO2-based hierarchical nano microstructures: facile synthesis and their applications in gas sensors and lithium-ion batteries. J. Phys. Chem. C 113, 14213–14219 (2009)CrossRef
13.
M.S. Park, Y.M. Kang, S.X. Dou, H.K. Liu, Reduction-free synthesis of carbon-encapsulated SnO2 nanowires and their superiority in electrochemical performance. J. Phys. Chem. C 112, 11286–11289 (2008)CrossRef
14.
X.W. Lou, D. Deng, J.Y. Lee, L.A. Archer, Preparation of SnO2/carbon composite hollow spheres and their lithium storage properties. Chem. Mater. 20, 6562–6566 (2008)CrossRef
15.
M.S. Parka, Y.M. Kang, J.H. Kima, G.X. Wang, S.X. Dou, H.K. Liu, Effects of low-temperature carbon encapsulation on the electrochemical performance of SnO2 nanopowders. Carbon 46, 35–40 (2008)CrossRef
16.
X.W. Lou, J.S. Chen, P. Chen, L.A. Archer, One-pot synthesis of carbon-coated SnO2 nanocolloids with improved reversible lithium storage properties. Chem. Mater. 21, 2868–2874 (2009)CrossRef
17.
K.S. Novoselov, A.K. Geim, S.V. Morozov, D. Jiang, Y. Zhang, S.V. Dubonos, Electric field effect in atomically thin carbon films. Science 30, 6666–6669 (2004)
18.
F. Miao, S. Wijeratne, Y. Zhang, U.C. Coskun, W. Bao, C.N. Lau, Phase-coherent transport in graphene quantum billiards. Science 317, 1530–15333 (2007)CrossRef
19.
N.M.R. Peres, A.H. Castro Neto, F. Guinea, Electronic properties of disordered two-dimensional carbon. Phys. Rev. B 73, 125411–125419 (2006)CrossRef
20.
A.A. Balandin, S. Ghosh, W.Z. Bao, I. Calizo, D. Teweldebrhan, F. Miao, Superior thermal conductivity of single-layer grapheme. Nano Lett. 8, 902–907 (2008)CrossRef
21.
B.J. Li, H.Q. Cao, ZnO@graphene composite with enhanced performance for the removal of dye from water. J. Mater. Chem. 21, 3346–3349 (2011)CrossRef
22.
Q. Guo, Z. Zheng, H. Gao, J. Ma, X. Qin, SnO2/graphene composite as highly reversible anode materials for lithium ion batteries. J. Power Sources 240, 149–154 (2013)CrossRef
23.
G.D. Jiang, Z.F. Lin, C. Chen, L.H. Zhu, Q. Chang, N. Wang, W. Wei, H.Q. Tang, TiO2 nanoparticles assembled on graphene oxide nanosheets with high photocatalytic activity for removal of pollutants. Carbon 49, 2693–2701 (2011)CrossRef
24.
X. Liu, M. Wu, M. Li, X. Pan, J. Chen, X. Bao, Facile encapsulation of nanosized SnO2 particles in carbon nanotubes as an efficient anode of Li-ion batteries. J. Mater. Chem. A 1, 9527–9535 (2013)CrossRef
25.
S. Yang, W. Yue, J. Zhu, Y. Ren, X. Yan, Graphene-based mesoporous SnO2 with enhanced electrochemical performance for lithium-ion batteries. Adv. Funct. Mater. 23, 3570–3576 (2013)CrossRef
26.
Y.G. Zhu, Y. Wang, J. Xie, G.S. Cao, T.-J. Zhu, X. Zhao, H.Y. Yang, Effects of graphene oxide function groups on SnO2/graphene nanocomposites for lithium storage application. Electrochim. Acta 154, 338–344 (2015)CrossRef
27.
J. Su, Y. Chia, M.T. Tan, P.S. Khiew, J.K. Chin, H. Lee, D.C.S. Bien, A.S. Teh, C.W. Siong, Facile synthesis of few-layer graphene by mild solvent thermal exfoliation of highly oriented pyrolytic graphite. Chem. Eng. J. 231, 1–11 (2013)CrossRef
28.
J. Hodkiewicz, Characterizing Graphene with Raman Spectroscopy (Thermo Fisher Scientific, Madison, 2010)
29.
X. Fu, X. Song, Y. Zhang, Facile preparation of graphene sheets from synthetic graphite. Mater. Lett. 70, 181–184 (2012)CrossRef
30.
M.Z. Iqbal, F. Wang, H. Zhao, M.Y. Rafique, J. Wang, Q. Li, Structural and electrochemical properties of SnO nanoflowers as an anode material for lithium ion batteries. Scripta Mater. 67, 665–668 (2012)CrossRef
31.
K. Satheesh, R. Jayave, Synthesis and electrochemical properties of reduced graphene oxide via chemical reduction using thiourea as a reducing agent. Mater. Lett. 113, 5–8 (2013)CrossRef
32.
P. Lian, J. Wang, D. Cai, L. Ding, Q. Jia, H. Wang, Porous SnO2@C/graphene nanocomposite with 3D carbon conductive network as a superior anode material for lithium-ion batteries. Electrochim. Acta 116, 103–110 (2014)CrossRef
33.
M. Aziz, S.S. Abbas, W.R. Baharom, W. Zuraidah, W. Mahmud, Structure of SnO2 nanoparticles by sol–gel method. Mater. Lett. 74, 62–64 (2012)CrossRef
34.
Y. Geng, S.J. Wang, J.-K. Kim, Preparation of graphite nanoplatelets and graphene sheets. J. Colloid Interface Sci. 336, 592–598 (2009)CrossRef
35.
H.C. Schniepp, J. Li, M.J. Mcallister, H. Sai, M. Herrera-Alonso, D.H. Adamson, R.K. Prud’homme, R. Car, D.A. Saville, I.A. Aksay, Functionalized single graphene sheets derived from splitting graphite oxide. J. Phys. Chem. B 110, 8535–8539 (2006)CrossRef
36.
A.Y. Shenouda, H.K. Liu, Preparation, characterization, and electrochemical performance of Li2CuSnO4 and Li2CuSnSiO6 electrodes for lithium batteries. J. Electrochem. Soc. 157, A1183–A1187 (2010)CrossRef
37.
X. Zhu, Y. Zhu, S. Murali, M.D. Stoller, R.S. Ruof, Reduced graphene oxide/tin oxide composite as an enhanced anode material for lithium ion batteries prepared by homogenous co-precipitation. J. Power Sources 196, 6473–6477 (2011)CrossRef
Metadaten
Titel
A study on graphene/tin oxide performance as negative electrode compound for lithium battery application
verfasst von
Atef Y. Shenouda
Anton A. Momchilov
Publikationsdatum
31.10.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 1/2019
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-018-0265-9

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