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Erschienen in: Journal of Materials Science 18/2017

05.06.2017 | Energy materials

A three-dimensional network structure Si/C anode for Li-ion batteries

verfasst von: Ying Jiang, Shi Chen, Daobin Mu, Borong Wu, Qi Liu, Zhikun Zhao, Feng Wu

Erschienen in: Journal of Materials Science | Ausgabe 18/2017

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Abstract

A three-dimensional (3D) network structure Si/C anode with large pores is fabricated by using gelatin-PVA as carbon source. Silicon particles are embedded in the 3D network carbon skeleton. Gaussian calculation and FTIR test are employed to analyze the role of molecules interaction in forming the 3D network structure. The modified Si/C anode exhibits a reversible capacity of 830 mA h g−1 after 100 cycles at 400 mA g−1, and a capacity of 810 mA h g−1 at 1.6 A g−1 and 521 mA h g−1 at 3.2 A g−1. The 3D network structure with large pores benefits the electrolyte penetration, and the carbon coating layer avoids the direct contact of silicon particles with the electrolyte. The carbon layer can also help buffer the volume expansion of silicon, which is good to the cycling stability. All these aspects contribute to the enhanced electrochemical performance of the Si anode.

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Metadaten
Titel
A three-dimensional network structure Si/C anode for Li-ion batteries
verfasst von
Ying Jiang
Shi Chen
Daobin Mu
Borong Wu
Qi Liu
Zhikun Zhao
Feng Wu
Publikationsdatum
05.06.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 18/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1253-9

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