Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Nanoparticle Research
Erschienen in: Journal of Nanoparticle Research 6/2015

01.06.2015 | Brief Communication

Additives to disturb LiMn0.8Fe0.2PO4 growth and their influence on performance

verfasst von: Guangrong Du, Xueyi Guo, Wenchao Yang, Yujing Bi, Rui Du, Yang Liu, Deyu Wang

Erschienen in: Journal of Nanoparticle Research | Ausgabe 6/2015

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

In this work, nano-LiMn0.8Fe0.2PO4/C is synthesized via dimethyl sulfoxide-assisted co-precipitation route, and various additives are introduced to disturb the phosphate crystal growth. Among the investigated systems, introducing beta-cyclodextrin and ascorbic acid decreases the surface area of the prepared samples, whereas involving hexadecyltrimethyl ammonium bromide (CTAB) effectively diminishes the particle size of LiMn0.8Fe0.2PO4. Due to the reduced diffusion length and augmented active area, samples from systems containing CTAB exhibited improved electrochemical performance, 155 mAh g−1 at 0.05 C and 120 mAh g−1 at 5 C, relative to the control sample (152 and 114 mAh g−1 at 0.05 and 5 C). Our results indicate that the LiMnPO4 kinetics could be tailored using appropriate additives.
Vorheriger Artikel Double-band enhancement of effective third-order nonlinear susceptibility in gold-dielectric-gold multilayer nanoshells
Nächster Artikel Synthesis and surface modification of magnetic nanoparticles for potential applications in sarcomas

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
Aravindan V, Gnanaraj J, Lee YS, Madhavi S (2013) LiMnPO4: a next generation cathode material for lithium-ion batteries. J Mater Chem A 1(11):3518–3539CrossRef
Bi Y, Yang W, Yang B, Wang C, Wang D, Shi S (2014) Influence of Li3V2(PO4)3 complexing on the performance of LiMnPO4 based materials utilized in lithium ion battery. Ceram Int 40(5):7637–7641CrossRef
Chung SY, Kim YM, Lee S, Oh SH, Kim JG, Choi SY, Kim YJ, Kang SJL (2012) Cation disordering by rapid crystal growth in olivine-phosphate nanocrystals. Nano Lett 12(6):3068–3073CrossRef
Delacourt C, Poizot P, Morcrette M, Tarascon JM, Masquelier C (2004) One-step low temperature route for the preparation of electrochemically active LiMnPO4 powders. Chem Mater 16(1):93–99CrossRef
Doi T, Yatomi S, Kida T, Okada S, Yamaki J (2009) Liquid-phase synthesis of uniformly nanosized LiMnPO4 particles and their electrochemical properties for lithium-ion batteries. Cryst Growth Des 9(12):4990–4992CrossRef
Drezen T, Kwon NH, Bowen P, Teerlinck I, Isono M, Exnar I (2007) Effect of particle size on LiMnPO4 cathodes. J Power Sources 174(2):949–953CrossRef
Guo YG, Hu JS, Wan LJ (2008) Nanostructured materials for electrochemical energy conversion and storage devices. Adv Mater 20:2878–2887CrossRef
Guo H, Wu C, Xie J, Zhang S, Cao G, Zhao X (2014) Controllable synthesis of high-performance LiMnPO4 nanocrystals by a facile one-spot solvothermal process. J Mater Chem A 2(27):10581–10588CrossRef
Huo ZQ, Cui YT, Wang D, Dong Y, Chen L (2014) The influence of temperature on a nutty-cake structural material: LiMn1−x Fe x PO4 composite with LiFePO4 core and carbon outer layer for lithium-ion battery. J Power Sources 245:331–336CrossRef
Liu Z, Xu B, Xing Y, Li J, Zhang L, Wang L, Fang S (2015) Determination of the relationship between particle size and electrochemical performance of uncoated LiFePO4 materials. J Nanopart Res 17:163CrossRef
Lu Q, Hutchings GS, Zhou Y, Xin HL, Zheng HM, Jiao F (2014) Nanostructured flexible Mg-modified LiMnPO4 matrix as high-rate cathode materials for Li-ion batteries. J Mater Chem A 2(18):6368–6373CrossRef
Ma Z, Shao G, Wang X, Song J, Wang G, Liu T (2014) Solvothermal synthesis of LiFePO4 nanoplates with (010) plane and the uniform carbon coated on their surface by esterification reaction. Mater Chem Phys 143(3):969–976CrossRef
Malik R, Abdellahi A, Ceder G (2013) A critical review of the Li insertion mechanisms in LiFePO4 electrodes. J Electrochem Soc 160(5):A3179–A3197CrossRef
Meligrana G, Lupo FD, Ferrari S, Destro M, Bodoardo S, Garino N, Gerbaldi C (2013) Surfactant-assisted mild hydrothermal synthesis to nanostructured mixed orthophosphates LiMn y Fe1-y PO4/C lithium insertion cathode materials. Electrochim Acta 105:99–109CrossRef
Örnek A, Bulut E, Can M, Özacar M (2013) Characteristics of nanosized LiNi x Fe1−x PO4/C (x  =  0.00-0.20) composite material prepared via sol-gel-assisted carbothermal reduction method. J Solid State Electrochem 17(12):3101–3107CrossRef
Paclhi AK, Nanjunclaswamy KS, Masquelier C, Okada S, Gooclenoug JB (1997) Phospho-oliviens as positive-electrode materials for rechargeable lithium batteries. J Electrochem Soc 144(4):1188–1194CrossRef
Park OK, Cho Y, Lee S, Yoo HC, Song HK, Cho J (2011) Who will drive electric vehicles, olivine or spinel? Energy Environ Sci 4(5):1621–1633CrossRef
Satou Y, Komine S, Park S, Yao T (2014) Relaxation analysis of LiMnPO4-based olivine-type material. Solid State Ion 262:35–38CrossRef
Song J, Wang L, Shao G, Shi M, Ma Z, Wang G, Song W, Liu S, Wang C (2014) Controllable synthesis, morphology evolution and electrochemical properties of LiFePO4 cathode materials for Li-ion batteries. Phys Chem Chem Phys 16:7728–7733CrossRef
Su K, Liu F, Chen J (2013) Preparation of high performance carbon-coated LiMnPO4 nanocomposite by an acetate-assisted antisolvent precipitation method. J Power Sources 232:234–239CrossRef
Wang D, Buqa H, Crouzet M, Deghenghi G, Drezen T, Exnar I, Kwon NH, Miners JH, Polletto L, Graetzel M (2009) High-performance, nano-structured LiMnPO4 synthesized via a polyol method. J Power Sources 189:624–628CrossRef
Wang D, Ouyang C, Drezen T, Exnar I, Kay A, Kwon NH, Gouerec P, Miners KH, Wang M, Greatzel M (2010) Improving the electrochemical activity of LiMnPO4 via Mn-site substitution. J Electrochem Soc 157:A225–A229CrossRef
Wang F, Yang J, Gao P, Li YN, Wang J (2011a) Morphology regulation and carbon coating of LiMnPO4 cathode material for enhanced electrochemical performance. J Power Sources 196(23):10258–10262CrossRef
Wang YR, Chen YF, Cheng SQ, He LN (2011b) Improving electrochemical performance of LiMnPO4 by Zn doping using a facile solid state method. Korean J Chem Eng 28(3):964–968CrossRef
Wang J, Yang J, Zhang Y, Li Y, Tang Y, Banis MN, Li X, Liang G, Li R, Sun X (2013) Interaction of carbon coating on LiFePO4: a local visualization study of the influence of impurity phases. Adv Funct Mater 23(7):806–814CrossRef
Wu L, Zhong S, Lu J, Liu J, Lv F (2013a) Synthesis of Cr-doped LiMnPO4/C cathode materials by sol-gel combined ball milling method and its electrochemical properties. Ionics 19(7):1061–1065CrossRef
Wu XL, Guo YG, Su J, Xiong JW, Zhang YL, Wan LJ (2013b) Carbon-nanotube-decorated nano-LiFePO4@C cathode material with superior high-rate and low-temperature performances for lithium-ion batteries. Adv Energy Mater 3(9):1155–1160CrossRef
Yang J, Xu JJ (2006) Synthesis and characterization of carbon-coated lithium transition metal phosphates LiMPO4 (M = Fe, Mn Co, Ni) prepared via a nonaqueous sol-gel route. J Electrochem Soc 153(4):A716–A723CrossRef
Yang Z, Xia J, Zhi L, Zhang W, Pei B (2013) An improved solid-state reaction route to Mg2+-doped LiFePO4/C cathode material for Li-ion battery. Ionics 20(2):169–174CrossRef
Yang M, Guo Y, Wang Q, Xie J (2014) Synthesis and properties of optimized LiFePO4/C by a CVD-assisted two-step coating method. J Nanopart Res 16:2598CrossRef
Yang W, Bi Y, Qin Y, Liu Y, Zhang X, Yang B, Wu Q, Wang D, Shi S (2015) LiMn0.8Fe0.2PO4/C cathode material synthesized via co-precipitation method with superior high-rate and low-temperature performances for lithium-ion batteries. J Power Sources 275:785–791CrossRef
Yoshida J, Stark M, Holzbock J, Husing N, Nakanishi S, Iba H, Abe H, Naito M (2013) Analysis of the size effect of LiMnPO4 particles on the battery properties by using STEM-EELS. J Power Sources 226:122–126CrossRef
Zhang XD, Bi ZY, He W, Yang G, Liu H, Yue Y (2014) Fabricating high-energy quantum dots in ultra-thin LiFePO4 nanosheet using a multifunctional high-energy biomolecule-ATP. Energy Environ Sci 7:2285–2294CrossRef
Zhao Y, Peng L, Liu B, Yu G (2014) Single-crystalline LiFePO4 nanosheets for high-rate li-ion batteries. Nano Lett 14(5):2849–2853CrossRef
Metadaten
Titel
Additives to disturb LiMn0.8Fe0.2PO4 growth and their influence on performance
verfasst von
Guangrong Du
Xueyi Guo
Wenchao Yang
Yujing Bi
Rui Du
Yang Liu
Deyu Wang
Publikationsdatum
01.06.2015
Verlag
Springer Netherlands
Erschienen in
Journal of Nanoparticle Research / Ausgabe 6/2015
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-015-3077-3

Weitere Artikel der Ausgabe 6/2015

Journal of Nanoparticle Research 6/2015 Zur Ausgabe

Research Paper

Pulmonary toxicity of well-dispersed titanium dioxide nanoparticles following intratracheal instillation

Research Paper

Phytotoxicity, uptake, and accumulation of silver with different particle sizes and chemical forms

Erratum

Erratum to: Encapsulated heterogeneous base catalysts onto SBA-15 nanoporous material as highly active catalysts in the transesterification of sunflower oil to biodiesel

Research Paper

Integrated probabilistic risk assessment for nanoparticles: the case of nanosilica in food

Research Paper

All-proportional solid-solution Rh–Pd–Pt alloy nanoparticles by femtosecond laser irradiation of aqueous solution with surfactant

Research Paper

Experimental and numerical investigation of the effective electrical conductivity of nitrogen-doped graphene nanofluids

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise