nach oben

Erschienen in:

2011 | OriginalPaper | Buchkapitel

55. Adhesives with Nanoparticles

verfasst von : Dr. Ambrose C. Taylor

Erschienen in: Handbook of Adhesion Technology

Verlag: Springer Berlin Heidelberg

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

The increased commercial availability and the reduced prices of nanoparticles are leading to their incorporation in polymers and structural adhesives. This chapter outlines the principal types of nanoparticles, and the methods that may be used to disperse the particles in a polymer matrix. It discusses how nanoparticles can alter the mechanical properties (e.g., stiffness), electrical properties (e.g., conductivity), functional properties (e.g., permeability, glass transition temperature), and fracture performance of thermoset polymers. The effect of nanoparticles on joint performance is also discussed.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Vorheriges Kapitel Biological Fibrillar Adhesives: Functional Principles and Biomimetic Applications

Nächstes Kapitel Adhesive Dentistry

Ahmed S, Jones FR (1990) A review of particulate reinforcement theories for polymer composites. J Mater Sci 25:4933

Ajayan PM, Stephan O et al (1994) Aligned carbon nanotube arrays formed by cutting a polymer resin-nanotube composite. Science 265:1212

Alexandre M, Dubois P (2000) Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials. Mater Sci Eng R 28:1

Azimi HR, Pearson RA et al (1996a) Fatigue of hybrid epoxy composites: Epoxies containing rubber and hollow glass spheres. Polym Eng Sci 36:2352

Azimi HR, Pearson RA et al (1996b) Fatigue of rubber-modified epoxies: effect of particle size and volume fraction. J Mater Sci 31:3777

Baik Y, Lee S et al (2005) Unidirectional alignment of carbon nano-sized fiber using drawing process. J Mater Sci 40:6037

Bechelany M, Brioude A et al (2007) Large-scale preparation of faceted Si₃N₄ nanorods from beta-SiC nanowires. Nanotechnology 18:335305

Becker O, Simon GP (2006) Epoxy nanocomposites based on layered silicates and other nanostructured fillers. In: Mai YW, Yu ZZ (eds) Polymer nanocomposites. Woodhead, Cambridge, p 594

Beyer G (2002) Carbon nanotubes as flame retardants for polymers. Fire Mater 26:291

Blackman BRK, Kinloch AJ et al (2007) The fracture and fatigue behaviour of nano-modified epoxy polymers. J Mater Sci 42:7049

Brnardic I, Macan J et al (2008) Thermal degradation kinetics of epoxy/organically modified montmorillonite nanocomposites. J Appl Polymer Sci 107:1932

Brooker RD, Blackman BRK et al (2008) Nano-Reinforcement of Epoxy/Thermoplastic Blends. 31st Annual Meeting of the Adhesion Society, Austin, USA, Adhesion Society, Blacksburg, USA

Brooker RD, Kinloch AJ et al (2010) The morphology and fracture properties of thermoplastic-toughened epoxy polymers. J Adhesion 86:726

Brown DM, Kinloch IA et al (2007) An in vitro study of the potential of carbon nanotubes and nanofibres to induce inflammatory mediators and frustrated phagocytosis. Carbon 45:1743

Bugnicourt E, Galy J et al (2007) Effect of sub-micron silica fillers on the mechanical performances of epoxy-based composites. Polymer 48:1596

Cao Y, Irwin PC et al (2004) The future of nanodielectrics in the electrical power industry. IEEE Trans Dielectric Electrical Insul 11:797

Chakrabarti S, Nagasaka T et al (2006) Growth of super long aligned brush-like carbon nanotubes. Japan J Appl Phys 2 Lett and Expr Lett 45:L720

Chandradass J, Bae D-S (2008) Preparation and Properties of Barium Titanate Nanopowder/Epoxy Composites. Mater Manuf Process 23:116

CheapTubes (2009) http://www.cheaptubes.com. Retrieved 4 Nov 2009

Chen C, Curliss D (2001) Resin matrix composites: Organoclay-aerospace epoxy nanocomposites, Part II. SAMPE J 37:11

Chen TK, Jan YH (1992) Fracture mechanism of toughened epoxy-resin with bimodal rubber-particle size distribution. J Mater Sci 27:111

Chen XQ, Saito T et al (2001) Aligning single-wall carbon nanotubes with an alternating-current electric field. Appl Phys Lett 78:3714

Demczyk BG, Wang YM et al (2002) Direct mechanical measurement of the tensile strength and elastic modulus of multiwalled carbon nanotubes. Mater Sci Eng A 334:173

Dodiuk H, Belinski I et al (2006) Polyurethane adhesives containing functionalized nanoclays. J Adhesion Sci Tech 20:1345

Dompas D, Groeninckx G (1994) Toughening behavior of rubber-modified thermoplastic polymers involving very small rubber particles. 1. A criterion for internal rubber cavitation. Polymer 35:4743

Feynman RP (1959) There’s plenty of room at the bottom – an invitation to enter a new field of physics http://www.zyvex.com/nanotech/feynman.html. Accessed 9 April 2008

Fiedler B, Gojny FH et al (2006) Fundamental aspects of nano-reinforced composites. Composites Sci Tech 66:3115

Gilbert EN, Hayes BS et al (2003) Nano-alumina modified epoxy based film adhesives. Polym Eng Sci 43:1096

Gilman JW (1999) Flammability and thermal stability studies of polymer layered-silicate (clay) nanocomposites. Appl Clay Sci 15:31

Gilman JW, Harris RH et al (1999a) Cyanate ester clay nanocomposites: synthesis and flammability studies. Evolving and Revolutionary Technologies for the New Millennium 44th International SAMPE Symposium/Exhibition, Long Beach, CA, USA, Society for the Advancement of Material and Process Engineering (SAMPE)

Gilman JW, Kashiwagi T et al (1999b) Flammability studies of polymer layered silicate nanocomposites: polyolefin, epoxy and vinyl ester resins. In: Ak-Malaika S, Golovoy A et al (eds) Chemistry and technology of polymer additives. Blackwell Science, Malden, p 249

Gilman JW, Harris RH et al (2000a) Phenolic cyanate ester nanocomposites: effect of ammonium ion structure on flammability and nano-dispersion. Spring Meeting, Division of Polymeric Materials: Science and Engineering, American Chemical Society, San Francisco, USA, American Chemical Society

Gilman JW, Jackson CL et al (2000b) Flammability Properties of Polymer-Layered-Silicate Nanocomposites. Polypropylene and Polystyrene Nanocomposites. Chem Mater 12:1866

Gintert MJ, Jana SC et al (2007) A novel strategy for nanoclay exfoliation in thermoset polyimide nanocomposite systems. Polymer 48:4166

Gojny FH, Nastalczyk J et al (2003) Surface modified multi-walled carbon nanotubes in CNT/epoxy-composites. Chem Phys Lett 370:820

Gojny FH, Wichmann MHG et al (2004) Carbon nanotube-reinforced epoxy-composites: enhanced stiffness and fracture toughness at low nanotube content. Composites Sci Tech 64:2363

Gojny FH, Wichmann MHG et al (2006) Evaluation and identification of electrical and thermal conduction mechanisms in carbon nanotube/epoxy composites. Polymer 47:2036

Gordon JE (1978) The new science of strong materials or why you don’t fall through the floor. Penguin, Harmondsworth

Green K, Dean D et al (2006) Aligned carbon nanofiber/epoxy nanocomposites. Polym Mater Sci Eng 94:53

Gusev AA, Lusti HR (2001) Rational design of nanocomposites for barrier applications. Adv Mater 13:1641

Hackman I, Hollaway L (2006) Epoxy-layered silicate nanocomposites in civil engineering. Composites Pt A 37:1161

Harper T (2003) What is nanotechnology? Nanotechnology 14:U5

Harris PJF (1999) Carbon nanotubes and related structures: new materials for the twenty-first century. Cambridge University Press, Cambridge

Harris PJF (2009) Carbon nanotube science: synthesis, properties and applications. Cambridge University Press, Cambridge

Hay J, Shaw S (2001) Into the Labyrinth. Chem Brit 2001:34

Hsiao K-T, Alms J et al (2003) Use of epoxy/multiwalled carbon nanotubes as adhesives to join graphite fibre reinforced polymer composites. Nanotechnology 14:791

Hsieh TH, Kinloch AJ et al (2010) The toughness of epoxy polymers and fibre composites modified with rubber microparticles and silica nanoparticles. J Mater Sci 45:1193

ICBA (2008) International Carbon Black Association. http://www.carbon-black.org. Retrieved 9 April 2008

Iijima S (1991) Helical microtubules of graphitic carbon. Nature 354:56

Iijima S, Ichihashi T (1993) Single-shell carbon nanotubes of 1-nm diameter. Nature 363:603

Imai T, Sawa F et al (2006) Effects of nano- and micro-filler mixture on electrical insulation properties of epoxy based composites. IEEE Trans Dielectric Electrical Insul 13:319

Johnsen BB, Kinloch AJ et al (2007) Toughening mechanisms of nanoparticle-modified epoxy polymers. Polymer 48:530

Kaneka (2008) http://www.kaneka.com. Retrieved 9 April 2008

Karger-Kocsis J, Friedrich K (1992) Fatigue crack-propagation and related failure in modified, anhydride-cured epoxy-resins. Colloid Polymer Sci 270:549

Karger-Kocsis J, Gryshchuk O et al (2003) Interpenetrating vinylester/epoxy resins modified with organophilic layered silicates. Composites Sci Tech 63:2045

Kathi J, Rhee K (2008) Surface modification of multi-walled carbon nanotubes using 3-aminopropyltriethoxysilane. J Mater Sci 43:33

Kawaguchi T, Pearson RA (2003) The effect of particle-matrix adhesion on the mechanical behavior of glass filled epoxies. Part 2. A study on fracture toughness. Polymer 44:4239

Kinloch AJ, Lee JH et al (2003) Toughening structural adhesives via nano- and micro-phase inclusions. J Adhesion 79:867

Kinloch AJ, Maxwell DL et al (1985) The fracture of hybrid-particulate composites. J Mater Sci 20:4169

Kinloch AJ, Mohammed RD et al (2005) The effect of silica nano particles and rubber particles on the toughness of multiphase thermosetting epoxy polymers. J Mater Sci 40:5083

Kinloch AJ, Taylor AC (2002) The Toughening of Cyanate-Ester Polymers. Part I: Physical Modification using Particles, Fibres and Woven-Mats. J Mater Sci 37:433

Kinloch AJ, Taylor AC (2003) Mechanical and fracture properties of epoxy/inorganic micro- and nano-composites. J Mater Sci Lett 22:1439

Kinloch AJ, Taylor AC (2006) The mechanical properties and fracture behaviour of epoxy-inorganic micro- and nano-composites. J Mater Sci 41:3271

Kody RS, Lesser AJ (1999) Yield behavior and energy absorbing characteristics of rubber-modified epoxies subjected to biaxial stress states. Polym Compos 20:250

Koerner H, Hampton E et al (2005) Generating triaxial reinforced epoxy/montmorillonite nanocomposites with uniaxial magnetic fields. Chem Mater 17:1990

Kornmann X (1999) Synthesis and characterisation of thermoset-clay nanocomoposites. Licentiate Thesis. Materials and Manufacturing Engineering Department. University of Lulea, Lulea, Sweden

Lam C-W, James JT et al (2004) Pulmonary toxicity of single-wall carbon nanotubes in mice 7 and 90 days after intratracheal instillation. Toxicol Sci 77:126

Lam C-K, Lau K-T et al (2005) Effect of ultrasound sonication in nanoclay clusters of nanoclay/epoxy composites. Mater Lett 59:1369

Lau K-T, Gu C et al (2004) Stretching process of single- and multi-walled carbon nanotubes for nanocomposite applications. Carbon 42:426

Lazzeri A, Bucknall CB (1993) Dilatational bands in rubber-toughened polymers. J Mater Sci 28:6799

Liang G, Hu X (2004) Preparation and performance of aluminum borate whisker-reinforced epoxy composites. I. Effect of whiskers on processing, reactivity, and mechanical properties. J Appl Polymer Sci 92:1950

Liang YL, Pearson RA (2009) Toughening mechanisms in epoxy-silica nanocomposites (ESNs). Polymer 50:4895

Liu WP, Hoa SV et al (2004) Morphology and performance of epoxy nanocomposites modified with organoclay and rubber. Polym Eng Sci 44:1178

Lu KL, Lago RM et al (1996) Mechanical damage of carbon nanotubes by ultrasound. Carbon 34:814

Martin CA, Sandler JKW et al (2005) Electric field-induced aligned multi-wall carbon nanotube networks in epoxy composites. Polymer 46:877

Messersmith PB, Giannelis EP (1994) Synthesis and characterisation of layered silicate-epoxy nanocomposites. Chem Mater 6:1719

Mohammed RD (2007) Material properties and fracture mechanisms of epoxy nano-composites. PhD thesis. Mechanical Engineering. Imperial College of Science, Technology and Medicine, London

Moloney AC, Kausch HH et al (1983) The fracture of particulate-filled epoxide resins. J Mater Sci 19:1125

Montanari GC, Ciani F et al (2005) Electric strength, space charge and surface discharge characterization of nanostructured epoxy-silicate insulating materials. 2005 International Symposium on Electrical Insulating Materials, vols. 1–3, Tokyo, Inst Electr Engineers Japan

Morisada Y, Miyamoto Y et al (2007) Mechanical properties of SiC composites incorporating SiC-coated multi-walled carbon nanotubes. Int J Refract Met Hard Mater 25:322

Naganuma T, Kagawa Y (2002) Effect of particle size on the optically transparent nano meter-order glass particle-dispersed epoxy matrix composites. Composites Sci Tech 62:1187

Nanoresins (2008) http://www.nanoresins.com. Retrieved 9 April 2008

Oba T (1999) The fatigue behaviour of toughened epoxy polymers. PhD thesis. Mechanical Engineering. Imperial College of Science, Technology and Medicine, London

Patel S, Bandyopadhyay A et al (2006) Synthesis and properties of nanocomposite adhesives. J Adhesion Sci Tech 20:371

Pearson RA, Yee AF (1991) Influence of particle-size and particle-size distribution on toughening mechanisms in rubber-modified epoxies. J Mater Sci 26:3828

Puglia D, Valentini L et al (2003) Analysis of the cure reaction of carbon nanotubes/epoxy resin composites through thermal analysis and Raman spectroscopy. J Appl Polymer Sci 88:452

Radford T (2003) Brave new world or miniature menace? Why Charles fears grey goo nightmare. The Guardian, London, Issued April 29, 2003

Ragosta G, Abbate M et al (2005) Epoxy-silica particulate nanocomposites: Chemical interactions, reinforcement and fracture toughness. Polymer 46:10506

Rosso P, Ye L et al (2006) A toughened epoxy resin by silica nanoparticle reinforcement. J Appl Polymer Sci 100:1849

Rothon RN, Hancock M (1995) General principles guiding selection and use of particulate materials. In: Rothon RN (ed) Particulate-filled polymer composites. Longman Scientific and Technical, Harlow, p 1

Saito R, Dresselhaus G et al (1998) Physical properties of carbon nanotubes. Imperial College, London

Salinas-Ruiz MdM (2009) Development of a rubber toughened epoxy adhesive loaded with carbon nanotubes, for aluminium – polymer bonds. PhD thesis. School of Applied Science, Cranfield University

Sandler J, Shaffer MSP et al (1999) Development of a dispersion process for carbon nanotubes in an epoxy matrix and the resulting electrical properties. Polymer 40:5967

Sandler JKW, Kirk JE et al (2003) Ultra-low electrical percolation threshold in carbon-nanotube-epoxy composites. Polymer 44:5893

Sautereau H, Maazouz A et al (1995) Fatigue behavior of glass bead filled epoxy. J Mater Sci 30:1715

Schadler LS (2003) Polymer-based and polymer-filled nanocomposites. In: Ajayan PM, Schadler LS et al (eds) Nanocomposite science and technology. Wiley-VCH, Weinheim, p 380

Schmid CF, Klingenberg DJ (2000) Mechanical flocculation in flowing fiber suspensions. Phys Rev Lett 84:290

Shaffer MSP, Kinloch IA (2004) Prospects for nanotube and nanofibre composites. Composites Sci Tech 64:2281

Shaffer MSP, Sandler JKW (2006) Carbon nanotube/nanofibre polymer composites. In: Advani SG (ed) Processing and properties of nanocomposites. World Scientific, Singapore

Sheng N, Boyce MC et al (2004) Multiscale micromechanical modeling of polymer/clay nanocomposites and the effective clay particle. Polymer 45:487

SigmaAldrich (2008) http://www.sigmaaldrich.com. Retrieved 9 April 2008

Sohn Lee J (2009) The fatigue behaviour of nano-modified epoxy adhesives. PhD thesis. Department of Mechanical Engineering. Imperial College London, London

Sorrentino A, Gorrasi G et al (2006) Barrier properties of polymer/clay nanocomposites. In: Mai YW, Yu ZZ (eds) Polymer nanocomposites. Woodhead, Cambridge, p 594

Sprenger S, Eger C et al (2003) Nanoadhesives: toughness and high strength. Adhaesion, Kleben and Dichten. 2003:24

Sprenger S, Eger C et al (2004). Nano-modified ambient temperature curing epoxy adhesives. Adhaesion, Kleben and Dichten. 2004:1

Tang Y, Liang G et al (2007) Performance of aluminum borate whisker reinforced cyanate ester resin. J Appl Polymer Sci 106:4131

Tarrant AE (2004) Thermoset-acrylic/layered-silicate nanocomposites: synthesis and structure-property relationships. Imperial College London Thesis, London

Tjong SC (2006) Structural and mechanical properties of polymer nanocomposites. Mater Sci Eng R 53:73

Triantafyllidis KS, LeBaron PC et al (2006) Epoxy-clay fabric film composites with unprecedented oxygen-barrier properties. Chem Mater 18:4393

Vanorio T, Prasad M et al (2003) Elastic properties of dry clay mineral aggregates, suspensions and sandstones. Geophysical J Int 155:319

Wang ZL (ed) (2001) Characterization of nanophase materials. Wiley-VCH, Weinheim

Wang Z, Massam J et al (2000) Epoxy-clay nanocomposites. In: Pinnavaia TJ, Beall GW (eds) Polymer-clay nanocomposites. Wiley, Chichester

Warheit DB, Laurence BR et al (2004) Comparative Pulmonary Toxicity Assessment of Single-wall Carbon Nanotubes in Rats. Toxicol Sci 77:117

Wetzel B, Rosso P et al (2006) Epoxy nanocomposites - fracture and toughening mechanisms. Eng Fract Mech 73:2375

Xie X-L, Mai Y-W et al (2005) Dispersion and alignment of carbon nanotubes in polymer matrix: A review. Mater Sci Eng R 49:89

Yasmin A, Daniel IM (2004) Mechanical and thermal properties of graphite platelet/epoxy composites. Polymer 45:8211

Yasmin A, Abot JL et al (2003) Processing of clay/epoxy nanocomposites by shear mixing. Scr Mater 49:81

Yasmin A, Luo JJ et al (2006a) Mechanical and thermal behavior of clay/epoxy nanocomposites. Composites Sci Tech 66:2415

Yasmin A, Luo JJ et al (2006b) Processing of expanded graphite reinforced polymer nanocomposites. Composites Sci Tech 66:1182

Yin M, Koutsky JA et al (1993) Characterization of carbon microfibers as reinforcement for epoxy resins. Chem Mater 5:1024

Zeng MF, Sun XD et al (2007) Effects of SiO2 nanoparticles on the performance of carboxyl-randomized liquid butadiene-acrylonitrile rubber modified epoxy nanocomposites. J Appl Polymer Sci 106:1347

Zhang H, Zhang Z et al (2006) Property improvements of in situ epoxy nanocomposites with reduced interparticle distance at high nanosilica content. Acta Mater 54:1833

Zhang W, Picu RC et al (2007) Suppression of fatigue crack growth in carbon nanotube composites. Appl Phys Lett 91:193109

Zhou Y, Pervin F et al (2007) Effect vapor grown carbon nanofiber on thermal and mechanical properties of epoxy. J Mater Sci 42:7544

Zhu YQ, Kroto HW et al (2002) A systematic study of ceramic nanostructures generated by arc discharge. Chem Phys Lett 365:457

Zunjarrao S, Sriraman R et al (2006) Effect of processing parameters and clay volume fraction on the mechanical properties of epoxy-clay nanocomposites. J Mater Sci 41:2219

Titel: Adhesives with Nanoparticles
verfasst von: Dr. Ambrose C. Taylor
Verlag: Springer Berlin Heidelberg
Buch: Handbook of Adhesion Technology
Print ISBN: 978-3-642-01168-9

Electronic ISBN: 978-3-642-01169-6

Copyright-Jahr: 2011
DOI: https://doi.org/10.1007/978-3-642-01169-6_55

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht