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Environmental Earth Sciences

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01.04.2019 | Original Article

Adsorption behaviors of Eu(III) on granite: batch, electron probe micro-analysis and modeling studies

verfasst von: Hong Li, Bihong He, Ping Li, Qiaohui Fan, Hanyu Wu, Jianjun Liang, Chunli Liu, Tao Yu

Erschienen in: Environmental Earth Sciences | Ausgabe 8/2019

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Abstract

Although granite has been widely considered as the host rock of the high-level radioactive waste (HLRW) repository in the world, the adsorption behaviors of radionuclides on granite are quite complicated and still unclear, especially at molecular scales. In this study, the adsorption behaviors of europium(III) on Beishan granite (BSG), a preliminary selection of host rock for the HLRW repository in China, were explored under environmental conditions combining batch, electron probe micro-analyzer (EPMA), and modeling approaches. X-ray diffraction (XRD) pattern confirmed that albite, quartz and biotite were the main mineralogical components for the BSG grains. Eu(III) species on BSG grains are predominant as the ion exchange (≡X₃Eu⁰) and the inner sphere complexes of ≡S^wOEu(OH)₂⁰, ≡S^sOEu(OH)₂,⁰ ≡S^sOEu²⁺, and ≡S^wOEu²⁺. EPMA showed that the distribution of Eu(III) on BSG grains was strongly correlated to the biotite, which suggested that biotite is the host phase for retarding trivalent actinides in the BSG grains. The presence of soil humic and fulvic acids could enhance Eu(III) adsorption on BSG grains under low-pH conditions, and inhibit the adsorption under higher pH range.

Vorheriger Artikel Robust multivariate analysis of compositional data of treated wastewaters

Nächster Artikel Soil pollution evaluation and health risk assessment of heavy metals around Douroud cement factory, Iran

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Baek K, Yang JW (2004) Sorption and desorption characteristics of cobalt in clay: Effect of humic acids. Korean J Chem Eng 21(5):989–993CrossRef

Bierkens J, Simkiss K (1990) The use of chemical analogues such as Eu/Am in ecotoxicological studies. Funct Ecology 4(3):445–447CrossRef

Bradbury MH, Baeyens B (2002) Sorption of Eu on Na- and Ca-montmorillonites: experimental investigations and modelling with cation exchange and surface complexation. Geochim Cosmochim Acta 66(13):2325–2334CrossRef

Dario M, Molera M, Allard B (2006) Sorption of europium on TiO₂ and cement at high pH in the presence of organic ligands. J Radioanal Nucl Chem 270(3):495–505CrossRef

Ding CC, Cheng WC, Sun YB, Wang XK (2005) Novel fungus-Fe₃O₄ bio-nanocomposites as high performance adsorbents for the removal of radionuclides. J Hazard Mater 295:127–137CrossRef

Fan QH, Wu WS, Song XP, Xu JZ, Hu JH, Niu ZW (2008) Effect of humic acid, fulvic acid, pH and temperature on the sorption–desorption of Th(IV) on attapulgite. Radiochim Acta 96(3):159–165

Fan QH, Tan XL, Li JX, Wang XK, Wu WS (2009) Sorption of Eu(III) on attapulgite studied by Batch, XPS, and EXAFS techniques. Environ Sci Technol 43(15):5776–5782CrossRef

Fan QH, Li P, Chen YF, Wu WS (2011) Preparation and application of attapulgite/iron oxide magnetic composites for the removal of U(VI) from aqueous solution. J Hazard Mat 192(3):1851–1859CrossRef

Fan QH, Zhao XL, Ma XX, Yang YB, Wu WS, Zheng GD, Wang DL (2015) Comparative adsorption of Eu(III) and Am(III) on TPD. Environ Sci Proc Impacts 17(9):1634–1640CrossRef

Fukushi K, Hasegawa Y, Maeda K, Aoi Y, Tamura A, Arai S, Yamamoto Y, Aosai D, Mizuno T (2013) Sorption of Eu(III) on granite: EPMA, LA-ICP-MS, batch and modeling studies. Environ Sci Technol 47(22):12811–12818CrossRef

Guo ZJ, Xu J, Shi KL, Tang YQ, Wu WS, Tao ZY (2009) Eu(III) adsorption/desorption on Na-bentonite: experimental and modeling studies. Colloids Surf A Physicochem Eng Asp 339(1/3):126–133CrossRef

Holgersson S (2012) Studies on batch sorption methodologies: Eu sorption onto Kivetty granite. Procedia Chem 7(7):629–640CrossRef

Huang XF, He JG, Xu GQ (2009) Pre-selection research on granite mass for high level radioactive waste repository. World Nucl Geosci 26(4):219–227

Ishida K, Kimura T, Saito T, Tanaka S (2009) Adsorption of Eu(III) on a heterogeneous surface studied by time-resolved laser fluorescence microscopy (TRLFM). Environ Sci Technol 43(6):1744–1749CrossRef

Kitamura A, Yamamoto T, Nishikawa S, Moriyama H (1999) Sorption behavior of Am(III) onto granite. J Radioanal Nucl Chem 239(3):449–453CrossRef

Lee SG, Kim Y, Chae BG, Koh DC, Kim KH (2004) The geochemical implication of a variable Eu anomaly in a fractured gneiss core: application for understanding Am behavior in the geological environment. Appl Geochem 19(11):1711–1725CrossRef

Lee SG, Lee KY, Cho SY, Yoon SY, Kim YJ (2006) Sorption properties of ¹⁵²Eu and ²⁴¹Am in geological materials: Eu as an analogue for monitoring the Am behaviors in heterogeneous geological environments. Geosci J 10(2):103–114CrossRef

Li P, Fan Q, Pan D, Liu S, Wu W (2011) Effects of pH, ionic strength, temperature, and humic acid on Eu(III) sorption onto iron oxides. J Radioanal Nucl Chem 289(3):757–764CrossRef

Li P, Liu Z, Ma F, Shi Q, Guo Z, Wu W (2015) Effects of pH, ionic strength and humic acid on the sorption of neptunium(V) to Na-bentonite. J Mol Liq 206:285–292CrossRef

Li P, Ma X, Li H, Li S, Wu H, Xu D, Zheng G, Fan Q (2017a) Sorption mechanism of Th (IV) at iron oxyhydroxide (IOHO)/water interface: Batch, model and spectroscopic studies. J Mol Liq 241:478–485CrossRef

Li P, Wu H, Liang J, Yin Z, Pan D, Fan Q, Xu D, Wu W (2017b) Sorption of Eu(III) at feldspar/water interface: effects of pH, organic matter, counter ions, and temperature. Radiochim Acta 105(12):1049–1058CrossRef

Li P, Wang J, Wang X, He B, Pan D, Liang J, Wang F, Fan Q (2018) Arsenazo-functionalized magnetic carbon composite for uranium(VI) removal from aqueous solution. J Mol Liq 269:441–449CrossRef

Manohar DM, Noeline BF, Anirudhan TS (2006) Adsorption performance of Al-pillared bentonite clay for the removal of cobalt (II) from aqueous phase. Appl Clay Sci 31(3–4):194–206CrossRef

Niu ZW, Fan QH, Wang WH, Xu JZ, Chen L, Wu WS (2009) Effect of pH, ionic strength and humic acid on the sorption of uranium(VI) to attapulgite. Appl Radiat Isot 67(9):1582–1590CrossRef

Pan DQ (2014) Sorption of U(VI), Th(IV) and Eu(III) on mineralogical components of granite and bentonite [D]. Lanzhou University, Lanzhou

Qi W, Tian LL, Liu B, Lin J, Liu D, Tu PC, Liu D, Li Z, Chen XL, Wu WS (2015) Adsorption of Eu(III) on defective magnetic FeNi/RGO composites: effect of pH, ion strength, ions and humic acid. J Radioanal Nucl Chem 303(3):2211–2220

Rabung TH, Geckeis H, Kim JI, Beck HP (1998) Sorption of Eu(III) on a natural hematite: application of a surface complexation model. J Colloid Interf Sci 208(1):153–161CrossRef

Soler JM, Mäder UK (2007) Mineralogical alteration and associated permeability changes induced by a high-pH plume: modeling of a granite core infiltration experiment. Appl Geochem 22(1):17–29CrossRef

Spark KM, Wells JD, Johnson BB (1997) The interaction of a humic acid with heavy metals. J Soil Res 35(1):89–101CrossRef

Strathmann TJ, Myneni SB (2005) Effect of soil fulvic acid on nickel(II) sorption and bonding at the aqueous-boehmite interface. Environ Sci Technol 39(11):4027–4034CrossRef

Sun YN, Chen CL, Tan XL, Shao DD, Li JX, Zhao GX, Yang SB, Wang Q, Wang XK (2012) Enhanced adsorption of Eu(III) on mesoporous Al₂O₃/expanded graphite composites investigated by macroscopic and microscopic techniques. Dalton Trans 43(41):13388–13394CrossRef

Sun YB, Li JX, Wang XK (2014) The retention of uranium and europium onto sepiolite investigated by macroscopic, spectroscopic and modeling techniques. Geochim Cosmochim Acta 140:621–643CrossRef

Tan XL, Fan QH, Wang XK, Grambow B (2009a) Eu(III) sorption to TiO₂ (anatase and rutile): batch, XPS, and EXAFS studies. Environ Sci Technol 43(9):3115–3121CrossRef

Tan XL, Fang M, Li JX, Lu Y, Wang XK (2009b) Adsorption of Eu(III) onto TiO₂: effect of pH, concentration, ionic strength and soil fulvic acid. J Hazard Mat 168(1):458–465CrossRef

Tertre E, Berger G, Simoni E, Castet S, Giffaut E, Loubet M, Catalette H (2006) Europium retention onto clay minerals from 25 to 150 °C: Experimental measurements, spectroscopic features and sorption modeling. Geochim Cosmochim Acta 70(18):4563–4578CrossRef

Ticknor KV, Vilks P, Vandergraaf TT (1996) The effect of fulvic acid on the sorption of and fission products on granite and selected minerals. Appl Geochem 11(4):555–565CrossRef

Wang XK, Dong WM, Dai XX, Wang AX, Du JZ, Tao ZY (2000) Sorption and desorption of Eu and Yb on alumina: Mechanisms and effect of fulvic acid. Appl Radiat Isot 52(2):165–173CrossRef

Wang X, Xu D, Chen L, Tan X, Zhou X, Ren A, Chen C (2006) Sorption and complexation of Eu(III) on alumina: effects of pH, ionic strength, humic acid and chelating resin on kinetic dissociation study. Appl Radiat Isot 64(4):414–421CrossRef

Wang XF, Shi KL, Guo ZJ, Wu WS (2010) Eu(III) adsorption on rutile: Batch experiments and modeling. Sci China Chem 53(12):2628–2636CrossRef

Wang YQ, Fan QH, Li P, Zheng XB, Xu JZ, Jin YR, Wu WS (2011) The sorption of Eu(III) on calcareous soil: effects of pH, ionic strength, temperature foreign ions and humic acid. J Radioanal Nucl Chem 287(1):231–237CrossRef

Wang XX, Sun YB, Alsaedi A, Hayat T, Wang XK (2015) Interaction mechanism of Eu(III) with MX-80 bentonite studied by batch, TRLFS and kinetic desorption techniques. Chem Eng J 264:570–576CrossRef

Wang J, He B, Wei X, Li P, Liang J, Qiang S, Fan Q, Wu W (2018) Sorption of uranyl ions on TiO₂: Effects of pH, contact time, ionic strength, temperature and HA. J Environ Sci. https://doi.org/10.1016/j.jes.2018.03.010 CrossRef

Xu JZ, Fan QH, Niu ZW, Li Y, Li P, Wu WS (2012) Studies of Eu (III) sorption on TiO₂: Effects of pH, humic acid and poly (acrylic acid). Chem Eng J 179:186–192CrossRef

Yu T (2012) Study on sorption of Eu(III) and Am(III) onto red earth and bentonite [D]. Lanzhou University, Lanzhou

Zhang YJ, Fan XH, Su XG, Zeng JS, Wang Y, Zhou D, Liu DJ, Yao J (2005) Sorption behavior of Pu on granite. J Nucl Radiochem 27(3):137–137

Zhao X, Qiang S, Wu H, Yang Y, Shao D, Fang L, Liang J, Li P, Fan Q (2017a) Exploring the sorption mechanism of Ni(II) on illite: batch sorption, modelling, EXAFS and extraction investigations. Sci Rep 7(1):8495CrossRef

Zhao X, Wang Y, Wu H, Fang L, Liang J, Fan Q, Li P (2017b) Insights into the effect of humic acid on Ni(II) sorption mechanism on illite: Batch, XPS and EXAFS investigations. J Mol Liq 248:1030–1038CrossRef

Zhong X, Wang J, Hung ST, Wang SH (2012) The quantitative study of Pluton selection for the disposal repository of high level waste in Beishan. Uranium Geol 28(3):187–192

Zhong XJ, Liu X, Duan SX, Yu SJ, Huang YS, Hayat T, Li JX (2016) The adsorption of Eu(III) on carbonaceous nanofibers: Batch experiments and modeling study. J Mol Liq 222:456–462CrossRef

Zhu YK, Liu HB, Chen TH, Xu B, Li P (2016) Kinetics and thermodynamics of Eu(III) adsorption onto synthetic monoclinic pyrrhotite. J Mol Liq 218:565–570CrossRef

Titel: Adsorption behaviors of Eu(III) on granite: batch, electron probe micro-analysis and modeling studies
verfasst von: Hong Li
Bihong He
Ping Li
Qiaohui Fan
Hanyu Wu
Jianjun Liang
Chunli Liu
Tao Yu
Publikationsdatum: 01.04.2019
Verlag: Springer Berlin Heidelberg
Erschienen in: Environmental Earth Sciences / Ausgabe 8/2019
Print ISSN: 1866-6280
Elektronische ISSN: 1866-6299
DOI: https://doi.org/10.1007/s12665-019-8170-y

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