Skip to main content
Erschienen in: Journal of Nanoparticle Research 12/2016

01.12.2016 | Research Paper

An alkaline one-pot reaction to synthesize luminescent Eu-BTC MOF nanorods, highly pure and water-insoluble, under room conditions

verfasst von: D. Y. Medina-Velazquez, B. Y. Alejandre-Zuniga, S. Loera-Serna, E. M. Ortiz, A. de J. Morales-Ramirez, E. Garfias-Garcia, A. Garcia-Murillo, C. Falcony

Erschienen in: Journal of Nanoparticle Research | Ausgabe 12/2016

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The increasing demand for optoelectronic devices requires the development of luminescent materials with high luminescence efficiency and low energy demands, and the metalorganic frameworks (MOFs) with lanthanides ions offer great potential in this area. The metalorganic materials provide properties of flexibility, low density, low-cost methods of synthesis, and insolubility in water, which gives them an advantage over traditional phosphors. In this study, a benzenetricarboxylate ligand (BTC) with a Eu3+ MOF was synthesized, and its structural and luminescent properties were measured. The metalorganic compound was generated in a one-pot reaction from europium nitrate and trimesic acid precursors. Through characterization by X-ray diffraction powder, infrared spectroscopy, SEM structural characterization, and luminescent spectroscopy, the formation of Europium benzenetricarboxylate (Eu-BTC) MOF nanorods was tested and the calculated value was in the range of 30–60 nm. A red luminescent emission with high intensity was observed for all the procedures.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Aldabergenova SB, Osvet A, Frank G, Strunk HP, Taylor PC, Andreev AA (2002) Blue, green and red emission from Ce3+, Tb3+ and Eu3+ ions in amorphous GaN and AlN thin films. J Non Cryst Solids 299–302(Part 1):709–713. doi:10.1016/S0022-3093(01)01211-X CrossRef Aldabergenova SB, Osvet A, Frank G, Strunk HP, Taylor PC, Andreev AA (2002) Blue, green and red emission from Ce3+, Tb3+ and Eu3+ ions in amorphous GaN and AlN thin films. J Non Cryst Solids 299–302(Part 1):709–713. doi:10.​1016/​S0022-3093(01)01211-X CrossRef
Zurück zum Zitat Bünzli J-CG (1987) The europium(III) ion as spectroscopic probe in bioinorganic chemistry. Inorg Chim Acta 139:219–222CrossRef Bünzli J-CG (1987) The europium(III) ion as spectroscopic probe in bioinorganic chemistry. Inorg Chim Acta 139:219–222CrossRef
Zurück zum Zitat Bünzli J-C, Eliseeva S (2011) Basics of lanthanide photophysics. In: Hänninen P, Härmä H (eds) Lanthanide luminescence, vol 7., Springer Series on FluorescenceSpringer, Berlin, pp 1–45. doi:10.1007/4243_2010_3 CrossRef Bünzli J-C, Eliseeva S (2011) Basics of lanthanide photophysics. In: Hänninen P, Härmä H (eds) Lanthanide luminescence, vol 7., Springer Series on FluorescenceSpringer, Berlin, pp 1–45. doi:10.​1007/​4243_​2010_​3 CrossRef
Zurück zum Zitat D’Vries RF, Snejko N, Iglesias M, Gutiérrez-Puebla E, Monge M (2014) Ln-MOF pseudo-merohedral twinned crystalline family as solvent-free heterogeneous catalysts. Cryst Growth Des 14:2516–2521. doi:10.1021/cg5002336 CrossRef D’Vries RF, Snejko N, Iglesias M, Gutiérrez-Puebla E, Monge M (2014) Ln-MOF pseudo-merohedral twinned crystalline family as solvent-free heterogeneous catalysts. Cryst Growth Des 14:2516–2521. doi:10.​1021/​cg5002336 CrossRef
Zurück zum Zitat Görller-Walrand C, Fluyt L, Ceulemans A, Carnall WT (1991) Magnetic dipole transitions as standards for Judd–Ofelt parameterization in lanthanide spectra. J Chem Phys 95:3099–3106CrossRef Görller-Walrand C, Fluyt L, Ceulemans A, Carnall WT (1991) Magnetic dipole transitions as standards for Judd–Ofelt parameterization in lanthanide spectra. J Chem Phys 95:3099–3106CrossRef
Zurück zum Zitat Hesterberg TW, Yang X, Holliday BJ (2010) Polymerizable cationic iridium(III) complexes exhibiting color tunable light emission and their corresponding conducting metallopolymers. Polyhedron 29:110–115. doi:10.1016/j.poly.2009.06.014 CrossRef Hesterberg TW, Yang X, Holliday BJ (2010) Polymerizable cationic iridium(III) complexes exhibiting color tunable light emission and their corresponding conducting metallopolymers. Polyhedron 29:110–115. doi:10.​1016/​j.​poly.​2009.​06.​014 CrossRef
Zurück zum Zitat Ibarra IA, Hesterberg TW, Holliday BJ, Lynch VM, Humphrey SM (2012) Gas sorption and luminescence properties of a terbium(iii)-phosphine oxide coordination material with two-dimensional pore topology. Dalton Trans 41:8003–8009. doi:10.1039/C2DT30138E CrossRef Ibarra IA, Hesterberg TW, Holliday BJ, Lynch VM, Humphrey SM (2012) Gas sorption and luminescence properties of a terbium(iii)-phosphine oxide coordination material with two-dimensional pore topology. Dalton Trans 41:8003–8009. doi:10.​1039/​C2DT30138E CrossRef
Zurück zum Zitat Jin G, Liu Z, Sun H, Tian Z (2016) Pyrolytic synthesis and luminescence of porous lanthanide Eu-MOF. Luminescence 31:190–194CrossRef Jin G, Liu Z, Sun H, Tian Z (2016) Pyrolytic synthesis and luminescence of porous lanthanide Eu-MOF. Luminescence 31:190–194CrossRef
Zurück zum Zitat Jørgensen CK, Judd BR (1964) Hypersensitive pseudoquadrupole transitions in lanthanides. Mol Phys 8:281–290CrossRef Jørgensen CK, Judd BR (1964) Hypersensitive pseudoquadrupole transitions in lanthanides. Mol Phys 8:281–290CrossRef
Zurück zum Zitat Judd DB, MacAdam DL, Wyszecki G, Budde HW, Condit HR, Henderson ST, Simonds JL (1964) Spectral distribution of typical daylight as a function of correlated color temperature. J Opt Soc Am 54:1031–1040CrossRef Judd DB, MacAdam DL, Wyszecki G, Budde HW, Condit HR, Henderson ST, Simonds JL (1964) Spectral distribution of typical daylight as a function of correlated color temperature. J Opt Soc Am 54:1031–1040CrossRef
Zurück zum Zitat Kwok HL (1997) Electronic materials. PWS Publishing Company, Boston Kwok HL (1997) Electronic materials. PWS Publishing Company, Boston
Zurück zum Zitat Lin J-D, Jia C-C, Li Z-H, Du S-W (2009) Syntheses, topological analyses and magnetic properties of two 3D supramolecular nickel-organic frameworks constructed from 1,3,5-benzenetricarboxylate and flexible imidazole-based ligands. Inorg Chem Commun 12:558–562. doi:10.1016/j.inoche.2009.04.020 CrossRef Lin J-D, Jia C-C, Li Z-H, Du S-W (2009) Syntheses, topological analyses and magnetic properties of two 3D supramolecular nickel-organic frameworks constructed from 1,3,5-benzenetricarboxylate and flexible imidazole-based ligands. Inorg Chem Commun 12:558–562. doi:10.​1016/​j.​inoche.​2009.​04.​020 CrossRef
Zurück zum Zitat Liu GX, Chen H, Zhu K et al (2008) A novel 3D europium (III) coordination polymer constructed from 3,5-pyridinedicarboxylate acid: synthesis, crystal structure and emission spectrum. J Inorg Organomet Polym 18:457. doi:10.1007/s10904-008-9222-z CrossRef Liu GX, Chen H, Zhu K et al (2008) A novel 3D europium (III) coordination polymer constructed from 3,5-pyridinedicarboxylate acid: synthesis, crystal structure and emission spectrum. J Inorg Organomet Polym 18:457. doi:10.​1007/​s10904-008-9222-z CrossRef
Zurück zum Zitat Liu K et al (2009a) Coordination-induced formation of one-dimensional nanostructures of europium benzene-1,3,5-tricarboxylate and its solid-state thermal transformation. Cryst Growth Des 9:3519–3524. doi:10.1021/cg900252r CrossRef Liu K et al (2009a) Coordination-induced formation of one-dimensional nanostructures of europium benzene-1,3,5-tricarboxylate and its solid-state thermal transformation. Cryst Growth Des 9:3519–3524. doi:10.​1021/​cg900252r CrossRef
Zurück zum Zitat Liu K et al (2009b) Facile shape-controlled synthesis of luminescent europium benzene-1,3,5-tricarboxylate architectures at room temperature. CrystEngComm 11:2622–2628. doi:10.1039/B905924P CrossRef Liu K et al (2009b) Facile shape-controlled synthesis of luminescent europium benzene-1,3,5-tricarboxylate architectures at room temperature. CrystEngComm 11:2622–2628. doi:10.​1039/​B905924P CrossRef
Zurück zum Zitat Loera-Serna S, Nunez LL, Flores J, Lopez-Simeon R, Beltran HI (2013) An alkaline one-pot metathesis reaction to give a [Cu3(BTC)2] MOF at r.t., with free Cu coordination sites and enhanced hydrogen uptake properties. RSC Adv 3:10962–10972. doi:10.1039/C3RA40726H CrossRef Loera-Serna S, Nunez LL, Flores J, Lopez-Simeon R, Beltran HI (2013) An alkaline one-pot metathesis reaction to give a [Cu3(BTC)2] MOF at r.t., with free Cu coordination sites and enhanced hydrogen uptake properties. RSC Adv 3:10962–10972. doi:10.​1039/​C3RA40726H CrossRef
Zurück zum Zitat Maiti S, Pramanik A, Mahanty S (2014) Extraordinarily high pseudocapacitance of metal organic framework derived nanostructured cerium oxide. Chem Commun 50:11717–11720. doi:10.1039/C4CC05363J CrossRef Maiti S, Pramanik A, Mahanty S (2014) Extraordinarily high pseudocapacitance of metal organic framework derived nanostructured cerium oxide. Chem Commun 50:11717–11720. doi:10.​1039/​C4CC05363J CrossRef
Zurück zum Zitat Matthes PR, Schönfeld F, Zottnick SH, Müller-Buschbaum K (2015) Post-synthetic shaping of porosity and crystal structure of Ln-Bipy-MOFs by thermal treatment. Molecules 20:12125–12153. doi:10.3390/molecules200712125 CrossRef Matthes PR, Schönfeld F, Zottnick SH, Müller-Buschbaum K (2015) Post-synthetic shaping of porosity and crystal structure of Ln-Bipy-MOFs by thermal treatment. Molecules 20:12125–12153. doi:10.​3390/​molecules2007121​25 CrossRef
Zurück zum Zitat Morales RamÍrez ÁdJ, Sarabia Dominguez F, Medina Velazquez DY, Jaramillo Vigueras D, GarcÍa Hernández M, Dorantes Rosales HJ (2014) Synthesis and photoluminescent properties of Y2O3:Eu3+ thin films prepared from F127-containing solution. J Ceram Soc Jpn 122:701–707. doi:10.2109/jcersj2.122.701 CrossRef Morales RamÍrez ÁdJ, Sarabia Dominguez F, Medina Velazquez DY, Jaramillo Vigueras D, GarcÍa Hernández M, Dorantes Rosales HJ (2014) Synthesis and photoluminescent properties of Y2O3:Eu3+ thin films prepared from F127-containing solution. J Ceram Soc Jpn 122:701–707. doi:10.​2109/​jcersj2.​122.​701 CrossRef
Zurück zum Zitat Qu Y, Ke Y, Lu S, Fan R, Pan G, Li J (2005) Hydrothermal synthesis, structures and spectroscopy of 2D lanthanide coordination polymers built from helical chains: [Ln2(BDC)3(H2O)2]n (Ln = Sm, 1; Ln = Eu, 2; BDC = 1,3-benzenedicarboxylate). J Mol Struct 734:7–13. doi:10.1016/j.molstruc.2004.03.035 CrossRef Qu Y, Ke Y, Lu S, Fan R, Pan G, Li J (2005) Hydrothermal synthesis, structures and spectroscopy of 2D lanthanide coordination polymers built from helical chains: [Ln2(BDC)3(H2O)2]n (Ln = Sm, 1; Ln = Eu, 2; BDC = 1,3-benzenedicarboxylate). J Mol Struct 734:7–13. doi:10.​1016/​j.​molstruc.​2004.​03.​035 CrossRef
Zurück zum Zitat Singh LR, Ningthoujam RS, Sudarsan V, Iti S, Singh SD, Dey GK, Kulshreshtha SK (2008) Luminescence study on Eu3+ doped Y2O3 nanoparticles: particle size, concentration and core–shell formation effects. Nanotechnology 19:055201CrossRef Singh LR, Ningthoujam RS, Sudarsan V, Iti S, Singh SD, Dey GK, Kulshreshtha SK (2008) Luminescence study on Eu3+ doped Y2O3 nanoparticles: particle size, concentration and core–shell formation effects. Nanotechnology 19:055201CrossRef
Zurück zum Zitat Song X-Z, Song S-Y, Zhang H-J (2015) Luminescent lanthanide metal-organic frameworks. In: Cheng P (ed) Lanthanide metal-organic frameworks, vol 163., Structure and BondingSpringer, Berlin, pp 109–144. doi:10.1007/430_2014_160 Song X-Z, Song S-Y, Zhang H-J (2015) Luminescent lanthanide metal-organic frameworks. In: Cheng P (ed) Lanthanide metal-organic frameworks, vol 163., Structure and BondingSpringer, Berlin, pp 109–144. doi:10.​1007/​430_​2014_​160
Zurück zum Zitat Weng YH, Cheng JK, Feng YL, Zhang J, Li ZJ, Yao YG (2005) Synthesis and crystal structure of [La(BTC)(H2O)6]n. Chin J Struct Chem 12:1440–1444 Weng YH, Cheng JK, Feng YL, Zhang J, Li ZJ, Yao YG (2005) Synthesis and crystal structure of [La(BTC)(H2O)6]n. Chin J Struct Chem 12:1440–1444
Zurück zum Zitat Xu B, Guo H, Wang S, Li Y, Zhang H, Liu C (2012) Solvothermal synthesis of luminescent Eu(BTC)(H2O)DMF hierarchical architecture. CrystEngComm 14:2914–2919CrossRef Xu B, Guo H, Wang S, Li Y, Zhang H, Liu C (2012) Solvothermal synthesis of luminescent Eu(BTC)(H2O)DMF hierarchical architecture. CrystEngComm 14:2914–2919CrossRef
Zurück zum Zitat Yang W, Feng J, Zhang H (2012) Facile and rapid fabrication of nanostructured lanthanide coordination polymers as selective luminescent probes in aqueous solution. J Mater Chem 22:6819–6823. doi:10.1039/C2JM16344F CrossRef Yang W, Feng J, Zhang H (2012) Facile and rapid fabrication of nanostructured lanthanide coordination polymers as selective luminescent probes in aqueous solution. J Mater Chem 22:6819–6823. doi:10.​1039/​C2JM16344F CrossRef
Zurück zum Zitat Yu M, Lin J, Wang Z, Fu J, Wang S, Zhang HJ, Han YC (2002) Fabrication, patterning, and optical properties of nanocrystalline YVO4: A (A = Eu3+, Dy3+, Sm3+, Er3+) Phosphor Films via sol–gel Soft lithography. Chem Mater 14:2224–2231. doi:10.1021/cm011663y CrossRef Yu M, Lin J, Wang Z, Fu J, Wang S, Zhang HJ, Han YC (2002) Fabrication, patterning, and optical properties of nanocrystalline YVO4: A (A = Eu3+, Dy3+, Sm3+, Er3+) Phosphor Films via sol–gel Soft lithography. Chem Mater 14:2224–2231. doi:10.​1021/​cm011663y CrossRef
Zurück zum Zitat Zhang QF, Hu FL, Wang SN, Sun DZ, Wang DQ, Dou JM (2012b) DMF/H2O volume-ratio-controlled assembly of 2D and 3D Ln-MOFs with 5-(pyridin-4-yl)isophthalic acid ligand. Aust J Chem 65:524–530. doi:10.1071/CH12072 CrossRef Zhang QF, Hu FL, Wang SN, Sun DZ, Wang DQ, Dou JM (2012b) DMF/H2O volume-ratio-controlled assembly of 2D and 3D Ln-MOFs with 5-(pyridin-4-yl)isophthalic acid ligand. Aust J Chem 65:524–530. doi:10.​1071/​CH12072 CrossRef
Zurück zum Zitat Zhang Y, Ju W, Xu X, Lv Y, Zhu D, Xu Y (2014b) Two novel mixed Eu3+/Y3+ Ln MOFs: influence of pH on the topology Eu/Y ratio and energy transfer. CrystEngComm 16:5681–5688. doi:10.1039/C4CE00513A CrossRef Zhang Y, Ju W, Xu X, Lv Y, Zhu D, Xu Y (2014b) Two novel mixed Eu3+/Y3+ Ln MOFs: influence of pH on the topology Eu/Y ratio and energy transfer. CrystEngComm 16:5681–5688. doi:10.​1039/​C4CE00513A CrossRef
Zurück zum Zitat Zych E (2002) Concentration dependence of energy transfer between Eu3+ ions occupying two symmetry sites in Lu2O3. J Phys Condens Matter 14:5637CrossRef Zych E (2002) Concentration dependence of energy transfer between Eu3+ ions occupying two symmetry sites in Lu2O3. J Phys Condens Matter 14:5637CrossRef
Metadaten
Titel
An alkaline one-pot reaction to synthesize luminescent Eu-BTC MOF nanorods, highly pure and water-insoluble, under room conditions
verfasst von
D. Y. Medina-Velazquez
B. Y. Alejandre-Zuniga
S. Loera-Serna
E. M. Ortiz
A. de J. Morales-Ramirez
E. Garfias-Garcia
A. Garcia-Murillo
C. Falcony
Publikationsdatum
01.12.2016
Verlag
Springer Netherlands
Erschienen in
Journal of Nanoparticle Research / Ausgabe 12/2016
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-016-3593-9

Weitere Artikel der Ausgabe 12/2016

Journal of Nanoparticle Research 12/2016 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.