Skip to main content

2014 | OriginalPaper | Buchkapitel

5. Analytical Methods for Investigation of Lithium-Ion Battery Ageing

verfasst von : Sascha Weber, Sascha Nowak, Falko Schappacher

Erschienen in: Automotive Battery Technology

Verlag: Springer International Publishing

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

One of the major issues battery research must address is the lifetime of a cell. This can be reduced by physical and chemical ageing processes that occur inside the cell and are influenced by both the operating strategy and the surrounding conditions (e.g. temperature). To understand battery ageing, it is necessary to analyze the materials used in a cell at the microscopic level and correlate the results with electrical measurement data. This chapter describes a strategy for performing an ageing experiment by using a combination of analytical methods.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
4.
Zurück zum Zitat Callahan RW, Nguyen KV, McLean JG, Propost J, Hoffman DK (1993) In: Proceedings of the 10th international seminar on primary and secondary battery technology and application, Fort Lauderdale, Florida Callahan RW, Nguyen KV, McLean JG, Propost J, Hoffman DK (1993) In: Proceedings of the 10th international seminar on primary and secondary battery technology and application, Fort Lauderdale, Florida
5.
Zurück zum Zitat Goldstein J, Newbury DE, Joy DC, Lyman CE, Echlin P, Lifshin E, Sawyer L, Michael JR (2003) Scanning electron microscopy and X-ray microanalysis, 3rd edn. Springer, New YorkCrossRef Goldstein J, Newbury DE, Joy DC, Lyman CE, Echlin P, Lifshin E, Sawyer L, Michael JR (2003) Scanning electron microscopy and X-ray microanalysis, 3rd edn. Springer, New YorkCrossRef
7.
Zurück zum Zitat Kohs W, Santner HJ, Hofer F, Schröttner H, Doninger J, Barsukov I, Buqa H, Albering JH, Möller KC, Besenhard JO, Winter M (2003) A study on electrolyte interactions with graphite anodes exhibiting structures with various amounts of rhombohedral phase. J Power Sources 119–121:528–537. doi:10.1016/S0378-7753(03)00278-7 CrossRef Kohs W, Santner HJ, Hofer F, Schröttner H, Doninger J, Barsukov I, Buqa H, Albering JH, Möller KC, Besenhard JO, Winter M (2003) A study on electrolyte interactions with graphite anodes exhibiting structures with various amounts of rhombohedral phase. J Power Sources 119–121:528–537. doi:10.​1016/​S0378-7753(03)00278-7 CrossRef
8.
Zurück zum Zitat Kostecki R, Norin L, Song X, McLarnon F (2004) Diagnostic studies of polyolefin separators in high-power Li-ion cells. J Electrochem Soc 151(4):A522–A526. doi:10.1149/1.1649233 CrossRef Kostecki R, Norin L, Song X, McLarnon F (2004) Diagnostic studies of polyolefin separators in high-power Li-ion cells. J Electrochem Soc 151(4):A522–A526. doi:10.​1149/​1.​1649233 CrossRef
10.
Zurück zum Zitat Lux SF, Terborg L, Hachmoller O, Placke T, Meyer HW, Passerini S, Winter M, Nowak S (2013) LiTFSI stability in water and its possible use in aqueous lithium-ion batteries: pH dependency, electrochemical window and temperature stability. J Electrochem Soc 160(10):A1694–A1700. doi:10.1149/2.039310jes CrossRef Lux SF, Terborg L, Hachmoller O, Placke T, Meyer HW, Passerini S, Winter M, Nowak S (2013) LiTFSI stability in water and its possible use in aqueous lithium-ion batteries: pH dependency, electrochemical window and temperature stability. J Electrochem Soc 160(10):A1694–A1700. doi:10.​1149/​2.​039310jes CrossRef
12.
Zurück zum Zitat Markevich E, Salitra G, Levi MD, Aurbach D (2005) Capacity fading of lithiated graphite electrodes studied by a combination of electroanalytical methods, Raman spectroscopy and SEM. J Power Sources 146(1–2):146–150. doi:10.1016/j.jpowsour.2005.03.107 CrossRef Markevich E, Salitra G, Levi MD, Aurbach D (2005) Capacity fading of lithiated graphite electrodes studied by a combination of electroanalytical methods, Raman spectroscopy and SEM. J Power Sources 146(1–2):146–150. doi:10.​1016/​j.​jpowsour.​2005.​03.​107 CrossRef
13.
Zurück zum Zitat Niehoff P, Passerini S, Winter M (2013) Interface investigations of a commercial lithium ion battery graphite anode material by sputter depth profile X-ray photoelectron spectroscopy. Langmuir 29(19):5806–5816. doi:10.1021/la400764r CrossRef Niehoff P, Passerini S, Winter M (2013) Interface investigations of a commercial lithium ion battery graphite anode material by sputter depth profile X-ray photoelectron spectroscopy. Langmuir 29(19):5806–5816. doi:10.​1021/​la400764r CrossRef
14.
16.
Zurück zum Zitat Peled E (1979) The electrochemical behavior of alkali and alkaline earth metals in nonaqueous battery systems-the solid electrolyte interphase model. J Electrochem Soc 126(12):2047–2051. doi:10.1149/1.2128859 CrossRef Peled E (1979) The electrochemical behavior of alkali and alkaline earth metals in nonaqueous battery systems-the solid electrolyte interphase model. J Electrochem Soc 126(12):2047–2051. doi:10.​1149/​1.​2128859 CrossRef
17.
Zurück zum Zitat Prochazka W, Pregartner G, Cifrain M (2013) Design-of-experiment and statistical modeling of a large scale aging experiment for two popular lithium ion cell chemistries. J Electrochem Soc 160(8):A1039–A1051. doi:10.1149/2.003308jes CrossRef Prochazka W, Pregartner G, Cifrain M (2013) Design-of-experiment and statistical modeling of a large scale aging experiment for two popular lithium ion cell chemistries. J Electrochem Soc 160(8):A1039–A1051. doi:10.​1149/​2.​003308jes CrossRef
18.
Zurück zum Zitat Santner HJ, Möller KC, Ivančo J, Ramsey MG, Netzer FP, Yamaguchi S, Besenhard JO, Winter M (2003) Acrylic acid nitrile, a film-forming electrolyte component for lithium-ion batteries, which belongs to the family of additives containing vinyl groups. J Power Sources 119–121:368–372. doi:10.1016/S0378-7753(03)00268-4 CrossRef Santner HJ, Möller KC, Ivančo J, Ramsey MG, Netzer FP, Yamaguchi S, Besenhard JO, Winter M (2003) Acrylic acid nitrile, a film-forming electrolyte component for lithium-ion batteries, which belongs to the family of additives containing vinyl groups. J Power Sources 119–121:368–372. doi:10.​1016/​S0378-7753(03)00268-4 CrossRef
19.
Zurück zum Zitat Santner HJ, Korepp C, Winter M, Besenhard JO, Möller KC (2004) In-situ FTIR investigations on the reduction of vinylene electrolyte additives suitable for use in lithium-ion batteries. Anal Bioanal Chem 379(2):266–271. doi:10.1007/s00216-004-2522-4 CrossRef Santner HJ, Korepp C, Winter M, Besenhard JO, Möller KC (2004) In-situ FTIR investigations on the reduction of vinylene electrolyte additives suitable for use in lithium-ion batteries. Anal Bioanal Chem 379(2):266–271. doi:10.​1007/​s00216-004-2522-4 CrossRef
20.
Zurück zum Zitat Song KM, Park SW, Hong WH, Lee H, Kwak SS, Liu JR (1992) Isolation of Vindoline from Catharanthus roseus by supercritical fluid extraction. Biotechnol Prog 8(6):583–586. doi:10.1021/bp00018a018 CrossRef Song KM, Park SW, Hong WH, Lee H, Kwak SS, Liu JR (1992) Isolation of Vindoline from Catharanthus roseus by supercritical fluid extraction. Biotechnol Prog 8(6):583–586. doi:10.​1021/​bp00018a018 CrossRef
21.
Zurück zum Zitat Spotnitz R (2011) Separators for lithium-ion batteries. In: Daniel C, Besenhard J (eds) Handbook of battery materials, 2nd edn. Wiley-VCH, Weinheim, chap 20, doi:10.1002/9783527637188.ch20 Spotnitz R (2011) Separators for lithium-ion batteries. In: Daniel C, Besenhard J (eds) Handbook of battery materials, 2nd edn. Wiley-VCH, Weinheim, chap 20, doi:10.​1002/​9783527637188.​ch20
22.
Zurück zum Zitat Stashenko EE, Puertas MA, Combariza MY (1996) Volatile secondary metabolites from Spilanthes americana obtained by simultaneous steam distillation-solvent extraction and supercritical fluid extraction. J Chromatogr A 752(1–2):223–232. doi:10.1016/S0021-9673(96)00480-3 CrossRef Stashenko EE, Puertas MA, Combariza MY (1996) Volatile secondary metabolites from Spilanthes americana obtained by simultaneous steam distillation-solvent extraction and supercritical fluid extraction. J Chromatogr A 752(1–2):223–232. doi:10.​1016/​S0021-9673(96)00480-3 CrossRef
23.
Zurück zum Zitat Terborg L, Nowak S, Passerini S, Winter M, Karst U, Haddad PR, Nesterenko PN (2012) Ion chromatographic determination of hydrolysis products of hexafluorophosphate salts in aqueous solution. Anal Chim Acta 714:121–126. doi:10.1016/j.aca.2011.11.056 CrossRef Terborg L, Nowak S, Passerini S, Winter M, Karst U, Haddad PR, Nesterenko PN (2012) Ion chromatographic determination of hydrolysis products of hexafluorophosphate salts in aqueous solution. Anal Chim Acta 714:121–126. doi:10.​1016/​j.​aca.​2011.​11.​056 CrossRef
24.
27.
Zurück zum Zitat Wagner MR, Raimann PR, Trifonova A, Moeller KC, Besenhard JO, Winter M (2004) Electrolyte decomposition reactions on tin- and graphite-based anodes are different. Electrochem Solid-State Lett 7(7):A201–A206. doi:10.1149/1.1739312 CrossRef Wagner MR, Raimann PR, Trifonova A, Moeller KC, Besenhard JO, Winter M (2004) Electrolyte decomposition reactions on tin- and graphite-based anodes are different. Electrochem Solid-State Lett 7(7):A201–A206. doi:10.​1149/​1.​1739312 CrossRef
28.
Zurück zum Zitat Winter M (2009) The solid electrolyte interphase - the most important and the least understood solid electrolyte in rechargeable Li batteries. Z Phys Chem 223(10–11):1395–1406. doi:10.1524/zpch 2009.6086CrossRef Winter M (2009) The solid electrolyte interphase - the most important and the least understood solid electrolyte in rechargeable Li batteries. Z Phys Chem 223(10–11):1395–1406. doi:10.​1524/​zpch 2009.6086CrossRef
32.
Zurück zum Zitat Winter M, Imhof R, Joho F, Novák P (1999) FTIR and DEMS investigations on the electroreduction of chloroethylene carbonate-based electrolyte solutions for lithium-ion cells. J Power Sources 81–82:818–823. doi:10.1016/S0378-7753(99)00116-0 CrossRef Winter M, Imhof R, Joho F, Novák P (1999) FTIR and DEMS investigations on the electroreduction of chloroethylene carbonate-based electrolyte solutions for lithium-ion cells. J Power Sources 81–82:818–823. doi:10.​1016/​S0378-7753(99)00116-0 CrossRef
33.
Zurück zum Zitat Winter M, Appel WK, Evers B, Hodal T, Möller KC, Schneider I, Wachtler M, Wagner MR, Wrodnigg GH, Besenhard JO (2001) Studies on the anode/electrolyte interface in lithium ion batteries. Monatsh Chem 132(4):473–486. doi:10.1007/s007060170110 CrossRef Winter M, Appel WK, Evers B, Hodal T, Möller KC, Schneider I, Wachtler M, Wagner MR, Wrodnigg GH, Besenhard JO (2001) Studies on the anode/electrolyte interface in lithium ion batteries. Monatsh Chem 132(4):473–486. doi:10.​1007/​s007060170110 CrossRef
34.
Zurück zum Zitat Yu DY, Donoue K, Kadohata T, Murata T, Matsuta S, Fujitani S (2008) Impurities in liFePO\(_{4}\) and their influence on material characteristics. J Electrochem Soc 155(7):A526–A530. doi:10.1149/1.2919105 CrossRef Yu DY, Donoue K, Kadohata T, Murata T, Matsuta S, Fujitani S (2008) Impurities in liFePO\(_{4}\) and their influence on material characteristics. J Electrochem Soc 155(7):A526–A530. doi:10.​1149/​1.​2919105 CrossRef
Metadaten
Titel
Analytical Methods for Investigation of Lithium-Ion Battery Ageing
verfasst von
Sascha Weber
Sascha Nowak
Falko Schappacher
Copyright-Jahr
2014
DOI
https://doi.org/10.1007/978-3-319-02523-0_5

    Premium Partner