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Erschienen in: Journal of Materials Engineering and Performance 10/2019

30.09.2019

Aqueous Corrosion Behavior of Cast CoCrFeMnNi Alloy

verfasst von: S. Pathak, N. Kumar, R. S. Mishra, P. S. De

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 10/2019

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Abstract

CoCrFeMnNi high-entropy alloy demonstrates good mechanical properties and can be further strengthened by thermomechanical processes. A sample alloy prepared by vacuum casting in a graphite mold was further investigated for its corrosion resistance. One-millimeter thin strips of cast alloy were used to investigate its corrosion behavior at room temperature. Linear potentiodynamic tests of the alloy in sodium chloride solution confirmed uniform corrosion property comparable to stainless steel AISI 304. However, a positive cyclic hysteresis loop indicated susceptibility to pitting corrosion. In sodium hydroxide solution, metastable pit formation was observed, while sulfuric acid solution passivated the alloy. In both cases, the alloy did not show any spontaneous pitting tendency.

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Literatur
1.
Zurück zum Zitat J.-W. Yeh, S.K. Chen, S.J. Lin, and J.Y. Gan, Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes, Adv. Eng. Mater., 2004, 6(5), p 299–303CrossRef J.-W. Yeh, S.K. Chen, S.J. Lin, and J.Y. Gan, Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes, Adv. Eng. Mater., 2004, 6(5), p 299–303CrossRef
2.
Zurück zum Zitat Y. Zhang, T.T. Zuo, Z. Tang, M.C. Gao, K.A. Dahmen, P.K. Liaw, and Z.P. Lu, Microstructures and Properties of High-Entropy Alloys, Prog. Mater Sci., 2014, 61, p 1–93CrossRef Y. Zhang, T.T. Zuo, Z. Tang, M.C. Gao, K.A. Dahmen, P.K. Liaw, and Z.P. Lu, Microstructures and Properties of High-Entropy Alloys, Prog. Mater Sci., 2014, 61, p 1–93CrossRef
3.
Zurück zum Zitat Y. Qiu, M.A. Gibson, H.L. Fraser, and N. Birbilis, Corrosion Characteristics of High Entropy Alloys, Mater. Sci. Technol., 2015, 31(10), p 1235–1243CrossRef Y. Qiu, M.A. Gibson, H.L. Fraser, and N. Birbilis, Corrosion Characteristics of High Entropy Alloys, Mater. Sci. Technol., 2015, 31(10), p 1235–1243CrossRef
4.
Zurück zum Zitat B. Cantor, I.T.H. Chang, P. Knight, and A.J.B. Vincent, Microstructural Development in Equiatomic Multicomponent Alloys, Mater. Sci. Eng. A, 2004, 375–377, p 213–218CrossRef B. Cantor, I.T.H. Chang, P. Knight, and A.J.B. Vincent, Microstructural Development in Equiatomic Multicomponent Alloys, Mater. Sci. Eng. A, 2004, 375–377, p 213–218CrossRef
5.
Zurück zum Zitat K.V.S. Thurston, B. Gludovatz, A. Hohenwarter, G. Laplanche, E.P. George, and R.O. Ritchie, Effect of Temperature on the Fatigue-Crack Growth Behavior of the High-Entropy Alloy CrMnFeCoNi, Intermetallics, 2017, 88, p 65–72CrossRef K.V.S. Thurston, B. Gludovatz, A. Hohenwarter, G. Laplanche, E.P. George, and R.O. Ritchie, Effect of Temperature on the Fatigue-Crack Growth Behavior of the High-Entropy Alloy CrMnFeCoNi, Intermetallics, 2017, 88, p 65–72CrossRef
6.
Zurück zum Zitat M.J. Yao, K.G. Pradeep, C.C. Tasan, and D. Raabe, A Novel, Single Phase, Non-equiatomic FeMnNiCoCr High-Entropy Alloy with Exceptional Phase Stability and Tensile Ductility, Scr. Mater., 2014, 72, p 5–8CrossRef M.J. Yao, K.G. Pradeep, C.C. Tasan, and D. Raabe, A Novel, Single Phase, Non-equiatomic FeMnNiCoCr High-Entropy Alloy with Exceptional Phase Stability and Tensile Ductility, Scr. Mater., 2014, 72, p 5–8CrossRef
7.
Zurück zum Zitat E.J. Pickering, R. Muñoz-Moreno, H.J. Stone, and N.G. Jones, Precipitation in the Equiatomic High-Entropy Alloy CrMnFeCoNi, Scr. Mater., 2016, 113, p 106–109CrossRef E.J. Pickering, R. Muñoz-Moreno, H.J. Stone, and N.G. Jones, Precipitation in the Equiatomic High-Entropy Alloy CrMnFeCoNi, Scr. Mater., 2016, 113, p 106–109CrossRef
8.
Zurück zum Zitat B. Schuh, F. Mendez-Martin, B. Völker, E.P. George, H. Clemens, R. Pippan, and A. Hohenwarter, Mechanical Properties, Microstructure and Thermal Stability of a Nanocrystalline CoCrFeMnNi High-Entropy Alloy After Severe Plastic Deformation, Acta Mater., 2015, 96, p 258–268CrossRef B. Schuh, F. Mendez-Martin, B. Völker, E.P. George, H. Clemens, R. Pippan, and A. Hohenwarter, Mechanical Properties, Microstructure and Thermal Stability of a Nanocrystalline CoCrFeMnNi High-Entropy Alloy After Severe Plastic Deformation, Acta Mater., 2015, 96, p 258–268CrossRef
9.
Zurück zum Zitat Y.-K. Kim, Y.-A. Joo, H.S. Kim, and K.-A. Lee, High Temperature Oxidation Behavior of Cr-Mn-Fe-Co-Ni High Entropy Alloy, Intermetallics, 2018, 98, p 45–53CrossRef Y.-K. Kim, Y.-A. Joo, H.S. Kim, and K.-A. Lee, High Temperature Oxidation Behavior of Cr-Mn-Fe-Co-Ni High Entropy Alloy, Intermetallics, 2018, 98, p 45–53CrossRef
10.
Zurück zum Zitat C.-H. Tsau, S.-X. Lin, and C.-H. Fang, Microstructures and Corrosion Behaviors of FeCoNi and CrFeCoNi Equimolar Alloys, Mater. Chem. Phys., 2017, 186, p 534–540CrossRef C.-H. Tsau, S.-X. Lin, and C.-H. Fang, Microstructures and Corrosion Behaviors of FeCoNi and CrFeCoNi Equimolar Alloys, Mater. Chem. Phys., 2017, 186, p 534–540CrossRef
11.
Zurück zum Zitat H. Lu, Z. Li, A.M. Mingers, and D. Raabe, Corrosion Behavior of an Equiatomic CoCrFeMnNi High-Entropy Alloy Compared with 304 Stainless Steel in Sulfuric Acid Solution, Corros. Sci., 2018, 134, p 131–139CrossRef H. Lu, Z. Li, A.M. Mingers, and D. Raabe, Corrosion Behavior of an Equiatomic CoCrFeMnNi High-Entropy Alloy Compared with 304 Stainless Steel in Sulfuric Acid Solution, Corros. Sci., 2018, 134, p 131–139CrossRef
12.
Zurück zum Zitat Standard Guide for Determination of Various Elements by Direct Current Plasma Atomic Emission Spectrometry, ASTM E1097-12 (2017) Standard Guide for Determination of Various Elements by Direct Current Plasma Atomic Emission Spectrometry, ASTM E1097-12 (2017)
13.
Zurück zum Zitat Standard Test Method for Determination of Carbon in Refractory and Reactive Metals and Their Alloys by Combustion Analysis, ASTM E1941-10 (2016) Standard Test Method for Determination of Carbon in Refractory and Reactive Metals and Their Alloys by Combustion Analysis, ASTM E1941-10 (2016)
14.
Zurück zum Zitat S. Zhang, C.L. Wu, C.H. Zhang, M. Guan, and J.Z. Tan, Laser Surface Alloying of FeCoCrAlNi High-Entropy Alloy on 304 Stainless Steel to Enhance Corrosion and Cavitation Erosion Resistance, Opt. Laser Technol., 2016, 84, p 23–31CrossRef S. Zhang, C.L. Wu, C.H. Zhang, M. Guan, and J.Z. Tan, Laser Surface Alloying of FeCoCrAlNi High-Entropy Alloy on 304 Stainless Steel to Enhance Corrosion and Cavitation Erosion Resistance, Opt. Laser Technol., 2016, 84, p 23–31CrossRef
15.
Zurück zum Zitat M. Vaidya, A. Karati, A. Marshal, K.G. Pradeep, and B.S. Murty, Phase Evolution and Stability of Nanocrystalline CoCrFeNi and CoCrFeMnNi High Entropy Alloys, J. Alloys Compd., 2019, 770, p 1004–1015CrossRef M. Vaidya, A. Karati, A. Marshal, K.G. Pradeep, and B.S. Murty, Phase Evolution and Stability of Nanocrystalline CoCrFeNi and CoCrFeMnNi High Entropy Alloys, J. Alloys Compd., 2019, 770, p 1004–1015CrossRef
16.
Zurück zum Zitat W.S. Tait, An Introduction to Electrochemical Corrosion Testing for Practicing Engineers and Scientists, Racine, Wisconsin, 1994 W.S. Tait, An Introduction to Electrochemical Corrosion Testing for Practicing Engineers and Scientists, Racine, Wisconsin, 1994
17.
Zurück zum Zitat J.R. Galvele, in Passivity of Metals, ed. by R.P. Frankenthal, J. Kruger (The Electrochemical Society, Princeton, 1978), p. 285 J.R. Galvele, in Passivity of Metals, ed. by R.P. Frankenthal, J. Kruger (The Electrochemical Society, Princeton, 1978), p. 285
18.
Zurück zum Zitat H.S. Isaacs, U. Bertocci, J. Kruger, and S. Smialowska, (eds.) in Advances in Localized Corrosion: Proceedings of the Second International Conference on Localized Corrosion. (Houston, Texas: National Association of Corrosion Engineers, 1990), p. 41 H.S. Isaacs, U. Bertocci, J. Kruger, and S. Smialowska, (eds.) in Advances in Localized Corrosion: Proceedings of the Second International Conference on Localized Corrosion. (Houston, Texas: National Association of Corrosion Engineers, 1990), p. 41
19.
Zurück zum Zitat G.S. Frankel, Pitting Corrosion of Metals a Review of the Critical Factors, J. Electrochem. Soc., 1998, 145(6), p 2186–2198CrossRef G.S. Frankel, Pitting Corrosion of Metals a Review of the Critical Factors, J. Electrochem. Soc., 1998, 145(6), p 2186–2198CrossRef
20.
Zurück zum Zitat P.M. Natishan, W.E. O’Grady, E. McCafferty, D.E. Ramaker, K. Pandya, and A. Russell, Chloride Uptake by Oxide Covered Aluminum as Determined by X-Ray Photoelectron and X-Ray Absorption Spectroscopy, J. Electrochem. Soc., 1999, 146(5), p 1737–1740CrossRef P.M. Natishan, W.E. O’Grady, E. McCafferty, D.E. Ramaker, K. Pandya, and A. Russell, Chloride Uptake by Oxide Covered Aluminum as Determined by X-Ray Photoelectron and X-Ray Absorption Spectroscopy, J. Electrochem. Soc., 1999, 146(5), p 1737–1740CrossRef
21.
Zurück zum Zitat L.A. Krebs and J. Kruger, in Passivity of Metals and Semiconductors, ed. by M.B. Ives, J.L. Luo, J.R. Rodda (The Electrochemical Society, Pennington, 2001), p. 561 L.A. Krebs and J. Kruger, in Passivity of Metals and Semiconductors, ed. by M.B. Ives, J.L. Luo, J.R. Rodda (The Electrochemical Society, Pennington, 2001), p. 561
22.
Zurück zum Zitat D.D. Macdonald, The Point Defect Model for the Passive State, J. Electrochem. Soc., 1992, 139(12), p 3434–3449CrossRef D.D. Macdonald, The Point Defect Model for the Passive State, J. Electrochem. Soc., 1992, 139(12), p 3434–3449CrossRef
23.
Zurück zum Zitat E. McCafferty, Introduction to Corrosion Science, Springer, Berlin, 2009 E. McCafferty, Introduction to Corrosion Science, Springer, Berlin, 2009
24.
Zurück zum Zitat E. McCafferty, A Competitive Adsorption Model for the Inhibition of Crevice Corrosion and Pitting, J. Electrochem. Soc., 1990, 137(12), p 3731–3737CrossRef E. McCafferty, A Competitive Adsorption Model for the Inhibition of Crevice Corrosion and Pitting, J. Electrochem. Soc., 1990, 137(12), p 3731–3737CrossRef
25.
Zurück zum Zitat G. Butler, P. Stretton, and J.G. Beynon, Initiation and Growth of Pits on High-Purity Iron and Its Alloys with Chromium and Copper in Neutral Chloride Solutions, Br. Corros. J., 1972, 7(4), p 168–173CrossRef G. Butler, P. Stretton, and J.G. Beynon, Initiation and Growth of Pits on High-Purity Iron and Its Alloys with Chromium and Copper in Neutral Chloride Solutions, Br. Corros. J., 1972, 7(4), p 168–173CrossRef
26.
Zurück zum Zitat H.-H. Strehblow, Nucleation and Repassivation of Corrosion Pits for Pitting on Iron and Nickel, Mater. Corros., 1976, 27(11), p 792–799CrossRef H.-H. Strehblow, Nucleation and Repassivation of Corrosion Pits for Pitting on Iron and Nickel, Mater. Corros., 1976, 27(11), p 792–799CrossRef
27.
Zurück zum Zitat T.J. Glover, Recent Developments in Corrosion-Resistant Metallic Alloys for Construction of Sea-Water Pumps, Mater. Perform., 1988, 27, p 51–56 T.J. Glover, Recent Developments in Corrosion-Resistant Metallic Alloys for Construction of Sea-Water Pumps, Mater. Perform., 1988, 27, p 51–56
28.
Zurück zum Zitat Y.L. Chou, J.W. Yeh, and H.C. Shih, The Effect of Molybdenum on the Corrosion Behavior of the High-Entropy Alloys Co1.CrFeNi1.5Ti0.5Mox in Aqueous Environments, Corros. Sci., 2010, 52, p 2571–2581CrossRef Y.L. Chou, J.W. Yeh, and H.C. Shih, The Effect of Molybdenum on the Corrosion Behavior of the High-Entropy Alloys Co1.CrFeNi1.5Ti0.5Mox in Aqueous Environments, Corros. Sci., 2010, 52, p 2571–2581CrossRef
29.
Zurück zum Zitat A.-D. Kamal, K.N. Raymond, and D.P. Freyberg, The Bihydroxide (H3O2-) Anion. A Very Short, Symmetric Hydrogen Bond, J. Am. Chem. Soc., 1979, 101(13), p 3688–3689CrossRef A.-D. Kamal, K.N. Raymond, and D.P. Freyberg, The Bihydroxide (H3O2-) Anion. A Very Short, Symmetric Hydrogen Bond, J. Am. Chem. Soc., 1979, 101(13), p 3688–3689CrossRef
30.
Zurück zum Zitat B.N. Popov, Corrosion Engineering: Principles and Solved Problems, Elsevier, Amsterdam, 2015 B.N. Popov, Corrosion Engineering: Principles and Solved Problems, Elsevier, Amsterdam, 2015
31.
Zurück zum Zitat C.P. Lee, Y.Y. Chen, C.Y. Hsu, J.W. Yeh, and H.C. Shih, Enhancing Pitting Corrosion Resistance of AlxCrFe1.5MnNi0.5 High-Entropy Alloys by Anodic Treatment in Sulfuric Acid, Thin Solid Films, 2008, 517, p 1301–1305CrossRef C.P. Lee, Y.Y. Chen, C.Y. Hsu, J.W. Yeh, and H.C. Shih, Enhancing Pitting Corrosion Resistance of AlxCrFe1.5MnNi0.5 High-Entropy Alloys by Anodic Treatment in Sulfuric Acid, Thin Solid Films, 2008, 517, p 1301–1305CrossRef
Metadaten
Titel
Aqueous Corrosion Behavior of Cast CoCrFeMnNi Alloy
verfasst von
S. Pathak
N. Kumar
R. S. Mishra
P. S. De
Publikationsdatum
30.09.2019
Verlag
Springer US
Erschienen in
Journal of Materials Engineering and Performance / Ausgabe 10/2019
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-019-04329-z

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