Effect of Fluorocarbon Polymer Buildup on Etching in  O 2/Ar and  CF 4 /  CHF 3 / Ar Plasma

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© 1997 ECS - The Electrochemical Society
, , Citation Dong‐Duk Lee et al 1997 J. Electrochem. Soc. 144 1774 DOI 10.1149/1.1837677

1945-7111/144/5/1774

Abstract

The effect of fluorocarbon polymer buildup on oxide etching was investigated by monitoring the reactor chamber under an /Ar plasma. Its effect on contact etching was also investigated by employing a plasma. It was determined that the /Ar plasma was very useful for confirming polymer buildup on the inner chamber surface. This is because of an increased oxide etch rate by fluorine radicals, formed by the dissociation of the fluorocarbon polymer. Meanwhile, contact etching in a plasma with a high ratio caused a reduction in etch rate near the edge of the wafer (in some cases even an etch stop), a considerable loss of critical dimension, and higher etch selectivity to polysilicon. These various etch behaviors are attributed to the polymer buildup on the inner surface of the chamber.

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10.1149/1.1837677