Galvanic Cell Studies on Ionic Carbide and Nitride Solutions in Molten Salts

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© 1977 ECS - The Electrochemical Society
, , Citation A. Bonomi et al 1977 J. Electrochem. Soc. 124 982 DOI 10.1149/1.2133513

1945-7111/124/7/982

Abstract

The free energy (Gibbs) of formation of , , and and their activities in molten salt solutions at temperatures between 823° and 973°K have been determined by using the following galvanic cells

and

The nitrogen electrode used in cell (II) has been proved to have a Nernstian behavior by studying the dependence of emf on the partial pressure of nitrogen. The activity coefficients of and in molten salts have been found to decrease with increasing concentration.

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10.1149/1.2133513