Anodic Films, Protons, and Electrolytic Rectification

© 1968 ECS - The Electrochemical Society
, , Citation D. A. Vermilyea 1968 J. Electrochem. Soc. 115 177 DOI 10.1149/1.2411070

1945-7111/115/2/177

Abstract

Anodic films contain many flaws which for thick films are the sites of electrolytic rectification. For and films below 1000Aå in thickness, however, bulk conduction also occurs. For such films the capacitance also increases markedly on polarization in the forward direction (base metal negative). One interpretation of the capacitance changes involves a proton space charge in the film. The relationship between capacitance change and current flow is examined in some detail, and it is shown that there is not a good correlation between the two effects; it therefore appears that two separate phenomena are involved. Possible interpretations are discussed.

Export citation and abstract BibTeX RIS

10.1149/1.2411070