Hydrogen Evolution from Dissolving Titanium‐Oxygen Alloys in Hydrofluoric Acid and the Constitution of Ti‐O Alloys

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© 1956 ECS - The Electrochemical Society
, , Citation M. E. Straumanis et al 1956 J. Electrochem. Soc. 103 439 DOI 10.1149/1.2430375

1945-7111/103/8/439

Abstract

Titanium‐oxygen alloys dissolve in according to the reaction , with a maximum for , which means that dissolves without hydrogen evolution. Higher titanium oxides do not dissolve in . The determination of the end point of the above reaction was affected by a secondary, but very slow reaction . Nevertheless, the experimental results agreed within ±2% for the first reaction for titanium containing oxygen up to 33 at.%. Titanium‐oxygen alloys do not represent titanium oxygen solid solutions but solid solutions of titanium oxides and titanium metal.

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10.1149/1.2430375