(Invited) Light-Emitting Devices Based on Defect-Enhanced Group-IV Nanostructures

© 2022 ECS - The Electrochemical Society
, , Citation Moritz Brehm 2022 Meet. Abstr. MA2022-01 1080 DOI 10.1149/MA2022-01201080mtgabs

2151-2043/MA2022-01/20/1080

Abstract

Combining Si-based integrated optics with Si-based microelectronics is crucial for next-generation applications ranging from data transfer on short distances to sensing and, potentially, to quantum cryptography at telecom wavelengths. However, Si's intrinsically poor light-emitting properties, i.e., its indirect energy bandgap, inhibit a straightforward implementation of telecom devices such as light-emitting diodes and lasers operating at room temperature.

We argue that adding Ge heterostructures, nanostructures, intentionally-induced defects, and defects within nanostructures to the Si platform can be a viable way to overcome the limitations of Si as a light-emitting material [1]. Significant progress for light-emission from group-IV nanostructures can be achieved by intentionally incorporating extended point defects inside the QDs upon in-situ low-energy ion implantation [2],[3]. This work discusses the superior light-emission properties from such defect-enhanced quantum dots (DEQDs) and our present understanding of their structural formation and light-emission mechanisms [4], indicating that optically direct recombination paths play a role in room-temperature light emission.

As compared to other group-IV systems with pronounced optical emission, contact doping and hence fabrication of electrically driven devices is relatively straightforward in this nanosystem since DEQDs are embedded into a defect-free Si matrix [5],[6]. We show that useful electrically driven devices, such as light-emitting diodes (LEDs), can be fabricated employing optically active DEQD material. These LEDs exhibit exceptional temperature stability of their light-emission properties even up to 100°C, unprecedented for purely group-IV-based optoelectronic devices [7]. We discuss the role of vital parameters, such as the temperature stability of the structural properties [8],[9], the scalability of the light-emission with the nanostructure density [6], and passivation schemes to further improve the optical properties [8],[10]. Additionally, we elaborate on schemes for advanced layouts for electrically-pumped devices.

References

[1 ] M. Brehm, Silicon Photonics IV, 67-103, Silicon Photonics IV: Innovative Frontiers, edited by David J. Lockwood and Lorenzo Pavesi, Springer series Topics in Applied Physics (2021).

[2] M. Grydlik et al., ACS Photonics 3, 298–303 (2016).

[3] M. Grydlik et al., Nano Lett. 16, 6802–6807 (2016).

[4] F. Murphy-Armando et al., Phys. Rev. B 103, 085310 (2021).

[5] M. Brehm and M. Grydlik, Nanotechnology 28, 392001 (2017).

[6] H. Groiss et al., Semicond. Sci. Technol. 32, 02LT01 (2017).

[7] P. Rauter et al., ACS Photonics 5, 431-438 (2018).

[8] L. Spindlberger et al., Crystals 10, 351 (2020).

[9] L. Spindlberger et al., Physica Status Solidi (a) 216, 1900307 (2019).

[10] L. Spindlberger et al., Appl. Phys. Lett. 118, 083104 (2021).

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10.1149/MA2022-01201080mtgabs