nach oben

Journal of Materials Science

Erschienen in:

07.01.2019 | Electronic materials

Asymmetric supercapacitor device performance based on microwave synthesis of N-doped graphene/nickel sulfide nanocomposite

verfasst von: B. Joji Reddy, P. Vickraman, A. Simon Justin

Erschienen in: Journal of Materials Science | Ausgabe 8/2019

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Nickel sulfide (NiS) and Nitrogen-doped Graphene/NiS nanocomposite (NG/NiS) are prepared via green microwave synthesis route as electrode materials for supercapacitors. As-prepared materials are examined using XRD, Raman, XPS, SEM, EDX and elemental mapping characterization techniques to obtain the information regarding their structure, complex formation, morphology and elemental presence. The electrochemical investigations like CV, GCD and impedance analysis suggest that NG/NiS is an excellent electrode material with a specific capacitance of 1467.8 F g⁻¹ at 1 A g⁻¹. In asymmetric configuration of NG//NG/NiS, with polyurethane foam as the separator soaked with 6 M KOH and graphite sheet as the current collector, the composite produces the energy density of 66.6 Wh kg⁻¹ at a power density of 405.83 W kg⁻¹ with a cyclic stability of 86.6% for 5000 cycles. The high electrochemical performance is because N-doped graphene houses NiS nanoflake clusters, and together they demonstrate an impressive performance for supercapacitors.

Vorheriger Artikel Influence of internal displacement on band structure, phase transition, and thermoelectric properties of bismuth

Nächster Artikel Effects of piezoelectric-phase orientations on magnetoelectric coefficient in AlN–FeCoSiB multiferroic composites

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Yadav R, Dixit CK (2017) Synthesis, characterization and prospective applications of nitrogen-doped graphene: a short review. J Sci Adv Mater Dev 2:141–149. https://doi.org/10.1016/j.jsamd.2017.05.007

Kwon OS, Park SJ, Hong JY, Han AR, Lee JS, Oh JH, Jang J (2012) Flexible FET-type VEGF aptasensor based on nitrogen-doped graphene converted from conducting polymer. ACS Nano 6:1486–1493. https://doi.org/10.1021/nn204395n CrossRef

Guan L, Cui L, Lin K, Wang YY, Wang XT, Jin FM, He F, Chen XP, Cui S (2011) Preparation of few-layer nitrogen-doped graphene nanosheets by DC arc discharge under nitrogen atmosphere of high temperature. Appl Phys A 102:289–294. https://doi.org/10.1007/s00339-010-6110-5 CrossRef

Jeong HM, Lee JW, Shin WH, Choi YJ, Shin HJ, Kang JK, Choi JW (2011) Nitrogen-doped graphene for high-performance ultracapacitors and the importance of nitrogen-doped sites at basal planes. Nano Lett 11:2472–2477. https://doi.org/10.1021/nl2009058 CrossRef

Zheng B, Wang J, Wang FB, Xi XH (2013) Synthesis of nitrogen doped graphene with high electrocatalytic activity toward oxygen reduction reaction. Electrochem Commun 28:24–26. https://doi.org/10.1016/j.elecom.2012.11.037 CrossRef

Sun L, Wang L, Tian CG, Tan TX, Xie Y, Shi KY, Li MT, Fu HG (2012) Nitrogen-doped graphene with high nitrogen level via a one-step hydrothermal reaction of graphene oxide with urea for superior capacitive energy storage. RSC Adv 12:4498–4506. https://doi.org/10.1039/c2ra01367c CrossRef

Liu C, Zhang L, Liu R, Gao Z, Yang X, Tu Z, Yang F, Ye Z, Cui L, Xu C, Li Y (2016) Hydrothermal synthesis of N-doped TiO₂ nanowires and N-doped graphene heterostructures with enhanced photocatalytic properties. J Alloys Compd 656:24–32. https://doi.org/10.1016/j.jallcom.2015.09.211 CrossRef

Lu Y, Huang Y, Zhang M, Chen Y (2014) Nitrogen-doped graphene materials for supercapacitor applications. J Nanosci Nanotechnol 14:1134–1144. https://doi.org/10.1166/jnn.2014.9102 CrossRef

Cheng CK, Lin CH, Wu HC, Ma CCM, Yeh TK, Chou HY, Tsai CH, Hsieh CK (2016) The Two-dimensional nanocomposite of molybdenum disulfide and nitrogen-doped graphene oxide for efficient counter electrode of dye-sensitized solar cells. Nanoscale Res Lett 11:117–125. https://doi.org/10.1186/s11671-016-1277-0 CrossRef

10.

Li YF, Liu YZ, Liang Y, Guo XH, Chen CM (2017) Preparation of nitrogen-doped graphene/activated carbon composite papers to enhance energy storage in supercapacitors. Appl Phys A 123:566–571. https://doi.org/10.1007/s00339-017-1178-9 CrossRef

11.

Li Z, Cao L, Qin P, Liu X, Chen Z, Wang L, Pan D, Wu M (2018) Nitrogen and oxygen co-doped graphene quantum dots with high capacitance performance for micro-supercapacitors. Carbon 139:67–75. https://doi.org/10.1016/j.carbon.2018.06.042 CrossRef

12.

Ramesh S, Kim HS, Kim J, Kim H, Karuppasamy K, Msolli S (2017) Nanocrystalline structured of NiO/MnO₂@nitrogen-doped graphene oxide hybrid nanocomposite for high performance supercapacitor. New J Chem 41:15517–15527. https://doi.org/10.1039/c7nj03730a CrossRef

13.

Xie B, Chen Y, Yu M, Shen X, Lei H, Xie T, Zhang Y, Wu Y (2015) Carboxyl-assisted synthesis of nitrogen-doped graphene sheets for supercapacitor applications. Nanoscale Res Lett 10:332–342. https://doi.org/10.1186/s11671-015-1031-z CrossRef

14.

Yang J, Duan X, Qin Q, Zheng W (2013) Solvothermal synthesis of hierarchical flower-like β-NiS with excellent electrochemical performance for supercapacitors. J Mater Chem A 1:7880–7884. https://doi.org/10.1039/c3ta11167a CrossRef

15.

Pang H, Wei C, Li X, Li G, Ma Y, Li S, Chen J, Zhang J (2014) Microwave-assisted synthesis of NiS₂ nanostructures for supercapacitors and cocatalytic enhancing photocatalytic H₂ production. Sci Rep 4:3577–3584. https://doi.org/10.1038/srep03577 CrossRef

16.

Su CW, Li JM, Yang W, Guo JM (2014) Electrodeposition of Nis₃S₂/Ni composites as high-performance cathodes for lithium batteries. J Phy Chem C 118:767–773. https://doi.org/10.1021/jp407185p CrossRef

17.

Son MY, Choi JH, Kang YC (2014) Electrochemical properties of bare nickel sulfide and nickel sulfide-carbon composites prepared by one-pot spray pyrolysis as anode materials for lithium secondary batteries. J Power Sour 251:480–487. https://doi.org/10.1016/j.jpowsour.2013.10.093 CrossRef

18.

Pan Q, Xie J, Zhu TJ, Cao GS, Zhao XB, Zhang SC (2014) Reduced graphene oxide-induced recrystallization of NiS nanorods to nanosheets and the improved Na-storage properties. Inorg Chem 53:3511–3518. https://doi.org/10.1021/ic402948s CrossRef

19.

Sebastian ST, Jagan RS, Rajagoplan R, Paravannoor A, Menon LV, Subramanian KRV, Nair SV, Balakrishnan A (2014) Lithium-ion storage performance of camphoric carbon wrapped NiS nano/micro-hybrids. RSC Adv 4:11673–11679. https://doi.org/10.1039/c4ra00176a CrossRef

20.

Jiang B, Tian C, Wang L, Sun L, Chen C, Nong X, Qiao Y, Fu H (2012) Highly concentrated, stable nitrogen-doped graphene for supercapacitors: simultaneous doping and reduction. Appl Surf Sci 258:3438–3443. https://doi.org/10.1016/j.apsusc.2011.11.091 CrossRef

21.

Cai F, Sun R, Kang Y, Chen H, Chen M, Li Q (2015) One-step strategy to a three-dimensional NiS-reduced graphene oxide hybrid nanostructure for high performance supercapacitors. RSC Adv 5:23073–23079. https://doi.org/10.1039/c5ra02058a CrossRef

22.

Yang J, Duan X, Guo W, Li D, Zhang H, Zheng W (2014) Electrochemical performances investigation of NiS/rGO composite as electrode material for supercapacitors. Nano Energy 5:74–81. https://doi.org/10.1016/j.nanoen.2014.02.006 CrossRef

23.

Wang A, Wang H, Zhang S, Mao C, Song J, Niu H, Jin B, Tian Y (2013) Controlled synthesis of nickel sulfide/graphene oxide nanocomposite for high-performance supercapacitor. Appl Surf Sci 282:704–708. https://doi.org/10.1016/j.apsusc.2013.06.038 CrossRef

24.

Singh A, Roberts AJ, Slade RCT, Chandra R (2014) High electrochemical performance in asymmetric supercapacitors using MWCNT/nickel sulfide composite and graphene nanoplatelets as electrodes. J Mater Chem A 2:16723–16730. https://doi.org/10.1039/c4ta02870h CrossRef

25.

Zhang Z, Zhao C, Min S, Qian X (2014) A facile one-step route to RGO/Ni₃S₂ for high-performance supercapacitors. Electrochim Acta 144:100–110. https://doi.org/10.1016/j.electacta.2014.08.038 CrossRef

26.

Xing Z, Chu Q, Ren X, Tian J, Asiri AM, Alamry KA, Al-Youbi AO, Sun X (2013) Biomolecule-assisted synthesis of nickel sulfides/reduced graphene oxide nanocomposites as electrode materials for supercapacitors. Electrochem Commun 32:9–13. https://doi.org/10.1016/j.elecom.2013.03.033 CrossRef

27.

Zhang Z, Liu X, Qi X, Huang Z, Renab L, Zhong J (2014) Hydrothermal synthesis of Ni₃S₂/graphene electrode and its application in a supercapacitor. RSC Adv 4:37278–37283. https://doi.org/10.1039/c4ra05078a CrossRef

28.

Jinlong L, Tongxiang L, Meng Y, Suzuki K, Miura H (2017) The plume-like Ni₃S₂ supercapacitor electrodes formed on nickel foam by catalysis of thermal reduced graphene oxide. J Electroanal Chem 786:8–13. https://doi.org/10.1016/j.jelechem.2017.01.004 CrossRef

29.

Zhou W, Cao X, Zheng Z, Shi W, Zhu Y, Yan Q, Liu H, Wang J, Zhang H (2013) One-step synthesis of Ni₃S₂ nanorod@Ni(OH)₂ nanosheet core–shell nanostructures on a three-dimensional graphene network for high-performance supercapacitors. Energy Environ Sci 6:2216–2221. https://doi.org/10.1039/c3ee40155c CrossRef

30.

Liu X, Qi X, Zhang Z, Ren L, Liu Y, Meng L, Huang K, Zhong J (2014) One-step electrochemical deposition of nickel sulfide/graphene and its use for supercapacitors. Ceram Int 40:8189–8193. https://doi.org/10.1016/j.ceramint.2014.01.015 CrossRef

31.

Wu P, Wang D, Ning J, Zhang J, Feng X, Dong J, Hao Y (2018) Novel 3D porous graphene/Ni₃S₂ nanostructures for high-performance supercapacitor electrodes. J Alloys Compd 731:1063–1068. https://doi.org/10.1016/j.jallcom.2017.10.060 CrossRef

32.

Meher SK, Justin P, Ranga Rao P (2011) Microwave-mediated synthesis for improved morphology and pseudocapacitance performance of nickel oxide. ACS Appl Mater Interfaces 3:2063–2073. https://doi.org/10.1021/am200294k CrossRef

33.

Yuan C, Zhang X, Su L, Gao B, Shen L (2009) Facile synthesis and self-assembly of hierarchical porous NiO nano/micro spherical superstructures for high performance supercapacitors. J Mater Chem 19:5772–5777. https://doi.org/10.1039/b902221j CrossRef

34.

Liu N, Wang X, Xu W, Hu H, Liang J, Qiu J (2014) Microwave-assisted synthesis of MoS₂/graphene nanocomposites for efficient hydrodesulfurization. Fuel 119:163–169. https://doi.org/10.1016/j.fuel.2013.11.045 CrossRef

35.

Peng L, Ji X, Wan H, Ruan Y, Xu K, Chen C, Miao L, Jiang J (2015) Nickel sulfide nanoparticles synthesized by microwave-assisted method as promising supercapacitor electrodes: an experimental and computational study. Electrochim Acta 182:361–367. https://doi.org/10.1016/j.electacta.2015.09.024 CrossRef

36.

Ghorbani M, Abdizedeh H, Golobostanfard MR (2015) Reduction of graphene oxide via modified hydrothermal method. Proc Mater Sci 11:326–330. https://doi.org/10.1016/j.mspro.2015.11.104 CrossRef

37.

Chen YL, Hu ZA, Chang YQ, Wang HW, Zhang ZY, Yang YY, Wu HY (2011) Zinc oxide/reduced graphene oxide composites and electrochemical capacitance enhanced by homogeneous incorporation of reduced graphene oxide sheets in zinc oxide matrix. J Phys Chem C 115:2563–2571. https://doi.org/10.1021/jp109597n CrossRef

38.

Mohan VB, Brown R, Jayaraman K, Bhattacharyya D (2014) Characterization of reduced graphene oxide: effects of reduction variables on electrical conductivity. Mater Sci Eng B 193:49–60. https://doi.org/10.1016/j.mseb.2014.11.002 CrossRef

39.

Rajagopalan B, Chung JS (2014) Reduced chemically modified graphene oxide for supercapacitor electrode. Nanoscale Res Lett 9:535–544. https://doi.org/10.1186/1556-276X-9-535 CrossRef

40.

Stankovich S, Dikin DA, Piner RD, Kohlhaas KA, Kleinhammes K, Jia Y, Wu Y, Nguyen ST, Ruoff RS (2007) Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon 45:1558–1565. https://doi.org/10.1016/j.carbon.2007.02.034 CrossRef

41.

Sudhakar S, Joshi DN, Peera SG, Sahu SK, Eggleston CM, Prasath RA (2018) Hydrothermal-microwave synthesis of cobalt oxide incorporated nitrogen-doped graphene composite as an efficient catalyst for oxygen reduction reaction in alkaline medium. J Mater Sci Mater Electron 29:6750–6762. https://doi.org/10.1007/s10854-018-8661-8 CrossRef

42.

Wang Z, Zhang X, Wang J, Zou L, Liu Z, Hao Z (2013) Preparation and capacitance properties of graphene/NiAl layered double-hydroxide nanocomposite. J Colloid Interface Sci 396:251–257. https://doi.org/10.1016/j.jcis.2013.01.013 CrossRef

43.

Zheng H, Ni Y, Wan F, Ma X (2015) Fast synthesis and electrochemical performance of hollow NiCo₂O₄ flowerlike microstructures. RSC Adv 5:31558–31565. https://doi.org/10.1039/c5ra03747f CrossRef

44.

Shou Q, Cheng JP, Zhang L, Nelson BJ, Zhang XB (2012) Synthesis and characterization of a nanocomposite of goethite nanorods and reduced graphene oxide for electrochemical capacitors. J Solid State Chem 185:191–197. https://doi.org/10.1016/j.jssc.2011.11.020 CrossRef

45.

Zhao F, Wang Y, Xu X, Liu Y, Song R, Lu G, Li Y (2014) Cobalt hexacyanoferrate nanoparticles as a high-rate and ultra-stable supercapacitor electrode material. ACS Appl Mater Interfaces 6:11007–11012. https://doi.org/10.1021/am503375h CrossRef

46.

Xie LJ, Wu JF, Chen CM, Zhang CM, Wan L, Wang JL, Kong QQ, Lv CX, Li KX, Sun GH (2013) A novel asymmetric supercapacitor with an activated carbon cathode and a reduced graphene oxide–cobalt oxide nanocomposite anode. J Power Sour 242:148–156. https://doi.org/10.1016/j.jpowsour.2013.05.081 CrossRef

47.

Xu XW, Shen JF, Li N, Ye MX (2014) Microwave-assisted synthesis of graphene/CoMoO₄ nanocomposites with enhanced supercapacitor performance. J Alloys Compd 616:58–65. https://doi.org/10.1016/j.jallcom.2014.07.047 CrossRef

48.

Morishita T, Soneda Y, Hatori H, Inagaki M (2007) Carbon-coated tungsten and molybdenum carbides for electrode of electrochemical capacitor. Electrochim Acta 52:2478–2484. https://doi.org/10.1016/j.electacta.2006.08.056 CrossRef

49.

Yu M, Chen JP, Liu JH, Li SM, Ma YX, Zhang JD, An JW (2015) Mesoporous NiCo₂O₄ nanoneedles grown on 3D graphene-nickel foam for supercapacitor and methanol electro-oxidation. Electrocim Acta 151:99–108. https://doi.org/10.1016/j.electacta.2014.10.156 CrossRef

50.

Zhang Z, Liu Y, Huang Z, Ren L, Qi X, Wei X, Zhong J (2015) Facile hydrothermal synthesis of NiMoO₄@CoMoO₄ hierarchical nanospheres for supercapacitor applications. Phys Chem Chem Phys 17:20795–20804. https://doi.org/10.1039/c5cp03331d CrossRef

Titel: Asymmetric supercapacitor device performance based on microwave synthesis of N-doped graphene/nickel sulfide nanocomposite
verfasst von: B. Joji Reddy
P. Vickraman
A. Simon Justin
Publikationsdatum: 07.01.2019
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 8/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-018-03314-6

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 8/2019

3D-printed highly porous and reusable chitosan monoliths for Cu(II) removal

High strength and ductility combination in nano-/ultrafine-grained medium-Mn steel by tuning the stability of reverted austenite involving intercritical annealing

Amorphization kinetics in strontium titanate at 16 and 300 K under argon ion irradiation

Metallic origami metastructures for high-temperature low electromagnetic reflectivity

Easily recyclable photocatalyst Bi2WO6/MOF/PVDF composite film for efficient degradation of aqueous refractory organic pollutants under visible-light irradiation

Novel tape-cast SiOC-based porous ceramic electrode materials for potential application in bioelectrochemical systems

Premium Partner

Marktübersichten