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Journal of Materials Engineering and Performance

Erschienen in:

16.01.2018

Atomic Layer-Deposited TiO₂ Coatings on NiTi Surface

verfasst von: D. Vokoun, J. Racek, L. Kadeřávek, C. C. Kei, Y. S. Yu, L. Klimša, P. Šittner

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 2/2018

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Abstract

NiTi shape-memory alloys may release poisonous Ni ions at the alloys’ surface. In an attempt to prepare a well-performing surface layer on an NiTi sample, the thermally grown TiO₂ layer, which formed during the heat treatment of NiTi, was removed and replaced with a new TiO₂ layer prepared using the atomic layer deposition (ALD) method. Using x-ray photoelectron spectroscopy, it was found that the ALD layer prepared at as low a temperature as 100 °C contained Ti in oxidation states + 4 and + 3. As for static corrosion properties of the ALD-coated NiTi samples, they further improved compared to those covered by thermally grown oxide. The corrosion rate of samples with thermally grown oxide was 1.05 × 10⁻⁵ mm/year, whereas the corrosion rate of the ALD-coated samples turned out to be about five times lower. However, cracking of the ALD coating occurred at about 1.5% strain during the superelastic mechanical loading in tension taking place via the propagation of a localized martensite band.

Vorheriger Artikel Dynamic Recrystallization Behavior of AISI 422 Stainless Steel During Hot Deformation Processes

Nächster Artikel Failure Analysis and Magnetic Evaluation of Tertiary Superheater Tube Used in Gas-Fired Boiler

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Titel: Atomic Layer-Deposited TiO2 Coatings on NiTi Surface
verfasst von: D. Vokoun
J. Racek
L. Kadeřávek
C. C. Kei
Y. S. Yu
L. Klimša
P. Šittner
Publikationsdatum: 16.01.2018
Verlag: Springer US
Erschienen in: Journal of Materials Engineering and Performance / Ausgabe 2/2018
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI: https://doi.org/10.1007/s11665-018-3136-x

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