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Journal of Materials Science
Erschienen in: Journal of Materials Science 4/2020

16.10.2019 | Energy materials

Benzene–toluene–xylene (BTX) from p-cresol by hydrodeoxygenation over nickel phosphide catalysts with different supports

verfasst von: Liuyi Pan, Yulong He, Menglong Niu, Yong Dan, Wenhong Li

Erschienen in: Journal of Materials Science | Ausgabe 4/2020

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Abstract

Ni2P catalysts supported on different supports, such as SiO2 from different sources, Al2O3, TiO2 and ZrO2 were prepared for the hydrodeoxygenation of p-cresol (monocyclic phenol model in coal tar). The reaction was carried out on a fixed-bed reactor at a temperature of 330–390 °C under 2 MPa. The order of conversion of p-cresol was as follows: Ni2P/SiO2-2 > Ni2P/SiO2-3 > Ni2P/SiO2-1 > Ni2P/Al2O3 > Ni2P/ZrO2 > Ni2P/TiO2. Ni2P/SiO2-3 shown higher DDO path selectivity, resulting in the conversion of p-cresol of 93% and a selectivity of 72.6% for BTX products under the reaction temperature of 370 °C with LHSV of 0.5 h−1. This catalyst was also used for the hydrodeoxygenation of the crude phenolic mixture extracted from coal tar, which shown that the phenol deoxidation rate was 87.6% and the BTX product selectivity was 73.7% by GC–MS.
Vorheriger Artikel Synthesis of Mn2+-doped ZnS by a mechanically induced self-sustaining reaction
Nächster Artikel Hierarchical NiCo2S4 nanosheets grown on graphene to catalyze the oxygen evolution reaction

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Metadaten
Titel
Benzene–toluene–xylene (BTX) from p-cresol by hydrodeoxygenation over nickel phosphide catalysts with different supports
verfasst von
Liuyi Pan
Yulong He
Menglong Niu
Yong Dan
Wenhong Li
Publikationsdatum
16.10.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 4/2020
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-019-04037-y

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