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Erschienen in: Journal of Materials Science 30/2020

20.07.2020 | Ceramics

[(Bi0.50Na0.40K0.10)0.94Ba0.06]1-xLaxTi0.975Ta0.025O3 lead-free relaxor ceramics with high energy storage density and thermally stable dielectric properties

verfasst von: Benben Yan, Huiqing Fan, Arun Kumar Yadav, Chao Wang, Zhinan Du, Mengyuan Li, Weijia Wang, Wenqiang Dong, Shuren Wang

Erschienen in: Journal of Materials Science | Ausgabe 30/2020

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Abstract

Dielectric ceramics for capacitors have attained significant attention in current time owing to their large power densities and fast charge/discharge rates. Lead-free [(Bi0.50Na0.40K0.10)0.94Ba0.06]1-xLaxTi0.975Ta0.025O3 (abbreviated as BNKBTT-100xLa) relaxor ceramics are prepared using mixed-oxide technique. All ceramics are revealed a pseudo-cubic structure using X-ray diffraction technique. The long-range order existing in BNKBTT-100xLa ceramics is found to reduce with increasing composition. As a result, a highly effective energy storage density (Wrec) ~ 1.558 J/cm3 and efficiency (η) ~ 88.46% is achieved in BNKBTT-2La ceramic. In addition, BNKBTT-2La composition is fatigue-free up to 105 cycles. Also, BNKBTT-4La ceramic exhibits a dielectric constant (ε') ~ 2281 near 150 °C with Δε'/ε'150 °C below 15% over a large range from 39 to 383 °C, showing an outstanding dielectric temperature stability. Therefore, BNKBTT-2La and BNKBTT-4La ceramics are outstanding for energy density and thermally stable dielectric permittivity, respectively, for the device applications.

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Metadaten
Titel
[(Bi0.50Na0.40K0.10)0.94Ba0.06]1-xLaxTi0.975Ta0.025O3 lead-free relaxor ceramics with high energy storage density and thermally stable dielectric properties
verfasst von
Benben Yan
Huiqing Fan
Arun Kumar Yadav
Chao Wang
Zhinan Du
Mengyuan Li
Weijia Wang
Wenqiang Dong
Shuren Wang
Publikationsdatum
20.07.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 30/2020
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-020-05070-y

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