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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 9/2019

01.09.2019 | ORIGINAL PAPER

Bio-inspired multiple complementary hydrogen bonds enhance the miscibility of conjugated polymers blended with polystyrene derivatives

verfasst von: Bo-Han Mao, Ahmed F. M. EL-Mahdy, Shiao-Wei Kuo

Erschienen in: Journal of Polymer Research | Ausgabe 9/2019

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Abstract

In this study, we prepared bio-inspired multiple-hydrogen-bonded blends of a thymine (T)-functionalized PTC-T conjugated polymer, synthesized through Suzuki coupling polymerization, and an adenine (A)-functionalized polystyrene (PVBA) homopolymer, synthesized through free radical polymerization, in each case applying also alkylene–azide click reactions. The resulting PTC-T/PVBA blends displayed a single glass transition temperature at all blend compositions (as determined using differential scanning calorimetry), suggesting that the miscibility arose because of the strong multiple hydrogen bonding between the A and T groups of the PVBA and PTC-T components, respectively. 1H NMR and FTIR spectroscopy provided evidence for such A–T binary hydrogen bonding in the PTC-T/PVBA miscible domains, both in solution and in the solid state. Furthermore, the incorporation of PVBA into PTC-T affected the photophysical properties of the luminescent film: the physically crosslinked structure formed from the multiple hydrogen bonding interactions improved the quantum yield through phase-miscible behavior.
Vorheriger Artikel Fluorinated polyimide nanocomposites for low K dielectric applications
Nächster Artikel Fabrication of Ni3S2@polypyrrole core-shell nanorod arrays on nickel foam as supercapacitor device

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Metadaten
Titel
Bio-inspired multiple complementary hydrogen bonds enhance the miscibility of conjugated polymers blended with polystyrene derivatives
verfasst von
Bo-Han Mao
Ahmed F. M. EL-Mahdy
Shiao-Wei Kuo
Publikationsdatum
01.09.2019
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 9/2019
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-019-1875-5

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