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Journal of Materials Science
Erschienen in: Journal of Materials Science 30/2020

27.07.2020 | Energy materials

Biomineralized zircon-coated PVDF nanofiber separator for enhancing thermo- and electro-chemical properties of lithium ion batteries

verfasst von: Shaojin Jia, Jiating Long, Jiwei Li, Shaohua Yang, Kaili Huang, Na Yang, Yuhao Liang, Jun Xiao

Erschienen in: Journal of Materials Science | Ausgabe 30/2020

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Abstract

As one of the components of the lithium ion batteries (LIBs), the separator plays a vital part in the safety and electrochemical performance. In this work, a ZrO2-ceramic-coated polyvinylidene fluoride (PVDF) nanofibrous separator for LIBs was successfully prepared by electrospinning, subsequent dopamine hydrophilic modification and biomimetic mineralization process. These preparation processes were environmentally friendly and simple. The ZrO2-ceramic coating endows the separator with outstanding electrolyte wettability and thermal stability. To be specific, the separator exhibits higher ionic conductivity (2.261 mS cm−1), high porosity (85.1%) and favorable electrolyte wettability (352%), and lower interfacial impedance (220 Ω). Compared with commercial polyolefin separator and PVDF nanofibrous separator, the ZrO2-ceramic-coated PVDF nanofibrous separator exhibits excellent rate performance and well cyclic stability. Most importantly the ZrO2–PDA/PEI–PVDF separator can still maintain a complete structure even at a high temperature of 300 °C. Compared with commercial separators, it greatly improves the safety of lithium ion batteries at high temperature. Therefore, this separator has far-reaching prospects for improving lithium ion safety and cycle stability.
Vorheriger Artikel Water-assisted formation of highly conductive silver nanowire electrode for all solution-processed semi-transparent perovskite and organic solar cells
Nächster Artikel Outstanding hydrogen production properties of surface catalysts promoted Mg–Ni–Ce composites at room temperature in simulated seawater

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Metadaten
Titel
Biomineralized zircon-coated PVDF nanofiber separator for enhancing thermo- and electro-chemical properties of lithium ion batteries
verfasst von
Shaojin Jia
Jiating Long
Jiwei Li
Shaohua Yang
Kaili Huang
Na Yang
Yuhao Liang
Jun Xiao
Publikationsdatum
27.07.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 30/2020
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-020-05051-1

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