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2018 | OriginalPaper | Buchkapitel

45. Boiling in Reagent and Polymeric Solutions

verfasst von : Raj M. Manglik

Erschienen in: Handbook of Thermal Science and Engineering

Verlag: Springer International Publishing

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Abstract

Multiphase interfaces and the convective mass, momentum, and heat transport across their boundaries fundamentally govern boiling heat transfer. This interfacial activity is further altered and is quite complex in reagent and polymeric aqueous solutions. At the gas-liquid-solid boundaries, wetting at the liquid-solid interface is modified by physisorption of solute, and the liquid-vapor interfacial tension displays a time-dependent behavior due to solute adsorption. At the microscale, the transient transport of surface-active additives (reagents or polymers) in the liquid modulates dynamically the solid-liquid-vapor interfaces during nucleation and subsequent vapor bubble growth dynamics. This essentially characterizes macroscale heat transport and the ebullient signature of boiling. The molecular characteristics of reagents thus affect and control this process; in fact, surface wetting and surface tension can be decoupled. An overview of the current state of the art of boiling with reagents and polymers is presented in this chapter. Particular emphasis is given to the role of microscale interfacial changes on boiling heat transfer, which are triggered at the molecular scale by the adsorption-desorption of the soluble additive at the liquid-vapor interface and its electrokinetics at the liquid-solid interface.

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Vorheriges Kapitel Mixture Boiling

Nächstes Kapitel Fundamental Equations for Two-Phase Flow in Tubes

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Titel: Boiling in Reagent and Polymeric Solutions
verfasst von: Raj M. Manglik
Verlag: Springer International Publishing
Buch: Handbook of Thermal Science and Engineering
Print ISBN: 978-3-319-26694-7

Electronic ISBN: 978-3-319-26695-4

Copyright-Jahr: 2018
DOI: https://doi.org/10.1007/978-3-319-26695-4_45

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