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Erschienen in:
Nanodiamonds: From Synthesis and Purification to Deposition Techniques, Hybrids Fabrication and Applications Kapitel lesen Erstes Kapitel lesen

2016 | OriginalPaper | Buchkapitel

Carbon Based Dots and Their Luminescent Properties and Analytical Applications

verfasst von : Yongqiang Dong, Jianhua Cai, Yuwu Chi

Erschienen in: Carbon Nanoparticles and Nanostructures

Verlag: Springer International Publishing

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Abstract

Carbon based dots (CDs) composed of sp2 carbon structures and surface functional groups are a new kind of carbon nanomaterials, exhibiting unique luminescent properties due to the quantum confinement and edge effects. This chapter introduces CDs in detail from their synthetic strategies, morphological and structural characteristics, luminescent properties and mechanisms, and sensing applications. The synthesis methods are summarized as “top-down” and “bottom-up” approaches. Luminescent properties discussed include photoluminescence, upconversion luminescence, chemiluminescence, electrochemiluminescence. Sensing applications mainly refer to the chemical and biological sensors based on the luminescent properties of CDs. This chapter provides an overview of the research field and gives future perspectives for developing the exciting materials.

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Vorheriges Kapitel Polyglycerol-Functionalized Nanoparticles for Biomedical Imaging
Nächstes Kapitel Photoluminescent Properties of Carbon Nanodots
Literatur
1.
2.
3.
X. Yan, B.S. Li, L.S. Li, Colloidal graphene quantum dots with well-defined structures. Acc. Chem. Res. 46(10), 2254–2262 (2013). doi:10.​1021/​ar300137p
4.
5.
6.
L. Cao, M.J. Meziani, S. Sahu, Y.P. Sun, Photoluminescence properties of graphene versus other carbon nanomaterials. Acc. Chem. Res. 46(1), 171–180 (2012). doi:10.​1021/​ar300128j CrossRef
7.
8.
X.Y. Xu, R. Ray, Y.L. Gu, H.J. Ploehn, L. Gearheart, K. Raker, W.A. Scrivens, Electrophoretic analysis and purification of fluorescent single-walled carbon nanotube fragments. J. Am. Chem. Soc. 126(40), 12736–12737 (2004). doi:10.​1021/​ja040082h CrossRef
9.
Y.P. Sun, B. Zhou, Y. Lin, W. Wang, K.A.S. Fernando, P. Pathak, M.J. Meziani, B.A. Harruff, X. Wang, H.F. Wang, Quantum-sized carbon dots for bright and colorful photoluminescence. J. Am. Chem. Soc. 128(24), 7756–7757 (2006). doi:10.​1021/​ja062677d CrossRef
10.
A.B. Bourlinos, R. Zbořil, J. Petr, A. Bakandritsos, M. Krysmann, E.P. Giannelis, Luminescent surface quaternized carbon dots. Chem. Mater. 24(1), 6–8 (2012). doi:10.​1021/​cm2026637 CrossRef
11.
F. Wang, S. Pang, L. Wang, Q. Li, M. Kreiter, C.Y. Liu, One-step synthesis of highly luminescent carbon dots innoncoordinating solvents. Chem. Mater. 22(16), 4528–4530 (2010). doi:10.​1021/​cm101350u CrossRef
12.
13.
S. Chandra, S.H. Pathan, S. Mitra, B.H. Modha, A. Goswami, P. Pramanik, Tuning of photoluminescence on different surface functionalized carbon quantum dots. RSC Adv. 2(9), 3602–3606 (2012). doi:10.​1039/​c2ra00030j CrossRef
14.
X.M. Wen, P. Yu, Y.R. Toh, X.Q. Ma, J. Tang, On the upconversion fluorescence in carbon nanodots and graphene quantum dots. Chem. Commun. 50(36), 4703–4706 (2014). doi:10.​1039/​c4cc01213e CrossRef
15.
A.B. Bourlinos, A. Stassinopoulos, D. Anglos, R. Zboril, V. Georgakilas, E.P. Giannelis, Photoluminescent carbogenic dots. Chem. Mater. 20(14), 4539–4541 (2008). doi:10.​1021/​cm800506r CrossRef
16.
17.
18.
19.
20.
21.
L.A. Ponomarenko, F. Schedin, M.I. Katsnelson, R. Yang, E.W. Hill, K.S. Novoselov, A.K. Geim, Chaotic dirac billiard in graphene quantum dots. Science 320(5874), 356–358 (2008). doi:10.​1126/​science.​1154663 CrossRef
22.
23.
S. Zhu, S. Tang, J. Zhang, B. Yang, Control the size and surface chemistry of graphene for the rising fluorescent materials. Chem. Commun. 48(38), 4527–4539 (2012). doi:10.​1039/​c2cc31201h CrossRef
24.
25.
Z. Zhang, J. Zhang, N. Chen, L. Qu, Graphene quantum dots: an emerging material for energy-related applications and beyond. Energ. Environ. Sci. 5(10), 8869–8895 (2012). doi:10.​1039/​c2ee22982j CrossRef
26.
X. Wang, G. Sun, P. Routh, D.H. Kim, W. Huang, P. Chen, Heteroatom-doped graphene materials: syntheses, properties and applications. Chem. Soc. Rev. 43(20), 7067–7098 (2014). doi:10.​1039/​c4cs00141a CrossRef
27.
J. Shen, Y. Zhu, X. Yang, C. Li, Graphene quantum dots: emergent nanolights for bioimaging, sensors, catalysis and photovoltaic devices. Chem. Commun. 48(31), 3686–3699 (2012). doi:10.​1039/​c2cc00110a CrossRef
28.
L. Lin, M. Rong, F. Luo, D. Chen, Y. Wang, X. Chen, Luminescent graphene quantum dots as new fluorescent materials for environmental and biological applications. TrAC Trends Anal. Chem. 54, 83–102 (2014). doi:10.​1016/​j.​trac.​2013.​11.​001 CrossRef
29.
L. Li, G. Wu, G. Yang, J. Peng, J. Zhao, J.J. Zhu, Focusing on luminescent graphene quantum dots: current status and future perspectives. Nanoscale 5(10), 4015–4039 (2013). doi:10.​1039/​c3nr33849e CrossRef
30.
31.
32.
S.L. Hu, K.Y. Niu, J. Sun, J. Yang, N.Q. Zhao, X.W. Du, One-step synthesis of fluorescent carbon nanoparticles by laser irradiation. J. Mater. Chem. 19(4), 484–488 (2009). doi:10.​1039/​b812943f CrossRef
33.
X. Wang, L. Cao, F. Lu, M.J. Meziani, H. Li, G. Qi, B. Zhou, B.A. Harruff, F. Kermarrec, Y.P. Sun, Photoinduced electron transfers with carbon dots. Chem. Commun. 25, 3774–3776 (2009). doi:10.​1039/​b906252a CrossRef
34.
S.T. Yang, X. Wang, H.F. Wang, F.S. Lu, P.J.G. Luo, L. Cao, M.J. Meziani, J.H. Liu, Y.F. Liu, M. Chen, Carbon dots as nontoxic and high-performance fluorescence imaging agents. J. Phys. Chem. C 113(42), 18110–18114 (2009). doi:10.​1021/​jp9085969 CrossRef
35.
S.T. Yang, L. Cao, P.G.J. Luo, F.S. Lu, X. Wang, H.F. Wang, M.J. Meziani, Y.F. Liu, G. Qi, Y.P. Sun, Carbon dots for optical imaging in vivo. J. Am. Chem. Soc. 131(32), 11308–11309 (2009). doi:10.​1021/​ja904843x CrossRef
36.
Q. Li, T.Y. Qhulchanskyy, R.L. Liu, K. Koynov, D.Q. Wu, A. Best, R. Kumar, A. Bonoiu, P.N. Prasad, Photoluminescent carbon dots as biocompatible nanoprobes for targeting cancer cells. J. Phys. Chem. C 114(28), 12062–12068 (2010). doi:10.​1021/​jp911539r CrossRef
37.
L. Cao, X. Wang, M.J. Meziani, F.S. Lu, H.F. Wang, P.J.G. Luo, Y. Lin, B.A. Harruff, L.M. Veca, D. Murray, Carbon dots for nultiphoton bioimaging. J. Am. Chem. Soc. 129(37), 11318–11319 (2007). doi:10.​1021/​ja073527l CrossRef
38.
39.
S.C. Ray, A. Saha, N.R. Jana, R. Sarkar, Fluorescent carbon nanoparticles: synthesis, characterization, and bioimaging application. J. Phys. Chem. C 113(43), 18546–18551 (2009). doi:10.​1021/​jp905912n CrossRef
40.
X.H. Wang, K.G. Qu, B.L. Xu, J.S. Ren, X.G. Qu, Multicolor luminescent carbon nanoparticles: synthesis, supramolecular assembly with porphyrin, intrinsic peroxidase-like catalytic activity and applications. Nano Res. 4(9), 908–920 (2011). doi:10.​1007/​s12274-011-0147-4 CrossRef
41.
M. Tan, L. Zhang, R. Tang, X. Song, Y. Li, H. Wu, Y. Wang, G. Lv, W. Liu, X. Ma, Enhanced photoluminescence and characterization of multicolor carbon dots using plant soot as a carbon source. Talanta 115, 950–956 (2013). doi:10.​1016/​j.​talanta.​2013.​06.​061 CrossRef
42.
L. Tian, D. Ghosh, W. Chen, S. Pradhan, X.J. Chang, S.W. Chen, Nanosized carbon particles from natural gas soot. Chem. Mater. 21(13), 2803–2809 (2009). doi:10.​1021/​cm900709w CrossRef
43.
J.M. Berlin, T.T. Pham, D. Sano, K.A. Mohamedali, D.C. Marcano, J.N. Myers, J.M. Tour, Noncovalent functionalization of carbon nanovectors with an antibody enables targeted drug delivery. ACS Nano 5(8), 6643–6650 (2011). doi:10.​1021/​nn2021293 CrossRef
44.
Y. Dong, N. Zhou, X. Lin, J. Lin, Y. Chi, G. Chen, Extraction of electrochemiluminescent oxidized carbon quantum dots from activated carbon. Chem. Mater. 22(21), 5895–5899 (2010). doi:10.​1021/​cm1018844 CrossRef
45.
Y. Dong, C. Chen, X. Zheng, L. Gao, Z. Cui, H. Yang, C. Guo, Y. Chi, C.M. Li, One-step and high yield simultaneous preparation of single- and multi-layer graphene quantum dots from CX-72 carbon black. J Mater Chem C 22(18), 8764–8766 (2012). doi:10.​1039/​c2jm30658a CrossRef
46.
Y. Dong, J. Lin, Y. Chen, F. Fu, Y. Chi, G. Chen, Graphene quantum dots, graphene oxide, carbon quantum dots and graphite nanocrystals in coals. Nanoscale 6(13), 7410–7415 (2014). doi:10.​1039/​c4nr01482k CrossRef
47.
Z.A. Qiao, Y. Wang, Y. Gao, H. Li, T. Dai, Y. Liu, Q. Huo, Commercially activated carbon as the source for producing multicolor photoluminescent carbon dots by chemical oxidation. Chem. Commun. 46(46), 8812–8814 (2010). doi:10.​1039/​c0cc02724c CrossRef
48.
Y. Dong, C.X. Guo, Y. Chi, C.M. Li, Reply to comment on “one-step and high yield simultaneous preparation of single- and multi-layer graphene quantum dots from CX-72 carbon black”. J. Mater. Chem. 22(40), 21777–21778 (2012). doi:10.​1039/​c2jm34130a CrossRef
49.
50.
R. Liu, D. Wu, X. Feng, K. Mullen, Bottom-up fabrication of photoluminescent graphene quantum dots with uniform morphology. J. Am. Chem. Soc. 133(39), 15221–15223 (2011). doi:10.​1021/​ja204953k CrossRef
51.
52.
J. Peng, W. Gao, B.K. Gupta, Z. Liu, R. Romero-Aburto, L. Ge, L. Song, L.B. Alemany, X. Zhan, G. Gao, S.A. Vithayathil, B.A. Kaipparettu, A.A. Marti, T. Hayashi, J.J. Zhu, P.M. Ajayan, Graphene quantum dots derived from carbon fibers. Nano Lett. 12(2), 844–849 (2012). doi:10.​1021/​nl2038979 CrossRef
53.
D.V. Kosynkin, A.L. Higginbotham, A. Sinitskii, J.R. Lomeda, A. Dimiev, B.K. Price, J.M. Tour, Longitudinal unzipping of carbon nanotubes to form graphene nanoribbons. Nature 458(7240), 872–876 (2009). doi:10.​1038/​nature07872 CrossRef
54.
55.
D. Pan, L. Guo, J. Zhang, C. Xi, Q. Xue, H. Huang, J. Li, Z. Zhang, W. Yu, Z. Chen, Z. Li, M. Wu, Cutting sp2 clusters in graphene sheets into colloidal graphene quantum dots with strong green fluorescence. J. Mater. Chem. 22(8), 3314–3318 (2012). doi:10.​1039/​c2jm16005f CrossRef
56.
S. Kim, S.W. Hwang, M.K. Kim, D.Y. Shin, D.H. Shin, C.O. Kim, S.B. Yang, J.H. Park, E. Hwang, S.H. Choi, Anomalous behaviors of visible luminescence from graphene quantum dots: interplay between size and shape. ACS Nano 6(9), 8203–8208 (2012). doi:10.​1021/​nn302878r CrossRef
57.
L.L. Li, J. Ji, R. Fei, C.Z. Wang, Q. Lu, J.R. Zhang, L.P. Jiang, J.J. Zhu, A facile microwave avenue to electrochemiluminescent two-color graphene quantum dots. Adv. Funct. Mater. 22(14), 2971–2979 (2012). doi:10.​1002/​adfm.​201200166 CrossRef
58.
M. Nurunnabi, Z. Khatun, K.M. Huh, S.Y. Park, D.Y. Lee, K.J. Cho, Y.K. Lee, In vivo biodistribution and toxicology of carboxylated graphene quantum dots. ACS Nano 7(8), 6858–6867 (2013). doi:10.​1021/​nn402043c CrossRef
59.
M. Nurunnabi, Z. Khatun, M. Nafiujjaman, D.G. Lee, Y.K. Lee, Surface coating of graphene quantum dots using mussel-inspired polydopamine for biomedical optical imaging. ACS Appl. Mater. Inter. 5(16), 8246–8253 (2013). doi:10.​1021/​am4023863 CrossRef
60.
Z.S. Qian, X.Y. Shan, L.J. Chai, J.J. Ma, J.R. Chen, H. Feng, A universal fluorescence sensing strategy based on biocompatible graphene quantum dots and graphene oxide for the detection of DNA. Nanoscale 6(11), 5671–5674 (2014). doi:10.​1039/​c3nr06583a CrossRef
61.
Y. Sun, S. Wang, C. Li, P. Luo, L. Tao, Y. Wei, G. Shi, Large scale preparation of graphene quantum dots from graphite with tunable fluorescence properties. Phys. Chem. Chem. Phys. 15(24), 9907–9913 (2013). doi:10.​1039/​c3cp50691f CrossRef
62.
R. Ye, C. Xiang, J. Lin, Z. Peng, K. Huang, Z. Yan, N.P. Cook, E.L. Samuel, C.C. Hwang, G. Ruan, G. Ceriotti, A.R. Raji, A.A. Marti, J.M. Tour, Coal as an abundant source of graphene quantum dots. Nat. Commun. 4, 2943 (2013). doi:10.​1038/​ncomms3943
63.
64.
X.J. Zhou, Y. Zhang, C. Wang, X.C. Wu, Y.Q. Yang, B. Zheng, H.X. Wu, S.W. Guo, J.Y. Zhang, Photo-fenton reaction of graphene oxide: a new strategy to prepare graphene quantum dots for DNA cleavage. ACS Nano 6(8), 6592–6599 (2012)CrossRef
65.
K. Ikehata, M.G. EI-Din, Aqueous pesticide degradation by hydrogen peroxide ultraviolet irradiation and Fenton-type advanced oxidation processes: a review. Environ. Eng. Sci. 5(2), 81–135 (2006). doi:10.​1139/​S05-046 CrossRef
66.
J.G. Zhou, C. Booker, R.Y. Li, X.T. Zhou, T.K. Sham, X.L. Sun, Z.F. Ding, An electrochemical avenue to blue luminescent nanocrystals from multiwalled carbon nanotubes (MWCNTs). J. Am. Chem. Soc. 129(4), 744–745 (2007). doi:10.​1021/​ja0669070 CrossRef
67.
Q.L. Zhao, Z.L. Zhang, B.H. Huang, J. Peng, M. Zhang, D.W. Pang, Facile preparation of low cytotoxicity fluorescent carbon nanocrystals by electrooxidation of graphite. Chem. Commun. 41, 5116–5118 (2008). doi:10.​1039/​b812420e CrossRef
68.
L. Zheng, Y. Chi, Y. Dong, J. Lin, B. Wang, Electrochemiluminescence of water-soluble carbon nanocrystals released electrochemically from graphite. J. Am. Chem. Soc. 131(13), 4564–4565 (2009). doi:10.​1021/​ja809073f CrossRef
69.
H. Li, X. He, Z. Kang, H. Huang, Y. Liu, J. Liu, S. Lian, C.H. Tsang, X. Yang, S.T. Lee, Water-soluble fluorescent carbon quantum dots and photocatalyst design. Angew. Chem. Int. Ed. 49(26), 4430–4434 (2010). doi:10.​1002/​anie.​200906154 CrossRef
70.
J. Lu, J.X. Yang, J.Z. Wang, A.L. Lim, S. Wang, K.P. Loh, One-pot synthesis of fluorescent carbon nanoribbons, nanoparticles, and graphene by the exfoliation of graphite in ionic liquids. ACS Nano 3(8), 2367–2375 (2009). doi:10.​1021/​nn900546b CrossRef
71.
Y. Li, Y. Hu, Y. Zhao, G. Shi, L. Deng, Y. Hou, L. Qu, An electrochemical avenue to green-luminescent graphene quantum dots as potential electron-acceptors for photovoltaics. Adv. Mater. 23(6), 776–780 (2011). doi:10.​1002/​adma.​201003819 CrossRef
72.
Y. Li, Y. Zhao, H. Cheng, Y. Hu, G. Shi, L. Dai, L. Qu, Nitrogen-doped graphene quantum dots with oxygen-rich functional groups. J. Am. Chem. Soc. 134(1), 15–18 (2012). doi:10.​1021/​ja206030c CrossRef
73.
L. Bao, Z.L. Zhang, Z.Q. Tian, L. Zhang, C. Liu, Y. Lin, B. Qi, D.W. Pang, Electrochemical tuning of luminescent carbon nanodots: from preparation to luminescence mechanism. Adv. Mater. 23(48), 5801–5806 (2011). doi:10.​1002/​adma.​201102866 CrossRef
74.
M. Zhang, L. Bai, W. Shang, W. Xie, H. Ma, Y. Fu, D. Fang, H. Sun, L. Fan, M. Han, C. Liu, S. Yang, Facile synthesis of water-soluble, highly fluorescent graphene quantum dots as a robust biological label for stem cells. J. Am. Chem. Soc. 22(15), 7461–7467 (2012). doi:10.​1039/​c2jm16835a
75.
76.
D.B. Shinde, V.K. Pillai, Electrochemical preparation of luminescent graphene quantum dots from multiwalled carbon nanotubes. Chem. Eur. J. 18(39), 12522–12528 (2012). doi:10.​1002/​chem.​201201043 CrossRef
77.
D.V. Kosynkin, A.L. Higginboham, A. Sinitskii, J.R. Lomeda, A. Dimiev, B.K. Price, J.M. Tour, Longitudinal unzipping of carbon nanotubes to form graphene nanoribbons. Nature 458(7240), 872–876 (2009). doi:10.​1038/​nature07872 CrossRef
78.
79.
F. Yang, M. Zhao, B. Zheng, D. Xiao, L. Wu, Y. Guo, Influence of pH on the fluorescence properties of graphene quantum dots using ozonation pre-oxide hydrothermal synthesis. J. Mater. Chem. 22(48), 25471–25479 (2012). doi:10.​1039/​c2jm35471c CrossRef
80.
H. Tetsuka, R. Asahi, A. Nagoya, K. Okamoto, I. Tajima, R. Ohta, A. Okamoto, Optically tunable amino-functionalized graphene quantum dots. Adv. Mater. 24(39), 5333–5338 (2012). doi:10.​1002/​adma.​201201930 CrossRef
81.
S. Zhu, J. Zhang, C. Qiao, S. Tang, Y. Li, W. Yuan, B. Li, L. Tian, F. Liu, R. Hu, H. Gao, H. Wei, H. Zhang, H. Sun, B. Yang, Strongly green-photoluminescent graphene quantum dots for bioimaging applications. Chem. Commun. 47(24), 6858–6860 (2011). doi:10.​1039/​c1cc11122a CrossRef
82.
L. Lin, S. Zhang, Creating high yield water soluble luminescent graphene quantum dots via exfoliating and disintegrating carbon nanotubes and graphite flakes. Chem. Commun. 48(82), 10177–10179 (2012). doi:10.​1039/​c2cc35559k CrossRef
83.
X. Zhu, H. Wang, Q. Jiao, X. Xiao, X. Zuo, Y. Liang, J. Nan, J. Wang, L. Wang, Preparation and characterization of the fluorescent carbon dots derived from the lithium-Intercalated graphite used for cell Imaging. Part. Part. Syst. Char. 31(7), 771–777 (2014). doi:10.​1002/​ppsc.​201300327 CrossRef
84.
J. Lee, K. Kim, W.I. Park, B.H. Kim, J.H. Park, T.H. Kim, S. Bong, C.H. Kim, G. Chae, M. Jun, Y. Hwang, Y.S. Jung, S. Jeon, Uniform graphene quantum dots patterned from self-assembled silica nanodots. Nano Lett. 12(12), 6078–6083 (2012). doi:10.​1021/​nl302520m CrossRef
85.
86.
87.
Y. Dong, H. Pang, H.B. Yang, C. Guo, J. Shao, Y. Chi, C.M. Li, T. Yu, Carbon-based dots co-doped with nitrogen and sulfur for high quantum yield and excitation-independent emission. Angew. Chem. Int. Ed. 52(30), 7800–7804 (2013). doi:10.​1002/​anie.​201301114 CrossRef
88.
S. Zhu, Q. Meng, L. Wang, J. Zhang, Y. Song, H. Jin, K. Zhang, H. Sun, H. Wang, B. Yang, Highly photoluminescent carbon dots for multicolor patterning, sensors, and bioimaging. Angew. Chem. Int. Ed. 52(14), 3953–3957 (2013). doi:10.​1002/​anie.​201300519 CrossRef
89.
M.J. Krysmann, A. Kelarakis, P. Dallas, E.P. Giannelis, Formation mechanism of carbogenic nanoparticles with dual photoluminescence emission. J. Am. Chem. Soc. 134(2), 747–750 (2012). doi:10.​1021/​ja204661r CrossRef
90.
D. Qu, M. Zheng, P. Du, Y. Zhou, L. Zhang, D. Li, H. Tan, Z. Zhao, Z. Xie, Z. Sun, Highly luminescent S, N co-doped graphene quantum dots with broad visible absorption bands for visible light photocatalysts. Nanoscale 5(24), 12272–12277 (2013). doi:10.​1039/​c3nr04402e CrossRef
91.
H. Zhang, Y. Chen, M. Liang, L. Xu, S. Qi, H. Chen, X. Chen, Solid-phase synthesis of highly fluorescent nitrogen-doped carbon dots for sensitive and selective probing ferric ions in living cells. Anal. Chem. 86(19), 9846–9852 (2014). doi:10.​1021/​ac502446m CrossRef
92.
M. Amjadi, J.L. Manzoori, T. Hallaj, M.H. Sorouraddin, Direct chemiluminescence of carbon dots induced by potassium ferricyanide and its analytical application. Spectrochimi. Acta A 122, 715–720 (2014). doi:10.​1016/​j.​saa.​2013.​11.​097 CrossRef
93.
94.
K. Qu, J. Wang, J. Ren, X. Qu, Carbon dots prepared by hydrothermal treatment of dopamine as an effective fluorescent sensing platform for the label-free detection of iron(III) ions and dopamine. Chem. Eur. J. 19(22), 7243–7249 (2013). doi:10.​1002/​chem.​20130004295 CrossRef
95.
P. Shen, Y. Xia, Synthesis-modification integration: one-step fabrication of boronic acid functionalized carbon dots for fluorescent blood sugar sensing. Anal. Chem. 86(11), 5323–5329 (2014). doi:10.​1021/​ac5001338 CrossRef
96.
97.
Z. Qian, J. Ma, X. Shan, H. Feng, L. Shao, J. Chen, Highly luminescent N-doped carbon quantum dots as an effective multifunctional fluorescence sensing platform. Chem. Eur. J. 20(8), 2254–2263 (2014). doi:10.​1002/​chem.​201304374 CrossRef
98.
99.
100.
A. Sachdev, I. Matai, P. Gopinath, Implications of surface passivation on physicochemical and bioimaging properties of carbon dots. RSC Adv. 4(40), 20915 (2014). doi:10.​1039/​c4ra02017k CrossRef
101.
102.
L. Wang, H.S. Zhou, Green synthesis of luminescent nitrogen-doped carbon dots from milk and its imaging application. Anal. Chem. 86(18), 8902–8905 (2014). doi:10.​1021/​ac502646x CrossRef
103.
Z. Qian, X. Shan, L. Chai, J. Ma, J. Chen, H. Feng, Si-doped carbon quantum dots: a facile and general preparation strategy, bioimaging application, and multifunctional sensor. ACS Appl. Mater. Inter. 6(9), 6797–6805 (2014). doi:10.​1021/​am500403n CrossRef
104.
105.
106.
107.
S. Sahu, B. Behera, T.K. Maiti, S. Mohapatra, Simple one-step synthesis of highly luminescent carbon dots from orange juice: application as excellent bio-imaging agents. Chem. Commun. 48(70), 8835–8837 (2012). doi:10.​1039/​c2cc33796g CrossRef
108.
W. Wang, Y.C. Lu, H. Huang, J.J. Feng, J.R. Chen, A.J. Wang, Facile synthesis of water-soluble and biocompatible fluorescent nitrogen-doped carbon dots for cell imaging. Analyst 139(7), 1692–1696 (2014). doi:10.​1039/​c3an02098c CrossRef
109.
Z.C. Yang, M. Wang, A.M. Yong, S.Y. Wong, X.H. Zhang, H. Tan, A.Y. Chang, X. Li, J. Wang, Intrinsically fluorescent carbon dots with tunable emission derived from hydrothermal treatment of glucose in the presence of monopotassium phosphate. Chem. Commun. 47(42), 11615–11617 (2011). doi:10.​1039/​c1cc14860e CrossRef
110.
111.
O. Kozák, K.K.R. Datta, M. Greplová, V. Ranc, J. Kašlík, R. Zbořil, Surfactant-derived amphiphilic carbon dots with tunable photoluminescence. J. Phys. Chem. C 117(47), 24991–24996 (2013). doi:10.​1021/​jp4040166 CrossRef
112.
Z.C. Liang, L. Zeng, X.D. Cao, Q. Wang, X.H. Wang, R.C. Sun, Sustainable carbon quantum dots from forestry and agricultural biomass with amplified photoluminescence by simple NH4OH passivation. J. Mater. Chem. C 2, 9760–9766. (2014). doi:10.​1039/​C4TC01714E
113.
P.C. Hsu, H.T. Chang, Synthesis of high-quality carbon nanodots from hydrophilic compounds: role of functional groups. Chem. Commun. 48(33), 3984–3986 (2012). doi:10.​1039/​c2cc30188a CrossRef
114.
X.M. Li, S.P. Lau, L.B. Tang, R.B. Ji, P.Z. Yang, Multicolour light emission from chlorine-doped graphene quantum dots. J. Mater. Chem. C 1, 7308–7313 (2014). doi:10.​1039/​C3TC31473A CrossRef
115.
Y. Xu, C.J. Tang, H. Huang, C.Q. Sun, Y.K. Zhang, Q.F. Ye, A.J. Wang, Green synthesis of fluorescent carbon quantum dots for detection of Hg2+. Chine. J. Anal. Chem. 42(9), 1252–1258 (2014). doi:10.​1016/​s1872-2040(14)60765-9 CrossRef
116.
Y. Dong, J. Shao, C. Chen, H. Li, R. Wang, Y. Chi, X. Lin, G. Chen, Blue luminescent graphene quantum dots and graphene oxide prepared by tuning the carbonization degree of citric acid. Carbon 50(12), 4738–4743 (2012). doi:10.​1016/​j.​carbon.​2012.​06.​002 CrossRef
117.
118.
X. Teng, C. Ma, C. Ge, M. Yan, J. Yang, Y. Zhang, P.C. Morais, H. Bi, Green synthesis of nitrogen-doped carbon dots from konjac flour with “off–on” fluorescence by Fe3+ and l-lysine for bioimaging. J. Mater. Chem. B 2(29), 4631–4639 (2014). doi:10.​1039/​c4tb00368c CrossRef
119.
P.Y. Lin, C.W. Hsieh, M.L. Kung, L.Y. Chu, H.J. Huang, H.T. Chen, D.C. Wu, C.H. Kuo, S.L. Hsieh, S. Hsieh, Eco-friendly synthesis of shrimp egg-derived carbon dots for fluorescent bioimaging. J. Biotechnol. 189, 114–119 (2014). doi:10.​1016/​j.​jbiotec.​2014.​08.​043 CrossRef
120.
121.
Y. Xu, M. Wu, X.Z. Feng, X.B. Yin, X.W. He, Y.K. Zhang, Reduced carbon dots versus oxidized carbon dots: photo- and electrochemiluminescence investigations for selected applications. Chem. Eur. J. 19(20), 6282–6288 (2013). doi:10.​1002/​chem.​201204372 CrossRef
122.
K. Hola, A.B. Bourlinos, O. Kozak, K. Berka, K.M. Siskova, M. Havrdova, J. Tucek, K. Safarova, M. Otyepka, E.P. Giannelis, R. Zboril, Photoluminescence effects of graphitic core size and surface functional groups in carbon dots: COO− induced red-shift emission. Carbon 70, 279–286 (2014). doi:10.​1016/​j.​carbon.​2014.​01.​008 CrossRef
123.
J. Niu, H. Gao, L. Wang, S. Xin, G. Zhang, Q. Wang, L. Guo, W. Liu, X. Gao, Y. Wang, Facile synthesis and optical properties of nitrogen-doped carbon dots. New J. Chem. 38(4), 1522–1527 (2014). doi:10.​1039/​c3nj01068f CrossRef
124.
J. Wei, J. Shen, X. Zhang, S. Guo, J. Pan, X. Hou, H. Zhang, L. Wang, B. Feng, Simple one-step synthesis of water-soluble fluorescent carbon dots derived from paper ash. RSC Adv. 3(32), 13119–13122 (2013). doi:10.​1039/​c3ra41751d CrossRef
125.
J. Wang, C.F. Wang, S. Chen, Amphiphilic egg-derived carbon dots: rapid plasma fabrication, pyrolysis process, and multicolor printing patterns. Angew. Chem. Int. Ed. 51(37), 9297–9301 (2012). doi:10.​1002/​anie CrossRef
126.
127.
X. Dong, Y. Su, H. Geng, Z. Li, C. Yang, X. Li, Y. Zhang, Fast one-step synthesis of N-doped carbon dots by pyrolyzing ethanolamine. J. Mater. Chem. C 2(36), 7477–7481 (2014). doi:10.​1039/​c4tc01139b CrossRef
128.
Z. Jiang, A. Nolan, J.G. Walton, A. Lilienkampf, R. Zhang, M. Bradley, Photoluminescent carbon dots from 1,4-addition polymers. Chem. Eur. J. 20(35), 10926–10931 (2014). doi:10.​1002/​chem.​201403076 CrossRef
129.
D. Pan, J. Zhang, Z. Li, C. Wu, X. Yan, M. Wu, Observation of pH-, solvent-, spin-, and excitation-dependent blue photoluminescence from carbon nanoparticles. Chem. Commun. 46(21), 3681–3683 (2010). doi:10.​1039/​c000114g CrossRef
130.
F. Wang, M. Kreiter, B. He, S. Pang, C.Y. Liu, Synthesis of direct white-light emitting carbogenic quantum dots. Chem. Commun. 46(19), 3309–3311 (2010). doi:10.​1039/​c002206c CrossRef
131.
X. Guo, C.F. Wang, Z.Y. Yu, L. Chen, S. Chen, Facile access to versatile fluorescent carbon dots toward light-emitting diodes. Chem. Commun. 48(21), 2692–2694 (2012). doi:10.​1039/​c2cc17769b CrossRef
132.
H. Zhu, X. Wang, Y. Li, Z. Wang, F. Yang, X. Yang, Microwave synthesis of fluorescent carbon nanoparticles with electrochemiluminescence properties. Chem. Commun. 34, 5118–5120 (2009). doi:10.​1039/​b907612c CrossRef
133.
X. Wang, K. Qu, B. Xu, J. Ren, X. Qu, Microwave assisted one-step green synthesis of cell-permeable multicolor photoluminescent carbon dots without surface passivation reagents. J. Mater. Chem. 21(8), 2445–2450 (2011). doi:10.​1039/​c0jm02963g CrossRef
134.
X. Zhai, P. Zhang, C. Liu, T. Bai, W. Li, L. Dai, W. Liu, Highly luminescent carbon nanodots by microwave-assisted pyrolysis. Chem. Commun. 48(64), 7955–7957 (2012). doi:10.​1039/​c2cc33869f CrossRef
135.
Z. Lin, W. Xue, H. Chen, J.M. Lin, Peroxynitrous-acid-induced chemiluminescence of fluorescent carbon dots for nitrite sensing. Anal. Chem. 83(21), 8245–8251 (2011). doi:10.​1021/​ac202039h CrossRef
136.
A. Salinas-Castillo, M. Ariza-Avidad, C. Pritz, M. Camprubi-Robles, B. Fernandez, M.J. Ruedas-Rama, A. Megia-Fernandez, A. Lapresta-Fernandez, F. Santoyo-Gonzalez, A. Schrott-Fischer, L.F. Capitan-Vallvey, Carbon dots for copper detection with down and upconversion fluorescent properties as excitation sources. Chem. Commun. 49(11), 1103–1105 (2013). doi:10.​1039/​c2cc36450f CrossRef
137.
A. Zhao, C. Zhao, M. Li, J. Ren, X. Qu, Ionic liquids as precursors for highly luminescent, surface-different nitrogen-doped carbon dots used for label-free detection of Cu2+/Fe3+ and cell imaging. Anal. Chem. Acta 809, 128–133 (2014). doi:10.​1016/​j.​aca.​2013.​10.​046 CrossRef
138.
Y. Zhai, Z. Zhu, C. Zhu, J. Ren, E. Wang, S. Dong, Multifunctional water-soluble luminescent carbon dots for imaging and Hg2+ sensing. J. Mater. Chem. B 2(40), 6995–6999 (2014). doi:10.​1039/​c4tb01035c CrossRef
139.
140.
W. Wang, Y. Li, L. Cheng, Z. Cao, W. Liu, Water-soluble and phosphorus-containing carbon dots with strong green fluorescence for cell labeling. J. Mater. Chem. B 2(1), 46–48 (2014). doi:10.​1039/​c3tb21370f CrossRef
141.
Y.F. Huang, X. Zhou, R. Zhou, H. Zhang, K.B. Kang, M. Zhao, Y. Peng, Q. Wang, H.L. Zhang, W.Y. Qiu, One-pot synthesis of highly luminescent carbon quantum dots and their nontoxic ingestion by zebrafish for in vivo imaging. Chem. Eur. J. 20(19), 5640–5648 (2014). doi:10.​1002/​chem.​201400011 CrossRef
142.
C. Liu, P. Zhang, X. Zhai, F. Tian, W. Li, J. Yang, Y. Liu, H. Wang, W. Wang, W. Liu, Nano-carrier for gene delivery and bioimaging based on carbon dots with PEI-passivation enhanced fluorescence. Biomaterials 33(13), 3604–3613 (2012). doi:10.​1016/​j.​biomaterials.​2012.​01.​052 CrossRef
143.
J. Gong, X. An, X. Yan, A novel rapid and green synthesis of highly luminescent carbon dots with good biocompatibility for cell imaging. New J. Chem. 38(4), 1376–1379 (2014). doi:10.​1039/​c3nj01320k CrossRef
144.
Q. Liu, S. Xu, C. Niu, M. Li, D. He, Z. Lu, L. Ma, N. Na, F. Huang, H. Jiang, J. Ouyang, Distinguish cancer cells based on targeting turn-on fluorescence imaging by folate functionalized green emitting carbon dots. Biosens. Bioelectron. 64, 119–125 (2015). doi:10.​1016/​j.​bios.​2014.​08.​052 CrossRef
145.
J. Wang, C. Cheng, Y. Huang, B. Zheng, H. Yuan, L. Bo, M.-W. Zheng, S.-Y. Yang, Y. Guo, D. Xiao, A facile large-scale microwave synthesis of highly fluorescent carbon dots from benzenediol isomers. J. Mater. Chem. C 2(25), 5028–5035 (2014). doi:10.​1039/​c3tc32131b CrossRef
146.
S. Liu, L. Wang, J. Tian, J. Zhai, Y. Luo, W. Lu, X. Sun, Acid-driven, microwave-assisted production of photoluminescent carbon nitride dots from N. N-dimethylformamide. RSC Adv. 1(6), 951–953 (2011). doi:10.​1039/​c1ra00249j CrossRef
147.
C. Liu, P. Zhang, F. Tian, W. Li, F. Li, W. Liu, One-step synthesis of surface passivated carbon nanodots by microwave assisted pyrolysis for enhanced multicolor photoluminescence and bioimaging. J. Mater. Chem. 21(35), 13163–13167 (2011). doi:10.​1039/​c1jm12744f CrossRef
148.
R.J. Libin Tang, Xiangke Cao, Jingyu Lin, Hongxing Jiang, Xueming Li, Kar Seng Teng, Chi Man Luk, Songjun Zeng, Jianhua Hao, Shu Ping Lau, Deep ultraviolet photoluminescence of water-soluble self-passivated graphene quantum dots. ACS Nano 6, 5102–5110 (2012). doi:10.​1021/​nn300760g CrossRef
149.
L.B. Tang, R.B. Ji, X.M. Li, G.X. Bai, C.P. Liu, J.H. Hao, J.Y. Lin, H.X. Jiang, K.S. Teng, Z.B. Yang, Deep ultraviolet to near-infrared emission and photoresponse in layered N-doped graphene quantum dots. ACS Nano 8(6), 6312–6320 (2014). doi:10.​1021/​nn501796r CrossRef
150.
R. Liu, D. Wu, S. Liu, K. Koynov, W. Knoll, Q. Li, An aqueous route to multicolor photoluminescent carbon dots using silica spheres as carriers. Angew. Chem. Int. Ed. 48(25), 4598–4601 (2009). doi:10.​1002/​anie.​200900652 CrossRef
151.
J. Zong, Y. Zhu, X. Yang, J. Shen, C. Li, Synthesis of photoluminescent carbogenic dots using mesoporous silica spheres as nanoreactors. Chem. Commun. (Camb.) 47(2), 764–766 (2011). doi:10.​1039/​c0cc03092a CrossRef
152.
J. Zong, X. Yang, A. Trinchi, S. Hardin, I. Cole, Y. Zhu, C. Li, T. Muster, G. Wei, Carbon dots as fluorescent probes for “off-on” detection of Cu2+ and L-cysteine in aqueous solution. Biosens. Bioelectron. 51, 330–335 (2014). doi:10.​1016/​j.​bios.​2013.​07.​042 CrossRef
153.
S. Liu, J. Tian, L. Wang, Y. Luo, J. Zhai, X. Sun, Preparation of photoluminescent carbon nitride dots from CCl4 and 1,2-ethylenediamine: a heat-treatment-based strategy. J. Mater. Chem. 21(32), 11726–11729 (2011). doi:10.​1039/​c1jm12149a CrossRef
154.
E.J. Goh, K.S. Kim, Y.R. Kim, H.S. Jung, S. Beack, W.H. Kong, G. Scarcelli, S.H. Yun, S.K. Hahn, Bioimaging of hyaluronic acid derivatives using nanosized carbon dots. Biomacromolecules 13(8), 2554–2561 (2012). doi:10.​1021/​bm300796q CrossRef
155.
156.
H. Nie, M. Li, Q. Li, S. Liang, Y. Tan, L. Sheng, W. Shi, S.X.-A. Zhang, Carbon dots with continuously tunable full-color emission and their application in ratiometric pH sensing. Chem. Mater. 26(10), 3104–3112 (2014). doi:10.​1021/​cm5003669 CrossRef
157.
W. Kong, R. Liu, H. Li, J. Liu, H. Huang, Y. Liu, Z. Kang, High-bright fluorescent carbon dots and their application in selective nucleoli staining. J. Mater. Chem. B 2(31), 5077–5082 (2014). doi:10.​1039/​c4tb00579a CrossRef
158.
C.-W. Lai, Y.-H. Hsiao, Y.-K. Peng, P.-T. Chou, Facile synthesis of highly emissive carbon dots from pyrolysis of glycerol; gram scale production of carbon dots/mSiO2 for cell imaging and drug release. J. Mater. Chem. 22(29), 14403–14409 (2012). doi:10.​1039/​c2jm32206d CrossRef
159.
160.
161.
X. Yan, B. Li, X. Cui, Q. Wei, K. Tajima, Li L-s, Independent tuning of the band gap and redox potential of graphene quantum dots. J. Phys. Chem. Lett. 2(10), 1119–1124 (2011). doi:10.​1021/​jz200450r CrossRef
162.
X. Yan, X. Cui, B. Li, L.S. Li, Large, solution-processable graphene quantum dots as light absorbers for photovoltaics. Nano Lett. 10(5), 1869–1873 (2010). doi:10.​1021/​nl101060h CrossRef
163.
164.
X.C. Xin Yan, Liang-shi Li, Synthesis of large, stable colloidal graphene quantum dots with tunable size. J. Am. Chem. Soc. 132, 5944–5945 (2010). doi:10.​1021/​ja1009376 CrossRef
165.
M.L. Mueller, X. Yan, J.A. McGuire, L.S. Li, Triplet states and electronic relaxation in photoexcited graphene quantum dots. Nano Lett. 10(7), 2679–2682 (2010). doi:10.​1021/​nl101474d CrossRef
166.
J. Zhang, W. Shen, D. Pan, Z. Zhang, Y. Fang, M. Wu, Controlled synthesis of green and blue luminescent carbon nanoparticles with high yields by the carbonization of sucrose. New J. Chem. 34(4), 591–593 (2010). doi:10.​1039/​b9nj00662a CrossRef
167.
168.
Y. Dong, H. Pang, H. Yang, J. Jiang, Y. Chi, T. Yu, Nitrogen-doped carbon-based dots prepared by dehydrating EDTA with hot sulfuric acid and their electrocatalysis for oxygen reduction reaction. RSC Adv. 4(62), 32791–32795 (2014). doi:10.​1039/​c4ra06594h CrossRef
169.
170.
D. Sun, R. Ban, P.-H. Zhang, G.-H. Wu, J.-R. Zhang, J.-J. Zhu, Hair fiber as a precursor for synthesizing of sulfur- and nitrogen-co-doped carbon dots with tunable luminescence properties. Carbon 64, 424–434 (2013). doi:10.​1016/​j.​carbon.​2013.​07.​095 CrossRef
171.
J.S. Suh JKa, Size-controllable and low-cost fabrication of graphene quantum dots using thermal plasma jet. ACS Nano 8, 4190–4196 (2014)CrossRef
172.
173.
174.
Z. Ma, H. Ming, H. Huang, Y. Liu, Z. Kang, One-step ultrasonic synthesis of fluorescent N-doped carbon dots from glucose and their visible-light sensitive photocatalytic ability. New J. Chem. 36(4), 861–864 (2012). doi:10.​1039/​c2nj20942j CrossRef
175.
Y. Fang, S. Guo, D. Li, C. Zhu, W. Ren, S. Dong, E. Wang, Easy synthesis and imaging applications of cross-linked green fluorescent hollow carbon nanoparticles. ACS Nano 6, 400–409 (2012). doi:10.​1021/​nn2046373 CrossRef
176.
177.
J. Shen, Y. Zhu, X. Yang, J. Zong, J. Zhang, C. Li, One-pot hydrothermal synthesis of graphene quantum dots surface-passivated by polyethylene glycol and their photoelectric conversion under near-infrared light. New J. Chem. 36(1), 97–101 (2012). doi:10.​1039/​c1nj20658c
178.
H. Peng, J. Travas-Sejdic, Simple aqueous solution route to luminescent carbogenic dots from carbohydrates. Chem. Mater. 21(23), 5563–5565 (2009). doi:10.​1021/​cm901593y CrossRef
179.
180.
H. Sun, L. Wu, N. Gao, J. Ren, X. Qu, Improvement of photoluminescence of graphene quantum dots with a biocompatible photochemical reduction pathway and its bioimaging application. ACS Appl. Mater. Interfaces 5(3), 1174–1179 (2013). doi:10.​1021/​am3030849 CrossRef
181.
G.S. Kumar, R. Roy, D. Sen, U.K. Ghorai, R. Thapa, N. Mazumder, S. Saha, K.K. Chattopadhyay, Amino-functionalized graphene quantum dots: origin of tunable heterogeneous photoluminescence. Nanoscale 6(6), 3384–3391 (2014). doi:10.​1039/​c3nr05376h CrossRef
182.
S.H. Jin, D.H. Kim, G.H. Jun, S.H. Hong, S. Jeon, Tuning the photoluminescence of graphene quantum dots through the charge transfer effect of functional groups. ACS Nano 7(2), 1239–1245 (2012). doi:10.​1021/​nn3046759 CrossRef
183.
184.
H. Zheng, Q. Wang, Y. Long, H. Zhang, X. Huang, R. Zhu, Enhancing the luminescence of carbon dots with a reduction pathway. Chem. Commun. 47(38), 10650–10652 (2011). doi:10.​1039/​c1cc14741b CrossRef
185.
186.
G. Eda, Y.Y. Lin, C. Mattevi, H. Yamaguchi, H.A. Chen, I.S. Chen, C.W. Chen, M. Chhowalla, Blue photoluminescence from chemically derived graphene oxide. Adv. Mater. 22(4), 505–509 (2010). doi:10.​1002/​adma.​200901996 CrossRef
187.
K.P. Loh, Q. Bao, G. Eda, M. Chhowalla, Graphene oxide as a chemically tunable platform for optical applications. Nat. Chem. 2(12), 1015–1024 (2010). doi:10.​1038/​nchem.​907 CrossRef
188.
189.
190.
M. Li, W. Wu, W. Ren, H.-M. Cheng, N. Tang, W. Zhong, Y. Du, Synthesis and upconversion luminescence of N-doped graphene quantum dots. Appl. Phys. Lett. 101(10), 103107 (2012). doi:10.​1063/​1.​4750065 CrossRef
191.
X. Wang, L. Cao, S.T. Yang, F. Lu, M.J. Meziani, L. Tian, K.W. Sun, M.A. Bloodgood, Y.P. Sun, Bandgap-like strong fluorescence in functionalized carbon nanoparticles. Angew. Chem. Int. Ed. 49(31), 5310–5314 (2010). doi:10.​1002/​anie.​201000982 CrossRef
192.
P. Anilkumar, X. Wang, L. Cao, S. Sahu, J.H. Liu, P. Wang, K. Korch, K.N. Tackett 2nd, A. Parenzan, Y.P. Sun, Toward quantitatively fluorescent carbon-based “quantum” dots. Nanoscale 3(5), 2023–2027 (2011). doi:10.​1039/​c0nr00962h CrossRef
193.
Y.P. Sun, X. Wang, F.S. Lu, L. Cao, M.J. Meziani, P.J.G. Luo, L.R. Gu, L.M. Veca, Doped carbon nanoparticles as a new platform for highly photoluminescent dots. J. Phys. Chem. C 112(47), 18295–18298 (2008). doi:10.​1021/​jp8076485 CrossRef
194.
A. Cayuela, M.L. Soriano, M. Valcarcel, Strong luminescence of carbon dots induced by acetone passivation: efficient sensor for a rapid analysis of two different pollutants. Anal. Chim. Acta 804, 246–251 (2013). doi:10.​1016/​j.​aca.​2013.​10.​031 CrossRef
195.
S. Zhu, J. Zhang, S. Tang, C. Qiao, L. Wang, H. Wang, X. Liu, B. Li, Y. Li, W. Yu, X. Wang, H. Sun, B. Yang, Surface chemistry routes to modulate the photoluminescence of graphene quantum dots: from fluorescence mechanism to up-conversion bioimaging applications. Adv. Func. Mater. 22(22), 4732–4740 (2012). doi:10.​1002/​adfm.​201201499 CrossRef
196.
Y. Dong, R. Dai, T. Dong, Y. Chi, G. Chen, Photoluminescence, chemiluminescence and anodic electrochemiluminescence of hydrazide-modified graphene quantum dots. Nanoscale 6(19), 11240–11245 (2014). doi:10.​1039/​c4nr02539c CrossRef
197.
Q. Liu, B. Guo, Z. Rao, B. Zhang, J.R. Gong, Strong two-photon-induced fluorescence from photostable, biocompatible nitrogen-doped graphene quantum dots for cellular and deep-tissue imaging. Nano Lett. 13(6), 2436–2441 (2013). doi:10.​1021/​nl400368v CrossRef
198.
C. Hu, Y. Liu, Y. Yang, J. Cui, Z. Huang, Y. Wang, L. Yang, H. Wang, Y. Xiao, J. Rong, One-step preparation of nitrogen-doped graphene quantum dots from oxidized debris of graphene oxide. J. Mater. Chem. B 1(1), 39–42 (2013). doi:10.​1039/​c2tb00189f CrossRef
199.
X.-M. Wei, Y. Xu, Y.-H. Li, X.-B. Yin, X.-W. He, Ultrafast synthesis of nitrogen-doped carbon dots via neutralization heat for bioimaging and sensing applications. RSC Adv. 4(84), 44504–44508 (2014). doi:10.​1039/​c4ra08523j CrossRef
200.
L. Tang, R. Ji, X. Li, K.S. Teng, S.P. Lau, Energy-level structure of nitrogen-doped graphene quantum dots. J. Mater. Chem. C 1(32), 4908–4915 (2013). doi:10.​1039/​c3tc30877d CrossRef
201.
Q.-Q. Shi, Y.-H. Li, Y. Xu, Y. Wang, X.-B. Yin, X.-W. He, Y.-K. Zhang, High-yield and high-solubility nitrogen-doped carbon dots: formation, fluorescence mechanism and imaging application. RSC Adv. 4(4), 1563–1566 (2014). doi:10.​1039/​c3ra45762a CrossRef
202.
J. Shen, Y. Zhu, X. Yang, J. Zong, J. Zhang, C. Li, One-pot hydrothermal synthesis of graphene quantum dots surface-passivated by polyethylene glycol and their photoelectric conversion under near-infrared light. New J. Chem. 36(1), 97–101 (2012). doi:10.​1039/​c1nj20658c CrossRef
203.
S.J. Zhuo, M.W. Shao, S.T. Lee, Upconversion and downconversion fluorescent graphene quantum dots: ultrasonic preparation and photocatalysis. ACS Nano 6(2), 1059–1064 (2012). doi:10.​1021/​nn2040395 CrossRef
204.
S. Zhu, J. Zhang, X. Liu, B. Li, X. Wang, S. Tang, Q. Meng, Y. Li, C. Shi, R. Hu, B. Yang, Graphene quantum dots with controllable surface oxidation, tunable fluorescence and up-conversion emission. RSC Adv. 2(7), 2717–2720 (2012). doi:10.​1039/​c2ra20182h CrossRef
205.
Y. Su, M. Xie, X. Lu, H. Wei, H. Geng, Z. Yang, Y. Zhang, Facile synthesis and photoelectric properties of carbon dots with upconversion fluorescence using arc-synthesized carbon by-products. RSC Adv. 4(10), 4839–4842 (2014). doi:10.​1039/​c3ra45453c CrossRef
206.
D.Z. Tan, S.F. Zhou, J.R. Qiu, Comment on “upconversion and downconversion fluorescent graphene quantum dots: ultrasonic preparation and photocatalysis”. ACS Nano 6(8), 6530–6531 (2012). doi:10.​1021/​nn3016822 CrossRef
207.
208.
209.
Z. Ding, B.M. Quinn, S.K. Haram, L.E. Pell, B.A. Korgel, A.J. Bard, Electrochemistry and electrogenerated chemiluminescence from silicon nanocrystal quantum dots. Science 296(5571), 1293–1297 (2002). doi:10.​1126/​science.​1069336 CrossRef
210.
Y. Bae, N. Myung, A.J. Bard, Electrochemistry and electrogenerated chemiluminescence of CdTe nanoparticles. Nano Lett. 4(6), 1153–1161 (2004). doi:10.​1021/​nl049516x CrossRef
211.
Y. Dong, W. Tian, S. Ren, R. Dai, Y. Chi, G. Chen, Graphene quantum dots/L-cysteine coreactant electrochemiluminescence system and its application in sensing lead(II) ions. ACS Appl. Mater. Interface 6(3), 1646–1651 (2014). doi:10.​1021/​am404552s CrossRef
212.
213.
T.T. Zhang, H.M. Zhao, X.F. Fan, S. Chen, X. Quan, Electrochemiluminescence immunosensor for highly sensitive detection of 8-hydroxy-2′-deoxyguanosine based on carbon quantum dot coated Au/SiO2 core-shell nanoparticles. Talanta 131, 379–385 (2015). doi:10.​1016/​j.​talanta.​2014.​08.​024 CrossRef
214.
M. Zhang, H. Liu, L. Chen, M. Yan, L. Ge, S. Ge, J. Yu, A disposable electrochemiluminescence device for ultrasensitive monitoring of K562 leukemia cells based on aptamers and ZnO@carbon quantum dots. Biosens. Bioelectron. 49, 79–85 (2013). doi:10.​1016/​j.​bios.​2013.​05.​003 CrossRef
215.
S. Yang, J. Liang, S. Luo, C. Liu, Y. Tang, Supersensitive detection of chlorinated phenols by multiple amplification electrochemiluminescence sensing based on carbon quantum dots/graphene. Anal. Chem. 85(16), 7720–7725 (2013). doi:10.​1021/​ac400874h CrossRef
216.
M. Su, H. Liu, L. Ge, Y. Wang, S. Ge, J. Yu, M. Yan, Aptamer-Based electrochemiluminescent detection of MCF-7 cancer cells based on carbon quantum dots coated mesoporous silica nanoparticles. Electrochim. Acta 146, 262–269 (2014). doi:10.​1016/​j.​electacta.​2014.​08.​129 CrossRef
217.
Q. Lu, W. Wei, Z. Zhou, Z. Zhou, Y. Zhang, S. Liu, Electrochemiluminescence resonance energy transfer between graphene quantum dots and gold nanoparticles for DNA damage detection. Analyst 139(10), 2404–2410 (2014). doi:10.​1039/​c4an00020j CrossRef
218.
J. Lu, M. Yan, L. Ge, S. Ge, S. Wang, J. Yan, J. Yu, Electrochemiluminescence of blue-luminescent graphene quantum dots and its application in ultrasensitive aptasensor for adenosine triphosphate detection. Biosens. Bioelectron. 47, 271–277 (2013). doi:10.​1016/​j.​bios.​2013.​03.​039 CrossRef
219.
220.
W. Xue, Z. Lin, H. Chen, C. Lu, J.-M. Lin, Enhancement of ultraweak chemiluminescence from reaction of hydrogen peroxide and bisulfite by water-soluble carbon nanodots. J. Phys. Chem. C 115(44), 21707–21714 (2011). doi:10.​1021/​jp207554t CrossRef
221.
Z. Lin, W. Xue, H. Chen, J.M. Lin, Classical oxidant induced chemiluminescence of fluorescent carbon dots. Chem. Commun. 48(7), 1051–1053 (2012). doi:10.​1039/​c1cc15290d CrossRef
222.
L. Zhao, F. Di, D. Wang, L.H. Guo, Y. Yang, B. Wan, H. Zhang, Chemiluminescence of carbon dots under strong alkaline solutions: a novel insight into carbon dot optical properties. Nanoscale 5(7), 2655–2658 (2013). doi:10.​1039/​c3nr00358b CrossRef
223.
H. Gonçalves, P.A.S. Jorge, J.R.A. Fernandes, J.C.G. Esteves da Silva, Hg(II) sensing based on functionalized carbon dots obtained by direct laser ablation. Sensor. Actuat. B-Chem. 145(2), 702–707 (2010). doi:10.​1016/​j.​snb.​2010.​01.​031 CrossRef
224.
225.
B. Cao, C. Yuan, B. Liu, C. Jiang, G. Guan, M.Y. Han, Ratiometric fluorescence detection of mercuric ion based on the nanohybrid of fluorescence carbon dots and quantum dots. Anal. Chim. Acta 786, 146–152 (2013). doi:10.​1016/​j.​aca.​2013.​05.​015 CrossRef
226.
W. Wang, T. Kim, Z. Yan, G. Zhu, I. Cole, N.T. Nguyen, Q. Li, Carbon dots functionalized by organosilane with double-sided anchoring for nanomolar Hg2+ detection. J. Colloid Interface Sci. 437, 28–34 (2015). doi:10.​1016/​j.​jcis.​2014.​09.​013 CrossRef
227.
F. Yan, Y. Zou, M. Wang, X. Mu, N. Yang, L. Chen, Highly photoluminescent carbon dots-based fluorescent chemosensors for sensitive and selective detection of mercury ions and application of imaging in living cells. Sens. Actuat. B Chem. 192, 488–495 (2014). doi:10.​1016/​j.​snb.​2013.​11.​041 CrossRef
228.
H. Li, J. Zhai, J. Tian, Y. Luo, X. Sun, Carbon nanoparticle for highly sensitive and selective fluorescent detection of mercury(II) ion in aqueous solution. Biosens. Bioelectron. 26(12), 4656–4660 (2011). doi:10.​1016/​j.​bios.​2011.​03.​026 CrossRef
229.
X. Cui, L. Zhu, J. Wu, Y. Hou, P. Wang, Z. Wang, M. Yang, A fluorescent biosensor based on carbon dots-labeled oligodeoxyribonucleotide and graphene oxide for mercury(II) detection. Biosens. Bioelectron. 63, 506–512 (2015). doi:10.​1016/​j.​bios.​2014.​07.​085 CrossRef
230.
I. Costas-Mora, V. Romero, I. Lavilla, C. Bendicho, In situ building of a nanoprobe based on fluorescent carbon dots for methylmercury detection. Anal. Chem. 86(9), 4536–4543 (2014). doi:10.​1021/​ac500517h CrossRef
231.
Y. Dong, R. Wang, G. Li, C. Chen, Y. Chi, G. Chen, Polyamine-functionalized carbon quantum dots as fluorescent probes for selective and sensitive detection of copper ions. Anal. Chem. 84(14), 6220–6224 (2012). doi:10.​1021/​ac3012126 CrossRef
232.
X. Lin, G. Gao, L. Zheng, Y. Chi, G. Chen, Encapsulation of strongly fluorescent carbon quantum dots in metal-organic frameworks for enhancing chemical sensing. Anal. Chem. 86(2), 1223–1228 (2014). doi:10.​1021/​ac403536a CrossRef
233.
Y. Dong, R. Wang, W. Tian, Y. Chi, G. Chen, “Turn-on” fluorescent detection of cyanide based on polyamine-functionalized carbon quantum dots. RSC Adv. 4(8), 3701–3705 (2014). doi:10.​1039/​c3ra45893h CrossRef
234.
Q. Qu, A. Zhu, X. Shao, G. Shi, Y. Tian, Development of a carbon quantum dots-based fluorescent Cu2+ probe suitable for living cell imaging. Chem. Commun. 48(44), 5473–5475 (2012). doi:10.​1039/​c2cc31000g CrossRef
235.
A. Zhu, Q. Qu, X. Shao, B. Kong, Y. Tian, Carbon-dot-based dual-emission nanohybrid produces a ratiometric fluorescent sensor for in vivo imaging of cellular copper ions. Angew. Chem. Int. Ed. 51(29), 7185–7189 (2012). doi:10.​1002/​anie.​201109089 CrossRef
236.
X. Liu, N. Zhang, T. Bing, D. Shangguan, Carbon dots based dual-emission silica nanoparticles as a ratiometric nanosensor for Cu2+. Anal. Chem. 86(5), 2289–2296 (2014). doi:10.​1021/​ac404236y CrossRef
237.
H. Sun, N. Gao, L. Wu, J. Ren, W. Wei, X. Qu, Highly photoluminescent amino-functionalized graphene quantum dots used for sensing copper ions. Chem. Eur. J. 19(40), 13362–13368 (2013). doi:10.​1002/​chem.​201302268 CrossRef
238.
239.
L. Liu, Y. Li, L. Zhan, Y. Liu, C. Huang, One-step synthesis of fluorescent hydroxyls-coated carbon dots with hydrothermal reaction and its application to optical sensing of metal ions. Sci. China Chem. 54(8), 1342–1347 (2011). doi:10.​1007/​s11426-011-4351-6 CrossRef
240.
Y. Song, S. Zhu, S. Xiang, X. Zhao, J. Zhang, H. Zhang, Y. Fu, B. Yang, Investigation into the fluorescence quenching behaviors and applications of carbon dots. Nanoscale 6(9), 4676–4682 (2014). doi:10.​1039/​c4nr00029c CrossRef
241.
242.
S. Hu, Q. Zhao, Q. Chang, J. Yang, J. Liu, Enhanced performance of Fe3+ detection via fluorescence resonance energy transfer between carbon quantum dots and Rhodamine B. RSC Adv. 4(77), 41069–41075 (2014). doi:10.​1039/​c4ra06371f CrossRef
243.
X. Li, S. Zhu, B. Xu, K. Ma, J. Zhang, B. Yang, W. Tian, Self-assembled graphene quantum dots induced by cytochrome c: a novel biosensor for trypsin with remarkable fluorescence enhancement. Nanoscale 5(17), 7776–7779 (2013). doi:10.​1039/​c3nr00006k CrossRef
244.
S. Gomez-de Pedro, A. Salinas-Castillo, M. Ariza-Avidad, A. Lapresta-Fernandez, C. Sanchez-Gonzalez, C.S. Martinez-Cisneros, M. Puyol, L.F. Capitan-Vallvey, J. Alonso-Chamarro, Microsystem-assisted synthesis of carbon dots with fluorescent and colorimetric properties for pH detection. Nanoscale 6(11), 6018–6024 (2014). doi:10.​1039/​c4nr00573b CrossRef
245.
W. Wei, C. Xu, J. Ren, B. Xu, X. Qu, Sensing metal ions with ion selectivity of a crown ether and fluorescence resonance energy transfer between carbon dots and graphene. Chem. Commun. 48(9), 1284–1286 (2012). doi:10.​1039/​c2cc16481g CrossRef
246.
Y. Dong, G. Li, N. Zhou, R. Wang, Y. Chi, G. Chen, Graphene quantum dot as a green and facile sensor for free chlorine in drinking water. Anal. Chem. 84(19), 8378–8382 (2012). doi:10.​1021/​ac301945z CrossRef
247.
248.
H.X. Zhao, L.Q. Liu, Z.D. Liu, Y. Wang, X.J. Zhao, C.Z. Huang, Highly selective detection of phosphate in very complicated matrixes with an off-on fluorescent probe of europium-adjusted carbon dots. Chem. Commun. 47(9), 2604–2606 (2011). doi:10.​1039/​c0cc04399k CrossRef
249.
J.M. Bai, L. Zhang, R.P. Liang, J.D. Qiu, Graphene quantum dots combined with europium ions as photoluminescent probes for phosphate sensing. Chem. Eur. J. 19(12), 3822–3826 (2013). doi:10.​1002/​chem.​201204295 CrossRef
250.
J.J. Liu, X.L. Zhang, Z.X. Cong, Z.T. Chen, H.H. Yang, G.N. Chen, Glutathione-functionalized graphene quantum dots as selective fluorescent probes for phosphate-containing metabolites. Nanoscale 5(5), 1810–1815 (2013). doi:10.​1039/​c3nr33794d CrossRef
251.
J. Xu, Y. Zhou, G. Cheng, M. Dong, S. Liu, C. Huang, Carbon dots as a luminescence sensor for ultrasensitive detection of phosphate and their bioimaging properties. Luminescence 30(4), 411–415 (2015). doi:10.​1002/​bio.​2752
252.
Y.H. Li, L. Zhang, J. Huang, R.P. Liang, J.D. Qiu, Fluorescent graphene quantum dots with a boronic acid appended bipyridinium salt to sense monosaccharides in aqueous solution. Chem. Commun. 49(45), 5180–5182 (2013). doi:10.​1039/​c3cc40652k CrossRef
253.
Z.B. Qu, X.G. Zhou, L. Gu, R.M. Lan, D.D. Sun, D.J. Yu, G.Y. Shi, Boronic acid functionalized Graphene quantum dots as fluorescent. Chem. Comm. 49(84), 9830–9832 (2013). doi:10.​1039/​C3CC44393K CrossRef
254.
L. Zhu, X. Cui, J. Wu, Z. Wang, P. Wang, Y. Hou, M. Yang, Fluorescence immunoassay based on carbon dots as labels for the detection of human immunoglobulin G. Anal. Methods 6(12), 4430–4436 (2014). doi:10.​1039/​c4ay00717d
255.
H. Zhao, Y. Chang, M. Liu, S. Gao, H. Yu, X. Quan, A universal immunosensing strategy based on regulation of the interaction between graphene and graphene quantum dots. Chem. Commun. 49(3), 234–236 (2013). doi:10.​1039/​c2cc35503e CrossRef
256.
D. Bu, H. Zhuang, G. Yang, X. Ping, An immunosensor designed for polybrominated biphenyl detection based on fluorescence resonance energy transfer (FRET) between carbon dots and gold nanoparticles. Sens. Actuat. B Chem. 195, 540–548 (2014). doi:10.​1016/​j.​snb.​2014.​01.​079 CrossRef
257.
Y. Wang, L. Zhang, R.P. Liang, J.M. Bai, J.D. Qiu, Using graphene quantum dots as photoluminescent probes for protein kinase sensing. Anal. Chem. 85(19), 9148–9155 (2013). doi:10.​1021/​ac401807b CrossRef
258.
259.
Y. Shi, Y. Pan, H. Zhang, Z. Zhang, M.J. Li, C. Yi, M. Yang, A dual-mode nanosensor based on carbon quantum dots and gold nanoparticles for discriminative detection of glutathione in human plasma. Biosens. Bioelectron. 56, 39–45 (2014). doi:10.​1016/​j.​bios.​2013.​12.​038 CrossRef
260.
S. Li, J. Luo, G. Yin, Z. Xu, Y. Le, X. Wu, N. Wu, Q. Zhang, Selective determination of dimethoate via fluorescence resonance energy transfer between carbon dots and a dye-doped molecularly imprinted polymer. Sens. Actuat. B Chem. 206, 14–21 (2015). doi:10.​1016/​j.​snb.​2014.​09.​038 CrossRef
261.
L. Wu, M. Li, M. Zhang, M. Yan, S. Ge, J. Yu, Ultrasensitive electrochemiluminescence immunosensor for tumor marker detection based on nanoporous sliver@carbon dots as labels. Sens. Actuat. B Chem. 186, 761–767 (2013). doi:10.​1016/​j.​snb.​2013.​06.​092 CrossRef
262.
J. Lou, S. Liu, W. Tu, Z. Dai, Graphene quantums dots combined with endonuclease cleavage and bidentate chelation for highly sensitive electrochemiluminescent DNA biosensing. Anal. Chem. 87(2), 1145–1151 (2015). doi:10.​1021/​ac5037318 CrossRef
263.
J. Shi, C. Lu, D. Yan, L. Ma, High selectivity sensing of cobalt in HepG2 cells based on necklace model microenvironment-modulated carbon dot-improved chemiluminescence in Fenton-like system. Biosens. Bioelectron. 45, 58–64 (2013). doi:10.​1016/​j.​bios.​2013.​01.​056 CrossRef
264.
Metadaten
Titel
Carbon Based Dots and Their Luminescent Properties and Analytical Applications
verfasst von
Yongqiang Dong
Jianhua Cai
Yuwu Chi
Copyright-Jahr
2016
Buch
Carbon Nanoparticles and Nanostructures

Print ISBN: 978-3-319-28780-5

Electronic ISBN: 978-3-319-28782-9

Copyright-Jahr: 2016

DOI
https://doi.org/10.1007/978-3-319-28782-9_6

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