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Journal of Sol-Gel Science and Technology

Erschienen in:

03.01.2017 | Original Paper: Sol-gel and hybrid materials for energy, environment and building applications

Carbon nanotubes/vanadium oxide composites as cathode materials for lithium-ion batteries

verfasst von: Xing Liang, Guohua Gao, Yindan Liu, Zeyuan Ge, Pengliang Leng, Guangming Wu

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 1/2017

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Abstract

The carbon nanotubes/vanadium oxide composites have been prepared through a facile hydrothermal method. Morphology features of the samples are investigated by field-emission scanning electron microscope. Raman and X-ray diffraction patterns confirm the formation of phase structure. Thermogravimetric analysis was used to quantify the content of carbon nanotube in the composites. When used as cathode materials for lithium-ion batteries, the composites exhibit improved electrochemical performance compared to electrode materials free of carbon nanotubes. V₂O₅/carbon nanotubes can deliver a good capacity of 196.8 mA h g⁻¹ at a current density of 100 mA g⁻¹ after 50 cycles. However, the electrode materials free of carbon nanotubes (V₂O₅) can reach a capacity of 171 mA h g⁻¹ at the same conditions. Moreover, V₂O₅/carbon nanotubes present a higher capacity than that of V₂O₅ under the same rate conditions. The improved electrochemical performance can be attributed to the fact that the carbon nanotubes in the V₂O₅/carbon nanotube composites can effectively facilitate ionic diffusion by raising the electrical conductivity.

Graphical Abstract

https://static-content.springer.com/image/art%3A10.1007%2Fs10971-016-4293-8/MediaObjects/10971_2016_4293_Figa_HTML.gif

Vorheriger Artikel Synthesis and phase formation in MxOy–ZrO2 nanosized precursors (M = Zn2+, Cd2+, Pb2+, Bi3+)

Nächster Artikel Preparation and electrochemical properties of Ba0.8La0.2FeO3-δ cathode for intermediate-temperature solid oxide fuel cells

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Titel: Carbon nanotubes/vanadium oxide composites as cathode materials for lithium-ion batteries
verfasst von: Xing Liang
Guohua Gao
Yindan Liu
Zeyuan Ge
Pengliang Leng
Guangming Wu
Publikationsdatum: 03.01.2017
Verlag: Springer US
Erschienen in: Journal of Sol-Gel Science and Technology / Ausgabe 1/2017
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI: https://doi.org/10.1007/s10971-016-4293-8

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