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Cellulose

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24.11.2017 | Original Paper

Carboxymethyl cellulose coated Fe₃O₄@SiO₂ core–shell magnetic nanoparticles for methylene blue removal: equilibrium, kinetic, and thermodynamic studies

verfasst von: Maryam Zirak, Aysan Abdollahiyan, Bagher Eftekhari-Sis, Mahnaz Saraei

Erschienen in: Cellulose | Ausgabe 1/2018

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Abstract

Fe₃O₄@SiO₂ core–shell magnetic nanoparticles (MNPs) were prepared by chemical coprecipitation of FeCl₃·6H₂O and FeCl₂·4H₂O in alkaline solution, followed by silylation using triethoxy silane, and then by treatment with 3-aminopropyltriethoxysilane. The corresponding MNPs were coated with carboxymethyl cellulose (CMC) by amide formation between carboxyl groups of CMC and amine functional groups of nanoparticles. The structure of MNPs was characterized by FT-IR, SEM, EDX, TEM, XRD, VSM and TGA analysis. CMC-coated Fe₃O₄@SiO₂ magnetic nanoparticles were used as an efficient adsorbent for the removal of methylene blue (MB, a cationic dye) from aqueous solutions. The impact of various factors such as adsorbent dosage, pH, initial concentration of MB, temperature and contact time were investigated. The kinetic, isotherms, and thermodynamic parameters of adsorption were also studied.

Vorheriger Artikel Dual-responsive composite hydrogels based on TEMPO-oxidized cellulose nanofibril and poly(N-isopropylacrylamide) for model drug release

Nächster Artikel Structure and properties of graphene oxide/cellulose hybrid fibers via divalent metal ions treatment

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Titel: Carboxymethyl cellulose coated Fe3O4@SiO2 core–shell magnetic nanoparticles for methylene blue removal: equilibrium, kinetic, and thermodynamic studies
verfasst von: Maryam Zirak
Aysan Abdollahiyan
Bagher Eftekhari-Sis
Mahnaz Saraei
Publikationsdatum: 24.11.2017
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 1/2018
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-017-1590-5

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