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Cellulose

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11.09.2019 | Original Research

Cellulose nanocrystal structure in the presence of salts

verfasst von: Aref Abbasi Moud, Mohammad Arjmand, Jie Liu, Yongfei Yang, Amir Sanati-Nezhad, S. Hossein Hejazi

Erschienen in: Cellulose | Ausgabe 18/2019

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Abstract

Aggregation and gelation of cellulose nanocrystals (CNCs) induced by magnesium chloride (MgCl₂) are investigated as a function of CNC and MgCl₂ concentrations. Transmission electron microscopy (TEM) and confocal laser scanning microscopy (CLSM) are employed to study the effect of ionic strength and CNC concentration on the extent of aggregation and structure of the CNC network. The location of CNC particles is traced with Fluorescent brightener 28 staining agent. The results show that the addition of different amounts of MgCl₂ causes a cluster formation of CNCs with different fractal dimensions, confirmed by TEM. The fractal dimension of CNC clusters varied from approximately 1.56 ± 0.08 to 1.98 ± 0.01 as the MgCl₂/CNC concentration ratio is increased from 0.17 to 0.42. We use the MgCl₂/CNC concentration ratio as a global parameter to correlate the results of different measurements and imaging data, including TEM, zeta potential and CLSM. Furthermore, we conduct molecular dynamic simulations to quantitatively examine different CNC behavior in MgCl₂ salt–CNC suspension. The results on the potential of mean force (PMF) indicate that the PMF of different ions concentration gravitates to zero where the distance between CNCs is increased from 3.1 nm to 3.5 nm. However, adding ions to the system changes the energy of the system and leads to a different behavior of CNC interactions.

Graphic abstract

Vorheriger Artikel The formation of Gluconacetobacter xylinum cellulose under the influence of the dye brilliant yellow

Nächster Artikel The potential of magnetisation transfer NMR to monitor the dissolution process of cellulose in cold alkali

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Titel: Cellulose nanocrystal structure in the presence of salts
verfasst von: Aref Abbasi Moud
Mohammad Arjmand
Jie Liu
Yongfei Yang
Amir Sanati-Nezhad
S. Hossein Hejazi
Publikationsdatum: 11.09.2019
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 18/2019
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-019-02734-0

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