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26.05.2021 | Original Research

Cellulose nanofiber-derived efficient stabilizer for oil-in-water high-internal-phase emulsion

verfasst von: Arindam Chakrabarty, Yoshikuni Teramoto

Erschienen in: Cellulose | Ausgabe 10/2021

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Abstract

Stabilization of emulsion using plant-derived nanomaterial has been of great research interest. In this regard, cellulose nanofibers (CNF) showed good potential in conventional emulsion system. Thus, it creates the scope to develop an efficient CNF-based stabilizer for high internal phase emulsion (HIPE) using a convenient process. Herein, we prepared oil-in-water (o/w) HIPEs or emulsion gels using amphiphile-grafted CNFs termed as cellulosic gelators (CLGs). The CLGs were obtained by grafting a poly(ethylene glycol)-based amphiphile (PGLE) onto CNFs by one-step etherification reaction at different degree of PGLE substitution (DS). The HIPEs remained stable at very high oil volume (upto 96.3%) and they were characterized by optical and electron microscopy, rheology and differential scanning calorimetry. The efficacy of stabilization and oil-droplet sizes were highly dependent to the DS, concentration of CLG, and the volume of aqueous phase. The beneficial effect of CNF in CLGs was observed from the higher thermal stability (control, 31.4 °C; CLG, 57.0 °C) and improved viscoelasticity (critical strain γ_c: control, 0.3%; CLG, 1.0%). This approach will pave the way to the application of CNFs in producing commercial HIPEs to be used in food, cosmetics and pharmaceuticals.

Vorheriger Artikel Functionalization of cellulose nanocrystal powder by non-thermal atmospheric-pressure plasmas

Nächster Artikel Synthesis and properties of cellulose nanocrystal conjugates with reactive dyes

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Titel: Cellulose nanofiber-derived efficient stabilizer for oil-in-water high-internal-phase emulsion
verfasst von: Arindam Chakrabarty
Yoshikuni Teramoto
Publikationsdatum: 26.05.2021
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 10/2021
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-021-03948-x

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