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Cellulose
Erschienen in: Cellulose 3/2013

01.06.2013 | Original Research

Cellulose polymorphism study with sum-frequency-generation (SFG) vibration spectroscopy: identification of exocyclic CH2OH conformation and chain orientation

verfasst von: Christopher M. Lee, Ashutosh Mittal, Anna L. Barnette, Kabindra Kafle, Yong Bum Park, Heenae Shin, David K. Johnson, Sunkyu Park, Seong H. Kim

Erschienen in: Cellulose | Ausgabe 3/2013

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Abstract

Sum-frequency-generation (SFG) vibration spectroscopy is a technique only sensitive to functional groups arranged without centrosymmetry. For crystalline cellulose, SFG can detect the C6H2 and intra-chain hydrogen-bonded OH groups in the crystal. The geometries of these groups are sensitive to the hydrogen bonding network that stabilizes each cellulose polymorph. Therefore, SFG can distinguish cellulose polymorphs (Iβ, II, IIII and IIIII) which have different conformations of the exocyclic hydroxymethylene group or directionalities of glucan chains. The C6H2 asymmetric stretching peaks at 2,944 cm−1 for cellulose Iβ and 2,960 cm−1 for cellulose II, IIII and IIIII corresponds to the trans-gauche (tg) and gauche-trans (gt) conformation, respectively. The SFG intensity of the stretch peak of intra-chain hydrogen-bonded O–H group implies that the chain arrangement in cellulose crystal is parallel in Iβ and IIII, and antiparallel in II and IIIII.
Vorheriger Artikel Clean and reactive nanostructured cellulose surface
Nächster Artikel Destructuration of cotton under elevated pressure

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Metadaten
Titel
Cellulose polymorphism study with sum-frequency-generation (SFG) vibration spectroscopy: identification of exocyclic CH2OH conformation and chain orientation
verfasst von
Christopher M. Lee
Ashutosh Mittal
Anna L. Barnette
Kabindra Kafle
Yong Bum Park
Heenae Shin
David K. Johnson
Sunkyu Park
Seong H. Kim
Publikationsdatum
01.06.2013
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 3/2013
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-013-9917-3

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