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Natural Aerogels with Interesting Environmental Features: C-Sequestration and Pesticides Trapping

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Aerogels Handbook

Part of the book series: Advances in Sol-Gel Derived Materials and Technologies ((Adv.Sol-Gel Deriv. Materials Technol.))

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Abstract

Volcanic (allophanic) soils contain amorphous clays (allophanes), which present completely different structures and physical properties compared to usual clays. Allophane aggregates have peculiar physical features very close to that of synthetic gels: large pore volume and pore size distribution, a high specific surface area and very large water content. These volcanic soils have exceptional carbon (C) sequestration properties and are considered as sink for green house gases (C and N). Moreover, these peculiar clays have a large ability to trap pesticides found in soils. One proposes that these interesting environmental properties can be due to the peculiar structure of the allophane aggregates. Because of a large irreversible shrinkage during drying, the supercritical drying technique was used to preserve the porous structure and the solid structure of allophanic soils, and the fractal structure of these natural aerogels was determined at the nanoscale. It was found that the spatial extent of the fractal aggregates depends on the allophane content in soils. One also proposes that this fractal structure, analogous to the silica gel network, could explain the high carbon, nitrogen, and pesticides content in the allophanic soils. Because of high specific surface area and low transport properties, the tortuous structure of the allophane aggregates plays the role of a labyrinth which traps C, N, and pesticides in the porosity of allophane aggregates.

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References

  1. Batjes, N.H. (1996) Total carbon and nitrogen in the soils of the world. European Journal of Soil Science 47(2): 151–163

    Google Scholar 

  2. Davidson E A, Janssens I A (2006) Temperature sensitivity of soil carbon decomposition and feedbacks to climate change. Nature 440 (9): 165–173

    Google Scholar 

  3. Feller C and Beare M.H. (1997) Physical control of soil organic matter dynamics in the tropics. Geoderma 79(1-4): 69–116

    Google Scholar 

  4. Boudot J P, Bel Hadj, B.A. and Choné, T (1986) Carbon mineralization in Andosols and aluminium-rich highlands soils. Soil Biology & Biochemistry 18(4): 457–461

    Google Scholar 

  5. Wada K.J (1985). The distinctive properties of Andosol. Advances in Soil Sciences 2: 173–229

    Google Scholar 

  6. Basile-Doelsch I, Amundson R, Stone W E E, Masiello CA, Bottero JY, Colin F, Masin F, Borschneck D and Meunier JD (2005) Mineralogical control of organic carbon dynamics in a volcanic ash soil on La Réunion. European Journal of Soil Science 56(6): 689–703

    Google Scholar 

  7. Feller C, Albrecht A, Blanchart E, Cabidoche, Y M, Chevallier T, Hartmann C, Eschenbrenner V, Larre-Larrouy M C and Ndandou JF (2001) Soil organic carbon sequestration in tropical areas. General considerations and analysis of some edaphic determinants for Lesser Antilles soils. Nutrient Cycling In Agroecosystems 61(1–2): 19–31

    Google Scholar 

  8. Dawson G W, Weimer WC, Shupe S J (1979) Kepone-A case study of a persistent material, The American Institute of Chemical Engineers (AIChE) Symposium Series 75, 190: 366–372

    Google Scholar 

  9. Cabidoche Y M, Achard R, Cattan P, Clermont-Dauphin C, Massat F, Sansoulet J, (2009) Long-term pollution by chlordecone of tropical volcanic soils in the French West Indies: A simple leaching model accounts for current residue. Environmental Pollution 157: 1697–1707

    Google Scholar 

  10. Quentin P, Balesdent J, Bouleau A, Delaune M, Feller C (1991) Premiers stades d’altération de ponces volcaniques en climat tropical humide (Montagne Pelée, Martinique. Geoderma 79: 125–148

    Google Scholar 

  11. Woignier, T., Braudeau, E., Doumenc, H. and Rangon, L (2005) Supercritical drying applied to natural “gels”: Allophanic soils. Journal of Sol–Gel Science and Technology. 36: 61–68

    Google Scholar 

  12. Kistler, S (1932) Coherent expanded aerogels. Journal of Physical Chemistry 36: 52–64

    Google Scholar 

  13. Brinker J F and Scherer G W (1990) Sol–Gel Science. Academic Press, N.Y.

    Google Scholar 

  14. Prassas M, Woignier T, Phalippou J (1990) Glasses from aerogels part 1: The synthesis of monolithic silica aerogel. J. Mater. Sci. 24: 3111–3117

    Google Scholar 

  15. Fillet S, Phalippou, J, Zarzycki J and Nogues JL (1986) Texture of gels produced by corrosion of radioactive waste disposal glass. Journal of Non-Crystalline Solids 82: 232–238

    Google Scholar 

  16. Macquet C, Thomassin J H, Woignier T (1994) Archaeological glass drying during hypercritical solvent evacuation method. Journal of Sol–Gel Science and Technology, 2: 285–291

    Google Scholar 

  17. Woignier T, Pochet G, Doumenc H, Dieudonne P and Duffours L (2007) Allophane: a natural gel in volcanic soils with interesting environmental properties. Journal of Sol–Gel Science and Technology 41(1): 25–30

    Google Scholar 

  18. Mizota C and Van Reewijk LP (1989) Clay mineralogy and chemistry of soils formed in volcanic material in diverse climatic regions Soil Monograph n°2. International Soil Reference and Information Center, Wageningen, 185 pp.

    Google Scholar 

  19. Braudeau E, Costantini J M, Bellier G, Colleuille H (1999) New devices and method for soil shrinkage curve measurements and characterization. Soil Sci. Soc. Amer. J., 63: 525–535

    Google Scholar 

  20. Lours T, Zarzycki J, Craiewich A, Dos Santos D, Aegerter M, (1987) SAXS and BET studies of aging and densification of silica aerogels. J. Non-Cryst. Solids 95&96 : 1151–1158

    Google Scholar 

  21. Bourret A (1988) Low density silica aerogels observed by high resolution electron microscopy. Europhysics lett. 6(8):731–737

    Google Scholar 

  22. Woignier T, Phalippou J, Pelous J, Courtens E (1990) Different kinds of fractal structures in Si02 aerogels. J. Non-Cryst. Solids 121:198–204

    Google Scholar 

  23. Adashi Y, Karube K (1999) Application of a scaling law to analysis of allophane aggregates. Colloids and surfaces A :Physicochem. Eng. Aspects 43:151–155

    Google Scholar 

  24. Gustafsson J P, Bhattacharya PJ, Blain DC, Fraser AR. and MacHardy W J (1995) Podzolization mechanisms and the synthesis of imogolite in northern Scandinavia. Geoderma 66: 167–174

    Google Scholar 

  25. Dubroeucq D, Geissert D and Quantin P (1998) Weathering and soil forming process under semi-arid conditions in two Mexican volcanic ash soils. Geoderma 86: 99–122

    Google Scholar 

  26. Anderson HA, Berow M L, Framer V C, Hepburn A (1982) A reassessment of podzol formation process. J. Soil Sci. 33:125–131

    Google Scholar 

  27. Farmer V C Lumdson D G (2001) Interaction of fulvic acid with aluminium and a proto imogolite sol. Eur. J. Soil Sci 52:177–185

    Google Scholar 

  28. Fieldes M, Fuckert R J (1966) The nature of allophane in soils: the significance of structural randomness in pedogenesis New Zealand J. of Science, 9(3): 608–622

    Google Scholar 

  29. Wada S, Eto A, Wada K (1979) Synthetic allophane and imogolite. J Soil Sci. 30: 347–355

    Google Scholar 

  30. Denaix L, Lamy I., Bottero JY (1999) Structure and affinity of synthetic colloidal amorphous alimino silicates and their precursors. Colloids and surfaces A :Physicochem. Eng. Aspect 158: 315–325

    Google Scholar 

  31. Chevallier T, Woignier T, Toucet J, Blanchart E and Dieudonné P (2008) Fractal structure in natural gels: effect on carbon sequestration in volcanic soils. Journal of Sol Gel Science and Technology 48(1–2): 231–238

    Google Scholar 

  32. Dorel M, Roger-Estrade J, Manichon H, Delvaux B (2000) Porosity and soil water properties of caribean volcanic ash soils. Soils use and Management 16:133–140

    Google Scholar 

  33. Teixeira, J(1988) Small-angle scattering by fractal systems. Journal of Applied Crystallography 21: 781–785

    Google Scholar 

  34. Freltof T, Kjems KJ and Sinha SK (1986) Power-law correlations and finite-size effects in silica particle aggregates studied by small-angle neutron scattering. Physical Review B 33(1): 269–275

    Google Scholar 

  35. Torn M, Trumbore S, Chadwick O, Vitousek P and Hendricks D (1997) Mineral control of soil organic carbon storage and turnover. Nature 389: 170–173

    Google Scholar 

  36. Parfitt RL, Parshotam A and Salt G J(2002) Carbon turnover in two soils with contrasting mineralogy under long-term maize and pasture. Australian Journal of Soil Research 40(1): 127–136

    Google Scholar 

  37. Percival H J, Parfitt R L and Scott N (2000) Factors controlling soil carbon levels in New Zealand grasslands: Is clay content important?. Soil Science Society of America Journal 64: 1623–1630

    Google Scholar 

  38. Buurman P, Peterse F and Almendros Martin G (2007) Soil organic matter chemistry in allophanic soils: a pyrolysis-GC/MS study of a Costa Rican Andosol catena. European Journal of Soil Science 58: 1330–1347

    Google Scholar 

  39. Kaiser K and Guggenberger G, 2003. Mineral surfaces and soil organic matter. European Journal of Soil Science 54(2): 219–236

    Google Scholar 

  40. Mayer L M (1994) Relationships between mineral surfaces and organic carbon concentrations in soils and sediments. Chemical Geology 114: 347–363

    Google Scholar 

  41. Mayer L M (1994). Surface area control of organic carbon accumulation in continental shelf sediments. Geochimica et Cosmochimica Acta 58: 1271–1284

    Google Scholar 

  42. Saggar S, Parshotam A, Sparling G P, Feltham C W and Hart P B S (1996) 14C-labelled ryegrass turnover and residence times in soils varying in clay content and mineralogy. Soil Biology & Biochemistry 28: 1677–1686

    Google Scholar 

  43. Mayer L M, Schick LL, Hardy KR, Wagai R and McCarthy J (2004) Organic matter in small mesopores in sediments and soils.Geochimica et Cosmochimica Acta 68(19): 3863–3872

    Google Scholar 

  44. Zimmerman A R, Goyne K W, Chorover J, Komarneni S. and Brantley S L (2004) Mineral mesopore effects on nitrogenous organic matter adsorption. Organic Geochemistry 35(3): 355–375

    Google Scholar 

  45. Jannoyer Lesueur M, Woignier T, Achard R, Calba H, (2009) Pesticide transfer from soils to plants in tropical soils: influence of clay microstructure SETAC, New Orleans 19–23 Nov 2009

    Google Scholar 

  46. Jullien R and Botet R (1987) Aggregation and Fractal Aggregates. World Scientific, Singapore

    Google Scholar 

  47. Sanchez A S, Ajabary M, Toledo Fernandez J A, Moralez Flores V, Kherbeche A, Esquivias Fedriani L M, (2008) Reactivity of C02 traps in aerogel-wollastonite composites, Journal of Sol–Gel Science and Technology, 48(1–2): 224–230

    Google Scholar 

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Authors and Affiliations

  1. UMR CNRS 6116-UMR IRD 193- IMEP- IRD-PRAM, 97200, Le Lamentin, Martinique, France

    Thierry Woignier

  2. CNRS-Université Montpellier II, Place E. Bataillon, 34095, Montpellier Cedex 5, France

    Thierry Woignier

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  1. Thierry Woignier
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Correspondence to Thierry Woignier .

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Editors and Affiliations

  1. Résidence Vert-Pré, Ch. des Placettes 6, Bottens, CH-1041, Switzerland

    Michel A. Aegerter

  2. Technology, Department of Chemistry, Missouri University of Science &, Rolla, 65409, Missouri, USA

    Nicholas Leventis

  3. , Building Technologies Laboratory, Empa, Überlandstrasse 129, Dübendorf, CH-8600, Switzerland

    Matthias M. Koebel

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Woignier, T. (2011). Natural Aerogels with Interesting Environmental Features: C-Sequestration and Pesticides Trapping. In: Aegerter, M., Leventis, N., Koebel, M. (eds) Aerogels Handbook. Advances in Sol-Gel Derived Materials and Technologies. Springer, New York, NY. https://doi.org/10.1007/978-1-4419-7589-8_12

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  • DOI: https://doi.org/10.1007/978-1-4419-7589-8_12

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