Abstract
The use of polydentate, bridging ligands has enabled the preparation and characterization of mono-, bi-, tri-, and tetrametallic systems. Experimental measurements such as absorption and emission spectroscopy, and electrochemistry have indicated that the exact structure of the ligand determines the amount of communication between the various metal centers in the polymetallic complexes. This lack of electronic communication with some bridging ligands allows these systems to have a lifetime long enough to undergo emission at room temperature. These polymetallic systems supply a wide range of excited-state donor energies and redox potentials that give additional flexibility for energy- and electron-transfer processes. The ability to prepare supramolécular systems with multi-function and controllable molecular properties is the future for these molecules.
Alexander von Humboldt Research Fellow, Universität Regensburg, 1986–87.
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Alexander von Humboldt Research Fellow, Universität Regensburg, 1986–87.
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Petersen, J.D. (1987). Intramolecular Energy and Electron Transfer in Polymetallic Complexes. In: Balzani, V. (eds) Supramolecular Photochemistry. NATO ASI Series, vol 214. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3979-0_9
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DOI: https://doi.org/10.1007/978-94-009-3979-0_9
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