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Reactivity in surfactant systems

  • Chapter
Surfactant Systems

Abstract

The transfer of a reactive solute into a micelle changes several features of its existence that can alter its inherent stability. In the micelle the molecular environment of the solute molecules will have changed drastically, from an aqueous to a relatively non-polar milieu, depending on the depth of insertion into the micelle. The simple fact that the solute may be protected from attacking species such as H+ or OH- ions will give rise to stabilization of labile molecules such as esters; in some charged micelles, the surface characteristics will be such that there is a concentration of ions which would result in a more rapid breakdown than in simple aqueous solution.

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Authors and Affiliations

  1. Department of Pharmacy, University of Manchester, UK

    D. Attwood

  2. Department of Pharmacy, University of Strathclyde, UK

    A. T. Florence

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Attwood, D., Florence, A.T. (1983). Reactivity in surfactant systems. In: Surfactant Systems. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-5775-6_11

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