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Properties of fluoride glasses

  • Chapter
Fluoride Glass Optical Fibres

Abstract

Many properties need to be considered in deciding whether a particular glass will be suitable for a given commercial application. To make heavy metal fluoride (HMF) glass fibres, the resistance of the glass to crystallization during fabrication is of prime importance and this is linked in turn to the viscosity-temperature behaviour. At the same time other properties, such as the refractive index and dispersion, thermal expansion coefficient, chemical durability and strength, must also be optimized to allow manufacture of fibres with appropriate waveguiding characteristics and able to survive a range of operating conditions. As a result considerable effort has gone into composition development since the initial identification of fluorozirconate glasses as potential materials for infrared transitting fibres. Drexhage [1] and Tran et al. [2] have given comprehensive reviews of work in this field.

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References

  1. M. Drexhage, Treatise on Materials Science and Technology ,Vol. 26, Academic Press, New York (1985) p. 151.

    Google Scholar 

  2. D.C. Tran, G.H. Sigel and B. Bendow,J. Lightwave Technol. 2 (1984) 566.

    Article  Google Scholar 

  3. W.H. Zachariasen, J. Am. Chem. Soc. 62 (1932) 537.

    Google Scholar 

  4. C.M. Baldwin, R.M. Almeida and J.D. Mackenzie, J. Non-Cryst. Solids 43 (1981) 309.

    Article  Google Scholar 

  5. A. Sarhangi and D.A. Thompson, in 12th Eur. Conf. on Optical Communications ,Barcelona III, (1986) p. 62.

    Google Scholar 

  6. K.H. Sun, J. Am. Ceram. Soc. 30 (1947) 277.

    Article  Google Scholar 

  7. C.M. Baldwin and J.D. Mackenzie, J. Am. Ceram. Soc. 62 (1979) 537.

    Article  Google Scholar 

  8. M. Poulain, Nature 293 (1981) 279.

    Article  Google Scholar 

  9. J. Lucas, J. Mater. Sci. 24 (1989) 1.

    Article  Google Scholar 

  10. C. Jacoboni, in Halide Glasses for Infrared Fiberoptics ,ed. R.M. Almeida, Martinus Nijhoff, Dordrecht (1987) p. 341.

    Google Scholar 

  11. K.H. Sun, Glass Technol. 20 (1979) 36.

    Google Scholar 

  12. G. Fonteneau, A. Bouaggad and J. Lucas, Mater. Sci. Forum 19, 20 (1987) 41.

    Article  Google Scholar 

  13. J.M. Greneche, A. Le Bail, M. Leblanc, A. Mosset and F. Varret, J. Phys. C: Solid State Phys. 21 (1988) 1351

    Article  Google Scholar 

  14. Hu Hefang,Lin Fengyin,Gu Donghong and Li Min, Mater. Sci. Forum 5 (1985)145.

    Article  Google Scholar 

  15. R.M. Almeida, in Halide Glasses for Infrared Fiberoptics ,ed. R.M. Almeida, Martinus Nijhoff, Dordrecht (1987) p. 57.

    Google Scholar 

  16. G. Etherington, L. Keller, A. Lee, C.N.J. Wagner and R.M. Almeida, J. Non-Cryst. Solids 69 (1984) 69.

    Article  Google Scholar 

  17. J.M. Parker, in Halide Glasses for Infrared Fiberoptics ,ed. R.M. Almeida, Martinus Nijhoff, Dordrecht, (1987) p.57.

    Google Scholar 

  18. C.C. Phifer, CA. Angell, J.P. Laval and J. Lucas, J. Non-Cryst. Solids 94 (1987) 315.

    Article  Google Scholar 

  19. M. Matecki, M. Poulain and M. Poulain, Mater. Res. Bull. 17 (1982) 1275.

    Article  Google Scholar 

  20. T. Izumitani, T. Yamashita, M. Tokida, K. Miura and H. Tajima, in Halide Glasses for Infrared Fiberoptics ,ed. R.M. Almeida, Martinus Nijhoff, Dordrecht, (1987) p. 1987.

    Google Scholar 

  21. P.A. Tick, Mater. Sci. Forum 6 (1985) 797.

    Article  Google Scholar 

  22. L. Boehm, K.H. Chung, S.N. Crichton and CT Moynihan, Mater. Sci. Forum 19, 20 (1987) p. 533.

    Article  Google Scholar 

  23. M.J. Suscavage and O.H. El-Bayoumi, J. Am. Ceram. Soc. 68 (1985) C256.

    Article  Google Scholar 

  24. C.J. Simmons and J.H. Simmons, J. Am. Ceram. Soc. 68 (1985) C258.

    Article  Google Scholar 

  25. A.C. Wright, in Halide Glasses for Infrared Fiberoptics ,ed. R.M. Almeida, Martinus Nijhoff, Dordrecht, (1987) p. 75.

    Google Scholar 

  26. L. Kaufman and D. Birnie, in 2nd Int, Symp. Halide Glasses ,Troy, New York, (1983) paper 17.

    Google Scholar 

  27. G. Hatem, K. Mahmoud and M. Gaune-Escard, in 5th Int. Symp. on Halide Glasses ,Shizuoka, Japan (1988) p. 326.

    Google Scholar 

  28. M. Saad and M. Poulain, Mater. Sci. Forum 19, 20 (1987) p. 11.

    Article  Google Scholar 

  29. J.M. Parker, A.B. Seddon and A.G. Clare, Phys. Chem. Glasses 28 (1987) 4.

    Google Scholar 

  30. E.R. Buckle and R.R. Finbow, Int. Metall Rev. 210 (1976) 197.

    Google Scholar 

  31. P. McNamara and D.R. MacFarlane, J. Non-Cryst. Solids 95, 96 (1987) 945.

    Article  Google Scholar 

  32. P.A. Tick and S. Mitachi, J. Mater. Sci. Lett. 8 (1989) 436.

    Article  Google Scholar 

  33. R. Ota and N. Soga, J. Non-Cryst. Solids 56 (1983) 105.

    Article  Google Scholar 

  34. M.P. Brassington, T. Hailing, A.J. Miller and G.A. Saunders, Mater. Res. Bull. 16 (1981) 613.

    Article  Google Scholar 

  35. X. Zhao, H. Kozuka and S. Sakka, J. Mater. Sci. 22 (1987) 4103.

    Article  Google Scholar 

  36. X. Zhao and S. Sakka, J. Non-Cryst, Solids 99 (1988) 45.

    Article  Google Scholar 

  37. W.L. Vaughan and S.H. Risbud, Mater. Sci. Forum 5 (1985) 159.

    Article  Google Scholar 

  38. W.L. Vaughan and S.H. Risbud, J. Mater. Sci. Lett. 3 (1984) 162.

    Article  Google Scholar 

  39. J.M. Parker and P.W. France, in Glasses and Glass Ceramics ,ed. M.H. Lewis, Chapman and Hall, London (1989).

    Google Scholar 

  40. T. Izawa, N. Shibata and A. Takeda, Appl. Phys. Lett. 31 (1977) 33.

    Article  Google Scholar 

  41. C.M. Baldwin, R.M. Almeida and J.D. Mackenzie, J. Non-Cryst. Solids 43 (1981) 309.

    Article  Google Scholar 

  42. J. Zarzycki and F. Naudin, Verres Refract 3 (1960) 113.

    Google Scholar 

  43. Y.N. Kondrateva, G.T. Petrovski and E.L. Raaben, Zh. Prikl, Spectrosk 10 (1969) 69.

    Google Scholar 

  44. C. Angell and J. Wong, J. Chem. Phys. 53 (1970) 2053.

    Google Scholar 

  45. B. Bendow, F.L. Galeener and S.S. Mitra, in 1st Int. Symp. on Halide and Other Non Oxide Glasses ,Soc. Glass Technol. Cambridge (1982) paper 5a.

    Google Scholar 

  46. B. Bendow, P.K. Banerjee, M.G. Drexhage and O.H. El-Bayoumi, J. Am. Ceram Soc. 66 (1983) C64.

    Article  Google Scholar 

  47. R.M. Almeida and J.D. Mackenzie, J. Mater. Sci. 17 (1982) 2533.

    Article  Google Scholar 

  48. P.K. Banerjee, B. Bendow, M.G. Drexhage, J.T. Goltman, S.S. Mitra and C.T. Moynihan, J. Phys. Colloq. C6, 42, C6–75, (1981).

    Google Scholar 

  49. B. Bendow, F. Galeener and S.S. Mitra, J. Am. Ceram. Soc. 68 (1985) C92.

    Article  Google Scholar 

  50. G. Rupprecht, Phys. Rev. Lett 12 (1964) 580.

    Article  Google Scholar 

  51. T.F. Deutch, J. Phys. Chem. Solids. 34 (1973) 2091.

    Article  Google Scholar 

  52. M. Sparks and L.G. DeShazer, Proc. SPIE 266 (1981) 3.

    Google Scholar 

  53. B. Bendow, P.K. Banerjee, M.G. Drexhage, J.T. Goltman, S.S. Mitra and C.T. Moynihan, J. Am. Ceram. Soc. 65 (1982) C8.

    Article  Google Scholar 

  54. B. Bendow, Annu. Rev. Mater. Sci. 7 (1977) 23.

    Article  Google Scholar 

  55. B. Szigeti, Proc. Soc. London Ser A 204 (1950) 51.

    Article  Google Scholar 

  56. J.R. Gannon, Proc. SPIE 266 (1981) 62.

    Google Scholar 

  57. M. Matecki, M. Poulain and M. Poulain, in Proc.2ndnt. Symp. on Halide Glasses. Troy (1983) paper 27.

    Google Scholar 

  58. C.T. Moynihan, M.G. Drexhage, B. Bendow, M. Saleh-Boulos, K.P. Quinlan, K.H. Chung and E. Gboji, Mater. Res. Bull. 16 (1981) 25.

    Article  Google Scholar 

  59. H. Poignant, Electron Lett. 18 (1982) 199.

    Article  Google Scholar 

  60. B. Bendow, Appl. Phys. Lett. 23 (1973) 133.

    Article  Google Scholar 

  61. M.G. Drexhage, B. Bendow, R.N. Brown, P.K. Banerjee, H.G. Lipson, G. Fonteneau, J. Lucas and C.T. Moynihan, Appl. Opt. 21 (1982) 971.

    Article  Google Scholar 

  62. H.R. Philip, Solid State Commun. 4 (1966) 73.

    Article  Google Scholar 

  63. R.T. Williams, D.J. Nagel, P.H. Klein and M.J. Webber, J. Appl. Phys. 52 (1981) 6279.

    Article  Google Scholar 

  64. T.H. DiStefano and D.E. Eastman, Phys. Rev. Lett. 27 (1971) 1560.

    Article  Google Scholar 

  65. T. Izumitama and S. Hirota, Mater. Sci. Forum 6 (1985) 645.

    Article  Google Scholar 

  66. F. Urbach, Phys. Rev. 92 (1953) 1324.

    Article  Google Scholar 

  67. G. Sigel, J. Chem. Solids 32 (1971) 2373.

    Article  Google Scholar 

  68. D.A. Pinnow, T.C. Rich, F.W. Ostermayer and M. DiDomenico, Appl. Phys. Lett. 22 (1973) 527.

    Article  Google Scholar 

  69. G. Sigel, Treatise on Materials Science and Technology ,Vol. 12, ed. M. Tomozawa and R.H. Doremus, Academic Press (1977) p. 5.

    Google Scholar 

  70. CM. Baldwin, R.M. Almeida and J.D. Mackenzie, J. Non-Cryst. Solids 43 (1981) 309.

    Article  Google Scholar 

  71. R.N. Brown, B. Bendow, M.G. Drexhage and C.T. Moynihan Appl. Opt. 21 (1982) 361.

    Article  Google Scholar 

  72. J.E. Shelby, J.C. Lapp and M.J. Suscavage, J. Appl. Phys. 59 (1986) 3412.

    Google Scholar 

  73. J. Schroeder, in Treatise on Materials Science and Technology ,Vol. 12, ed. M. Tomozawa and R.H. Doremus, Academic Press (1977) p. 158.

    Google Scholar 

  74. M.E. Lines, J. Appl. Phys. 55 (1984) 4052.

    Google Scholar 

  75. H. Poignant, Electron Lett. 17 (1981) 973.

    Article  Google Scholar 

  76. S. Shibata, M. Horiguchi, K. Jinguji, S. Mitachi, T. Kanamori and T. Manabe, Electron Lett. 17 (1981) 775.

    Article  Google Scholar 

  77. S. Takahashi, S. Shibata, T. Kanamori, S. Mitachi and T. Manabe, Adv. Ceram. 2 (1981) 74.

    Google Scholar 

  78. B. Bendow, R.N. Brown, M.G. Drexhage, T.J. Loretz and R.L. Kirk, Appl. Opt. 20 (1981) 3688.

    Article  Google Scholar 

  79. L. Wetencamp, T. Westendorf, G. West and A. Kober, in Proc.5th Int. Symp. on Halide Glasses. Shizuoka, Japan (1988) p. 117.

    Google Scholar 

  80. Zhang Lipeng and Gan Fuxi, in Proc 5th Int. Symp. on Halide Glasses. Shizuoka, Japan (1988) p. 117.

    Google Scholar 

  81. S.H. Wemple, Appl. Opt. 118 (1979) 31.

    Article  Google Scholar 

  82. K. Nassau and S.H. Wemple, Electron Lett. 18 (1982) p. 450.

    Article  Google Scholar 

  83. K. Patek, Glass Lasers ,Butterworth, London (1970).

    Google Scholar 

  84. R. Reisfeld, G. Katz, C. Jacoboni, M.G. Drexhage and R.N. Brown, Phys. Rev. A 30 (1984) 2429.

    Article  Google Scholar 

  85. S.T. Davey and P.W. France, Br. Telecom. Technol. J. 7 (1989) 58.

    Google Scholar 

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Parker, J.M., France, P.W. (1990). Properties of fluoride glasses. In: Fluoride Glass Optical Fibres. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-6865-6_2

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  • DOI: https://doi.org/10.1007/978-94-011-6865-6_2

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