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Attraction between likely charged colloidal macroions?

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Trends in Colloid and Interface Science XII

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 110))

Abstract

The distance-resolved effective force between two spherical highly charged colloidal macroions is calculated within the primitive model of strongly asymmetric electrolytes using computer simulations. For parameters corresponding to typical experimental samples, a repulsive force is obtained. Possibilities for an effective attraction induced by very strong coupling between the macroions or by a geometric confinement of the macroions between glass plates are briefly discussed.

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G. J. M. Koper D. Bedeaux C. Cavaco W. F. C. Sager

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© 1998 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG

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Löwen, H. (1998). Attraction between likely charged colloidal macroions?. In: Koper, G.J.M., Bedeaux, D., Cavaco, C., Sager, W.F.C. (eds) Trends in Colloid and Interface Science XII. Progress in Colloid & Polymer Science, vol 110. Steinkopff. https://doi.org/10.1007/BFb0118039

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  • DOI: https://doi.org/10.1007/BFb0118039

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  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-1117-0

  • Online ISBN: 978-3-7985-1653-3

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