Abstract
The distance-resolved effective force between two spherical highly charged colloidal macroions is calculated within the primitive model of strongly asymmetric electrolytes using computer simulations. For parameters corresponding to typical experimental samples, a repulsive force is obtained. Possibilities for an effective attraction induced by very strong coupling between the macroions or by a geometric confinement of the macroions between glass plates are briefly discussed.
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© 1998 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG
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Löwen, H. (1998). Attraction between likely charged colloidal macroions?. In: Koper, G.J.M., Bedeaux, D., Cavaco, C., Sager, W.F.C. (eds) Trends in Colloid and Interface Science XII. Progress in Colloid & Polymer Science, vol 110. Steinkopff. https://doi.org/10.1007/BFb0118039
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DOI: https://doi.org/10.1007/BFb0118039
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