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Thermal Spin Crossover in Mn(II), Mn(III), Cr(II) and Co(III) Coordination Compounds

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Spin Crossover in Transition Metal Compounds II

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 234))

Abstract

This chapter considers thermal spin crossover occurring in transition metal compounds other than those of Fe(II), Fe(III) and Co(II). Unusual magnetic properties of several coordination and organometallic complexes of Mn(II), Mn(III), Cr(II) and Co(III) are discussed in the light of their structural features.

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Abbreviations

SCO:

Spin crossover

ST:

Spin transition

HS:

High spin

LS:

Low spin

dmpe:

1,2-Bis(dimethylphosphino)ethane

depe:

1,2-Bis(diethylphosphino)ethane

tmtaa:

Dibenzotetramethyltetraaza[14]annulene

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Acknowledgement

We thank Professor Wolfgang Kläui for providing us with crystal structure data of the trinuclear cobalt(III) complex prior to publication.

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Authors and Affiliations

  1. Unité de Chimie des Matériaux Inorganiques et Organiques, Département de Chimie, Faculté des Sciences, Université catholique de Louvain, Place Louis Pasteur 1, 1348, Louvain-la-Neuve, Belgium

    Yann Garcia

  2. Institut für Anorganische Chemie und Analytische Chemie, Johannes Gutenberg Universität Mainz, Staudingerweg 9, 55099, Mainz, Germany

    Philipp Gütlich

Authors
  1. Yann Garcia
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  2. Philipp Gütlich
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Correspondence to Yann Garcia or Philipp Gütlich .

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Garcia, Y., Gütlich, P. Thermal Spin Crossover in Mn(II), Mn(III), Cr(II) and Co(III) Coordination Compounds. In: Spin Crossover in Transition Metal Compounds II. Topics in Current Chemistry, vol 234. Springer, Berlin, Heidelberg. https://doi.org/10.1007/b95412

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  • DOI: https://doi.org/10.1007/b95412

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-40396-8

  • Online ISBN: 978-3-540-36774-1

  • eBook Packages: Springer Book Archive

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