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Erschienen in: Rare Metals 10/2019

28.08.2019

Characteristics of Ce–Mn film on 6061 alloys and its improved performance

verfasst von: Xue-Long Hao, Wen Ma, Chu Luo, Shi-Chao Yang, Hong Ji, Kai Zhang

Erschienen in: Rare Metals | Ausgabe 10/2019

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Abstract

HF2 was applied to accelerate the Ce–Mn film formation on 6061 Al alloy in the Ce3+–MnO4 solution. The process of film formation, the composition and structure of the film were analyzed by scanning electron microscopy (SEM) equipped with energy-dispersive spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS) and X-ray diffractometer (XRD). The film formation process includes three stages. At the initial stage, a three-dimensional (3D) skeleton was formed quickly, and then the skeleton was fully filled with cerium oxide and manganese oxide, resulting in a dense structure. Subsequently, a new skeleton was formed and also filled. Al, Ce, O and Mn were detected in the film. Ce existed mainly in the form of Ce4+ (89%). The film existed in an amorphous form and was composed of ceria (cerium hydroxide), manganese dioxide and aluminum oxide. After electrostatically spraying fluorocarbon powder, the resultant products satisfied the required mechanical performance and exhibited almost non-filament corrosion compared with commercially available chromium-free conversion film. Its corrosion resistant time to acetate spray can reach 2000 h, which is consistent with that of fluorocarbon paint. The results showed that Ce–Mn film can offer an attractive prospect to eliminate volatile organic compounds (VOC) problem arisen by using fluorocarbon paint in the process of industrial production.

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Literatur
[1]
Zurück zum Zitat Hinton BRW, Arnott DR, Ryan NE. Cerium conversion coatings for the corrosion protection of Aluminum. Mater Forum. 1986;9(3):162. Hinton BRW, Arnott DR, Ryan NE. Cerium conversion coatings for the corrosion protection of Aluminum. Mater Forum. 1986;9(3):162.
[2]
Zurück zum Zitat Chester RJ, Clark G, Hinton BRW, Baker AA. Research into materials aspects of aircraft, maintenance and life extension—part 1. Aircr Eng Aerosp Technol. 1993;65(1):2.CrossRef Chester RJ, Clark G, Hinton BRW, Baker AA. Research into materials aspects of aircraft, maintenance and life extension—part 1. Aircr Eng Aerosp Technol. 1993;65(1):2.CrossRef
[3]
Zurück zum Zitat Mishra AK, Balasubramaniam R. Corrosion inhibition of aluminum alloy AA 2014 by rare earth chlorides. Corros Sci. 2007;49(3):1027.CrossRef Mishra AK, Balasubramaniam R. Corrosion inhibition of aluminum alloy AA 2014 by rare earth chlorides. Corros Sci. 2007;49(3):1027.CrossRef
[4]
Zurück zum Zitat Mishra AK, Balasubramaniam R. Corrosion inhibition of aluminum alloy 6061 by rare earth chlorides. Corrosion. 2007;63(3):240.CrossRef Mishra AK, Balasubramaniam R. Corrosion inhibition of aluminum alloy 6061 by rare earth chlorides. Corrosion. 2007;63(3):240.CrossRef
[5]
Zurück zum Zitat Venkatasubramanian G, Mideen AS, Jha AK, Kulandainathan MA. Inhibitive effect of Ce(III) and La(III) cations for AA2219 Aluminum alloy corrosion in sodium chloride medium. Mater Chem Phys. 2014;148(1):262.CrossRef Venkatasubramanian G, Mideen AS, Jha AK, Kulandainathan MA. Inhibitive effect of Ce(III) and La(III) cations for AA2219 Aluminum alloy corrosion in sodium chloride medium. Mater Chem Phys. 2014;148(1):262.CrossRef
[6]
Zurück zum Zitat Arnott DR, Hinton BRW, Ryan NE. Cationic-film-forming inhibitors for the protection of the AA 7075 Aluminum alloy against corrosion in aqueous chloride solution. Corrosion. 1989;45(1):12.CrossRef Arnott DR, Hinton BRW, Ryan NE. Cationic-film-forming inhibitors for the protection of the AA 7075 Aluminum alloy against corrosion in aqueous chloride solution. Corrosion. 1989;45(1):12.CrossRef
[7]
Zurück zum Zitat Hinton BRW, Arnott DR, Ryan NE. Inhibition of aluminum alloy corrosion by cerous cations. Met Forum. 1984;7(4):211. Hinton BRW, Arnott DR, Ryan NE. Inhibition of aluminum alloy corrosion by cerous cations. Met Forum. 1984;7(4):211.
[8]
Zurück zum Zitat Amy LR, Carmel BB, Florian M. The corrosion protection afforded by rare earth conversion coatings applied to magnesium. Corros Sci. 2000;42(2):275.CrossRef Amy LR, Carmel BB, Florian M. The corrosion protection afforded by rare earth conversion coatings applied to magnesium. Corros Sci. 2000;42(2):275.CrossRef
[9]
Zurück zum Zitat Miskovic DM, Pohl K, Birbilis N, Laws KJ, Ferry M. Formation of a phosphate conversion coating on bioresorbable Mg-based metallic glasses and its effect on corrosion performance. Corros Sci. 2017;129:214.CrossRef Miskovic DM, Pohl K, Birbilis N, Laws KJ, Ferry M. Formation of a phosphate conversion coating on bioresorbable Mg-based metallic glasses and its effect on corrosion performance. Corros Sci. 2017;129:214.CrossRef
[10]
Zurück zum Zitat Geary M, Carmel BB. The influence of dichromate and cerium passivation treatments on the dissolution of SnZn coatings. Corros Sci. 1997;39(8):1341.CrossRef Geary M, Carmel BB. The influence of dichromate and cerium passivation treatments on the dissolution of SnZn coatings. Corros Sci. 1997;39(8):1341.CrossRef
[11]
Zurück zum Zitat Bethencourt M, Botana FJ, Calvino JJ, Marcos M, Rodríguez-Chacón MA. Lanthanide compounds as environmentally-friendly corrosion inhibitors of aluminium alloys: a review. Corros Sci. 1998;40(11):1803.CrossRef Bethencourt M, Botana FJ, Calvino JJ, Marcos M, Rodríguez-Chacón MA. Lanthanide compounds as environmentally-friendly corrosion inhibitors of aluminium alloys: a review. Corros Sci. 1998;40(11):1803.CrossRef
[12]
Zurück zum Zitat Aramaki K. A self-healing protective film prepared on zinc by treatment in a Ce(NO3)3 solution and modification with Ce(NO3)3. Corros Sci. 2005;47(5):1285.CrossRef Aramaki K. A self-healing protective film prepared on zinc by treatment in a Ce(NO3)3 solution and modification with Ce(NO3)3. Corros Sci. 2005;47(5):1285.CrossRef
[13]
Zurück zum Zitat Yan Z, Niu XY, Du XQ, Wang QC, Wu XJ, Zhou YN. Activating AlN thin film by introducing Co nanoparticles as a new anode material for thin-film lithium batteries. Rare Met. 2018;37(8):625.CrossRef Yan Z, Niu XY, Du XQ, Wang QC, Wu XJ, Zhou YN. Activating AlN thin film by introducing Co nanoparticles as a new anode material for thin-film lithium batteries. Rare Met. 2018;37(8):625.CrossRef
[14]
Zurück zum Zitat Yoganandan G, Premkumar KP, Balaraju JN. Evaluation of corrosion resistance and self-healing behavior of zirconium–cerium conversion coating developed on AA2024 alloy. Surf Coat Technol. 2015;270:249.CrossRef Yoganandan G, Premkumar KP, Balaraju JN. Evaluation of corrosion resistance and self-healing behavior of zirconium–cerium conversion coating developed on AA2024 alloy. Surf Coat Technol. 2015;270:249.CrossRef
[15]
Zurück zum Zitat Lin CS, Fang SK. Formation of Cerium conversion coatings on AZ31 Magnesium alloys. J Electrochem Soc. 2005;152(2):B54.CrossRef Lin CS, Fang SK. Formation of Cerium conversion coatings on AZ31 Magnesium alloys. J Electrochem Soc. 2005;152(2):B54.CrossRef
[16]
Zurück zum Zitat Pardo A, Merino MC, Arrabal R, Viejo F, Muñoz JA. Ce conversion and electrolysis surface treatments applied to A3xx.x alloys and A3xx.x/SiCp composites. Appl Surf Sci. 2007;253(6):3334.CrossRef Pardo A, Merino MC, Arrabal R, Viejo F, Muñoz JA. Ce conversion and electrolysis surface treatments applied to A3xx.x alloys and A3xx.x/SiCp composites. Appl Surf Sci. 2007;253(6):3334.CrossRef
[17]
Zurück zum Zitat Zhang K, Li WF, Du J. Surface structure and corrosion resistance on the rare earth conversion coating of aluminum alloys in HF2 solution. J Funct Mater. 2010;41(3):512. Zhang K, Li WF, Du J. Surface structure and corrosion resistance on the rare earth conversion coating of aluminum alloys in HF2 solution. J Funct Mater. 2010;41(3):512.
[18]
Zurück zum Zitat Zhang JJ, Li WF, Du J. Preparation and performance of Ce–Mn conversion coating on Al alloy surface at room temperature. Acta Metall. 2009;45(12):1466. Zhang JJ, Li WF, Du J. Preparation and performance of Ce–Mn conversion coating on Al alloy surface at room temperature. Acta Metall. 2009;45(12):1466.
[19]
Zurück zum Zitat Zhang JJ, Han D, Li WF, Du J. Study of the Ce–Mn conversion coating on 6061 aluminium alloy. Adv Mater Res. 2011;189–193(1):838. Zhang JJ, Han D, Li WF, Du J. Study of the Ce–Mn conversion coating on 6061 aluminium alloy. Adv Mater Res. 2011;189–193(1):838.
[20]
Zurück zum Zitat Decroly A, Petitjean JP. Study of the deposition of cerium oxide by conversion on to aluminium alloys. Surf Coat Technol. 2005;194(1):1.CrossRef Decroly A, Petitjean JP. Study of the deposition of cerium oxide by conversion on to aluminium alloys. Surf Coat Technol. 2005;194(1):1.CrossRef
[21]
Zurück zum Zitat Saei E, Ramezanzadeh B, Amini R, Kalajahi MS. Effects of combined organic and inorganic corrosion inhibitors on the nanostructure cerium based conversion coating performance on AZ31 magnesium alloy: morphological and corrosion studies. Corros Sci. 2017;127:186.CrossRef Saei E, Ramezanzadeh B, Amini R, Kalajahi MS. Effects of combined organic and inorganic corrosion inhibitors on the nanostructure cerium based conversion coating performance on AZ31 magnesium alloy: morphological and corrosion studies. Corros Sci. 2017;127:186.CrossRef
[22]
Zurück zum Zitat Chen DC, Li WF, Gong WH, Wu GX, Wu JF. Microstructure and formation mechanism of Ce-based chemical conversion coating on 6063 Al alloy. Trans Nonferrous Met Soc China. 2009;19(3):592.CrossRef Chen DC, Li WF, Gong WH, Wu GX, Wu JF. Microstructure and formation mechanism of Ce-based chemical conversion coating on 6063 Al alloy. Trans Nonferrous Met Soc China. 2009;19(3):592.CrossRef
[23]
Zurück zum Zitat Li T, Huang H, Guo ZC. Electrochemical behavior of aluminum alloy as cathode in zinc electro-deposition. Chin J Rare Met. 2017;41(11):1188. Li T, Huang H, Guo ZC. Electrochemical behavior of aluminum alloy as cathode in zinc electro-deposition. Chin J Rare Met. 2017;41(11):1188.
[24]
Zurück zum Zitat Yu XW, Li GQ. XPS study of cerium conversion coating on the anodized 2024 aluminum alloy. J Alloy Compd. 2004;364(1–2):193.CrossRef Yu XW, Li GQ. XPS study of cerium conversion coating on the anodized 2024 aluminum alloy. J Alloy Compd. 2004;364(1–2):193.CrossRef
[25]
Zurück zum Zitat Zhao D, Sun J, Zhang LL, Tan Y, Li J. Corrosion behavior of rare earth cerium based conversion coating on aluminum alloy. J Rare Earth. 2010;28(S1):371.CrossRef Zhao D, Sun J, Zhang LL, Tan Y, Li J. Corrosion behavior of rare earth cerium based conversion coating on aluminum alloy. J Rare Earth. 2010;28(S1):371.CrossRef
[26]
Zurück zum Zitat Breslin CB, Chen C, Mansfeld F. The electrochemical behaviour of stainless steels following surface modification in cerium-containing solutions. Corros Sci. 1997;39(6):1061.CrossRef Breslin CB, Chen C, Mansfeld F. The electrochemical behaviour of stainless steels following surface modification in cerium-containing solutions. Corros Sci. 1997;39(6):1061.CrossRef
[27]
Zurück zum Zitat Savaloni H, Habibi M. Influence of Ni deposition and subsequent N+ ion implantation at different substrate temperatures on nano-structure and corrosion behaviour of type 316 and 304 stainless steels. Appl Surf Sci. 2011;258(1):103.CrossRef Savaloni H, Habibi M. Influence of Ni deposition and subsequent N+ ion implantation at different substrate temperatures on nano-structure and corrosion behaviour of type 316 and 304 stainless steels. Appl Surf Sci. 2011;258(1):103.CrossRef
[28]
Zurück zum Zitat Feliu S Jr, Samaniego A, El-Hadad AA, Llorente I. The effect of NaHCO3 treatment time on the corrosion resistance of commercial magnesium alloys AZ31 and AZ61 in 0.6 M NaCl solution. Corros Sci. 2013;67:204.CrossRef Feliu S Jr, Samaniego A, El-Hadad AA, Llorente I. The effect of NaHCO3 treatment time on the corrosion resistance of commercial magnesium alloys AZ31 and AZ61 in 0.6 M NaCl solution. Corros Sci. 2013;67:204.CrossRef
[29]
Zurück zum Zitat Teterin YA, Teterin AY, Lebedev AM, Utkin IO. The XPS spectra of cerium compounds containing oxygen. J Electron Spectrosc Relat Phenom. 1998;88–91(Special):275.CrossRef Teterin YA, Teterin AY, Lebedev AM, Utkin IO. The XPS spectra of cerium compounds containing oxygen. J Electron Spectrosc Relat Phenom. 1998;88–91(Special):275.CrossRef
[30]
Zurück zum Zitat Kannadasan N, Shanmugam N, Cholan S, Sathishkumar K, Viruthagiri G, Poonguzhali R. The effect of Ce4+ incorporation on structural, morphological and photocatalytic characters of ZnO nanoparticles. Mater Charact. 2014;97(11):37.CrossRef Kannadasan N, Shanmugam N, Cholan S, Sathishkumar K, Viruthagiri G, Poonguzhali R. The effect of Ce4+ incorporation on structural, morphological and photocatalytic characters of ZnO nanoparticles. Mater Charact. 2014;97(11):37.CrossRef
[31]
Zurück zum Zitat Pezzato L, Brunelli K, Dabalà M. Corrosion properties of plasma electrolytic oxidation coated AA7075 treated using an electrolyte containing lanthanum-salts. Surf Interface Anal. 2016;48(8):729.CrossRef Pezzato L, Brunelli K, Dabalà M. Corrosion properties of plasma electrolytic oxidation coated AA7075 treated using an electrolyte containing lanthanum-salts. Surf Interface Anal. 2016;48(8):729.CrossRef
Metadaten
Titel
Characteristics of Ce–Mn film on 6061 alloys and its improved performance
verfasst von
Xue-Long Hao
Wen Ma
Chu Luo
Shi-Chao Yang
Hong Ji
Kai Zhang
Publikationsdatum
28.08.2019
Verlag
Nonferrous Metals Society of China
Erschienen in
Rare Metals / Ausgabe 10/2019
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI
https://doi.org/10.1007/s12598-019-01313-3

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