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Erschienen in: Topics in Catalysis 1-2/2018

30.10.2017 | Original Paper

Characterization of Cerium and Oxygen Atoms in Free Clusters of Cerium Oxide by X-ray Absorption Spectroscopy

verfasst von: Tetsuichiro Hayakawa, Masashi Arakawa, Shun Sarugaku, Kota Ando, Kenichirou Tobita, Yuya Kiyomura, Tomoki Kawano, Akira Terasaki

Erschienen in: Topics in Catalysis | Ausgabe 1-2/2018

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Abstract

X-ray absorption spectroscopy of size-selected cerium oxide cluster ions, Ce3O4–7 +, has been carried out by fragment-ion-yield measurement. X-ray absorption spectra measured in the Ce M4-edge and the O K-edge regions provided novel experimental data for chemical analysis of the constituent atoms and for discussion of geometric structures. The spectra near the Ce M4-edge exhibited a clear main peak and subtle substructures. Composition dependence of the spectra indicated that the oxidation state of Ce atoms evolves from + 3 to + 4 as an O atom is introduced one by one. On the other hand, the O K-edge spectra consisted of a main peak at ca. 532 eV and two additional peaks in the pre-edge region, where the intensities of the pre-edge peaks were significantly dependent on Ce:O composition. These pre-edge peaks suggested that the geometric structures of Ce3O5–7 + retain the “framework” of Ce3O4 + with “peripheral” O atoms bound on-top to the Ce atoms; coexistence of a structural isomer was suggested for Ce3O6 +, indicating presence of a molecular oxygen with Ce3O4 +−O2 geometry.

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Metadaten
Titel
Characterization of Cerium and Oxygen Atoms in Free Clusters of Cerium Oxide by X-ray Absorption Spectroscopy
verfasst von
Tetsuichiro Hayakawa
Masashi Arakawa
Shun Sarugaku
Kota Ando
Kenichirou Tobita
Yuya Kiyomura
Tomoki Kawano
Akira Terasaki
Publikationsdatum
30.10.2017
Verlag
Springer US
Erschienen in
Topics in Catalysis / Ausgabe 1-2/2018
Print ISSN: 1022-5528
Elektronische ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-017-0869-y

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