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Cellulose

Erschienen in:

01.08.2007

Characterization of changes induced by ageing to the microstructure of pure cellulose paper by use of a gravimetric water vapour adsorption technique

verfasst von: Spiros Zervos

Erschienen in: Cellulose | Ausgabe 4/2007

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Abstract

The changes induced to paper microstructure by accelerated ageing were studied using an automated gravimetric technique based on water vapour adsorption. The technique can be used especially in applications involving the adsorption and desorption of water, such as paper recycling, hornification, ageing and aqueous conservation treatments. The logistics for the calculation of the specific surface area of the examined samples are presented, and the f-plot technique was applied for the visualization and interpretation of the results. These indicated that ageing reduced the adsorption and the swelling capacity of the paper, resulting in a more compact structure, increasing crystallinity and promoting hornification.

Vorheriger Artikel Oxygen and water vapor permeability of fully substituted long chain cellulose esters (LCCE)

Nächster Artikel Analysis of the effects of catalytic bleaching on cotton

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Anonymous (a) (2007) Cellulose filters. Whatman International. Available at: http://www.whatman.com/products/?pageID=7.25.5. Cited 18 April 2007

Anonymous (b) CISorp water sorption analyser – user manual. CI Electronics, SorpUM v.4.5

Atalla RH (1981) The crystallinity of cellulosic fibers: dependence on history and influence on properties. In: Williams JC (ed) Preservation of paper and textiles of historic and artistic value II. Advances in chemistry series, vol 193. American Chemical Society, Washington D.C., pp 169–176

Chesson A, Gardner PT, Wood TJ (1997) Cell wall porosity and available surface area of wheat straw and wheat grain fractions. J Sci Food Agric 75:289–295CrossRef

Ek R, Lennholm H, Davidson R, Nystrom C, Ragnarsson G (1995) Pore swelling in beads made of cellulose fibres and fibre fragments. Int J Pharm122:49–56CrossRef

Erhardt D, Tumosa CS, Mecklenburg F (1999) Material consequences of the aging of paper. In: Bridgland J (ed) Preprints 12th Triennial Meet ICOM Committeer Conservation, ICOM-CC, vol 2. James and James, London, pp 501–506

Feller RL, Lee SB, Bogaard J (1986) The kinetics of cellulose deterioration. In: Needles HL, Zeronian SH (eds) Historic textile and paper materials – conservation and characterization. Advances in chemistry series, vol 212. American Chemical Society, Washington D.C., pp 329–347

Gregg SJ, Sing KSW (1982) Adsorption, surface area and porosity, 2nd edn, 4th printing. Academic Press, London

Haggkvist M, Li T-Q, Odberg L (1998) Effects of drying and pressing on the pore structure in the cellulose fibre wall studied by ¹H and ²H NMR relaxation. Cellulose 5:33–49CrossRef

Kato Kl, Cameron RE (1999a) Structure–property relationships in thermally aged cellulose fibers and paper. J Appl Polym Sci 74:1465–1477CrossRef

Kato KL, Cameron RE (1999b) A review of the relationship between thermally-accelerated ageing of paper and hornification. Cellulose 6:23–40CrossRef

Klemm D, Philipp B, Heinze T, Heinze U, Wagenknecht W (1998) Comprehensive cellulose chemistry, vol 1: fundamentals and analytical methods. Wiley-VCH, Weinheim

Levis SR, Deasy PB (2001) Production and evaluation of size reduced grades of microcrystalline cellulose. Int J Pharm 213:13–24CrossRef

Lin JS, Tang M-Y, Fellers JF (1987) Fractal analysis of cotton cellulose as characterized by small-angle x-ray scattering. In: Atalla RH (ed) The structures of cellulose ACS symposium series, vol 340. American Chemical Society, Washington D.C., pp 233–254

Mangel A (1999) Investigating a range of solid samples by automatic water sorption. J Therm Anal Calorim 55:581–599CrossRef

Millett MA, Effland MJ, Caulfield DF (1979) Influence of fine grinding on the hydrolysis of cellulosic materials – acid vs enzymatic. In: Brown R, Jurasek L (eds) Hydrolysis of cellulose: mechanisms of enzymatic and acid catalysts. Advances in chemistry series, vol 181. American Chemical Society, Washington D.C., pp 71–89

Moropoulou A, Zervos S (2003) The immediate impact of aqueous treatments on the strength of paper. Restaurator 24:160–177

Roberts JC (1996) The chemistry of paper. The Royal Society of Chemistry, Cambridge

Segal L, Creeley JJ, Matrin AE Jr, Conrad CM (1959) An empirical method for estimating the degree of crystallinity of native cellulose using the x-ray diffractometer. Text Res J 29:786–794CrossRef

Stone JE, Scallan AM (1967) The effect of component removal upon the porous structure of the cell wall of wood. II. Swelling in water and the fibre saturation point. Tappi J 50:496–501

Topgaard D, Soderman O (2002) Changes of cellulose fiber wall structure during drying investigated using NMR self-diffusion and relaxation experiments. Cellulose 9:139–147CrossRef

Vertommen J, Rombaut P, Kinget R (1998) Internal and external structure of pellets made in a rotary processor. Int J Pharm 161:225–236CrossRef

Weatherwax RC (1977) Collapse of cell-wall pores during drying of cellulose. J Colloid Interf Sci 62:432–446CrossRef

Westermarck S (2000) Mercury porosimetry of microcrystalline cellulose tablets: effect of scanning speed and moisture. Eur J Pharm Biopharm 50:319–325CrossRef

Whitmore PM, Bogaard J (1994) Determination of the cellulose scission route in the hydrolytic and oxidative degradation of paper. Restaurator 15:26–45CrossRef

Zervos S, Moropoulou A (2005) Cotton cellulose ageing in sealed vessels. Kinetic model of autocatalytic depolymerization. Cellulose 12:485–496CrossRef

Zou X, Gurnagul N, Uesaka T, Bouchard J (1994) Accelerated ageing of papers of pure cellulose: mechanism of cellulose degradation and paper embrittlement. Polym Degrad Stabil 43:393–402CrossRef

Zou X, Uesaka T, Gurnagul N (1996) Prediction of paper permanence by accelerated aging I. Kinetic analysis of the aging process. Cellulose 3:243–267CrossRef

Titel: Characterization of changes induced by ageing to the microstructure of pure cellulose paper by use of a gravimetric water vapour adsorption technique
verfasst von: Spiros Zervos
Publikationsdatum: 01.08.2007
Verlag: Kluwer Academic Publishers
Erschienen in: Cellulose / Ausgabe 4/2007
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-007-9125-0

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