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02.11.2017 | Original Paper

Chemical crosslinking reinforced flexible cellulose nanofiber-supported cryogel

verfasst von: Huan Cheng, Yingzhan Li, Bijia Wang, Zhiping Mao, Hong Xu, Linping Zhang, Yi Zhong, Xiaofeng Sui

Erschienen in: Cellulose | Ausgabe 1/2018

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Abstract

A robust and flexible cellulose nanofiber (CNF)-supported cryogel was prepared by chemical crosslinking method using γ-glycidoxypropyltrimethoxysilane (GPTMS) and branched polyethylenimine (PEI). FT-IR, elemental analysis, EDS and solid state ¹³C NMR analysis revealed that the PEI had been successfully modified on cellulose via reacting with GPTMS. The obtained flexible cryogel displayed a three-dimensional structure composed of thin sheet. The maximal shape recovery of the CNF-supported cryogel from a 50% compression strain was up to 93% of its original thickness. The cryogel contained abundant amino groups and proved to be efficient in removing Cu²⁺ from solution with a maximum Cu²⁺ uptake of 138 mg/g. The adsorption kinetics curve fitted the pseudo-second-order model and the equilibrium absorption capacity fitted the Langmuir model. Moreover, adsorption capacity of the cryogel was up to 75% after four adsorption–desorption cycles (15 days).

Vorheriger Artikel Self-healing and injectable polysaccharide hydrogels with tunable mechanical properties

Nächster Artikel Precipitation assay meets low wettability on paper: a simple approach for fabricating patterned paper sensors

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Titel: Chemical crosslinking reinforced flexible cellulose nanofiber-supported cryogel
verfasst von: Huan Cheng
Yingzhan Li
Bijia Wang
Zhiping Mao
Hong Xu
Linping Zhang
Yi Zhong
Xiaofeng Sui
Publikationsdatum: 02.11.2017
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 1/2018
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-017-1548-7

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