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10.08.2020 | Original Research

Chitosan supported molybdate nanoclusters as an efficient catalyst for oxidation of alkenes and alcohols

verfasst von: Jacky H. Advani, Balasaheb D. Bankar, Hari C. Bajaj, Ankush V. Biradar

Erschienen in: Cellulose | Ausgabe 15/2020

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Abstract

The excellent Lewis acidity and variable oxidation states of molybdate anions for the oxidation reactions was utilized by supporting it on eco-friendly and amply available fishery waste chitosan backbone using a simple “mix and make” methodology. The comprehensive structural analysis was done by FTIR, XRD, FESEM, elemental mapping, TEM and XPS. FESEM and elemental analysis revealed the mono-dispersion of molybdate nanoclusters on the surface of the chitosan. The increase in the molybdate loading increased the size of the clusters without affecting their uniformity over the polymer. This multi-nuclear material showed high catalytic activity towards the liquid phase oxidation of alkenes and alcohols owing to the surface sorption of the molybdate nanoclusters. The oxidation of cycloalkenes gave full conversion with > 90% selectivity towards the corresponding epoxides, while the oxidation of aryl alkenes and alcohols gave good to best results in terms of catalytic activity and selectivity. The catalyst exhibited prominent reusability.

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Vorheriger Artikel A bowl-shaped biosorbent derived from sugarcane bagasse lignin for cadmium ion adsorption

Nächster Artikel Entangled cellulose nanofibrils/nanosheets derived from native mexican agave for lead(II) ion removal

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Titel: Chitosan supported molybdate nanoclusters as an efficient catalyst for oxidation of alkenes and alcohols
verfasst von: Jacky H. Advani
Balasaheb D. Bankar
Hari C. Bajaj
Ankush V. Biradar
Publikationsdatum: 10.08.2020
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 15/2020
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-020-03368-3

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